Recovery of the Rare Metals from Various Waste Ashes with the Aid of Temperature and Ultrasound Irradiation Using Chelants

Hasegawa, Hiroshi; Rahman, Ismail M. M.; Egawa, Yuji; Sawai, Hikaru; Begum, Zinnat A.; Maki, Teruya; Mizutani, Satoshi

Recovery of the Rare Metals from Various Waste Ashes with the Aid of Temperature and Ultrasound Irradiation Using Chelants

2014

The incineration fly ash (IFA), molten fly ash (MFA), thermal power plant fly ash (TPP-FA), and nonferrous metal processing plant ash (MMA) have been screened in terms of the following rare-termed metal contents: B, Ce, Co, Dy, Eu, Ga, Gd, Hf, In, Li, Lu, Mn, Nb, Nd, Ni, Pr, Rb, Sb, Se, Sm, Sr, Ta, Tb, Te, Ti, Tm, V, W, Y, and Yb. The pseudo-potential for recycling of the waste ashes, as compared to the cumulative concentration in the crust (mg kg⁻¹), was determined as follows: MMA > IFA > MFA > TPP-FA. The comparison with the crude ore contents indicates that the MMA is the best resource for reprocessing. The recovery of the target metals using aminopolycarboxylate chelants (APCs) has been attempted at varying experimental conditions and ultrasound-induced environment. A better APC-induced extraction yield can be achieved at 0.10 mol L⁻¹ concentration of chelant, or if the system temperature was maintained between 60 to 80 °C. Nevertheless, the mechanochemical reaction induced by the ultrasound irradiation has been, so far, the better option for rare metal dissolution with chelants as it can be conducted at a minimum chelant concentration (0.01 mol L⁻¹) and at room temperature (25 ± 0.5 °C).

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