Formation and mobilization of methylmercury across natural and experimental sulfur deposition gradients

Åkerblom, Staffan; Nilsson, Mats B.; Skyllberg, Ulf; Bjørn, Erik; Jonsson, Sofi; Ranneby, Bo; Bishop, Kevin

Formation and mobilization of methylmercury across natural and experimental sulfur deposition gradients

2020

We investigated the influence of sulfate (SO₄²⁻) deposition and concentrations on the net formation and solubility of methylmercury (MeHg) in peat soils. We used data from a natural sulfate deposition gradient running 300 km across southern Sweden to test the hypothesis posed by results from an experimental field study in northern Sweden: that increased loading of SO₄²⁻ both increases net MeHg formation and redistributes methylmercury (MeHg) from the peat soil to its porewater. Sulfur concentrations in peat soils correlated positively with MeHg concentrations in peat porewater, along the deposition gradient similar to the response to added SO₄²⁻ in the experimental field study. The combined results from the experimental field study and deposition gradient accentuate the multiple, distinct and interacting roles of SO₄²⁻ deposition in the formation and redistribution of MeHg in the environment.

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