The characterization and methane adsorption of Ag-, Cu-, Fe-, and H-exchanged chabazite-rich tuff from Turkey
2019
Sakızcı, Meryem | Özer, Mehmet
In this study, a chabazite-rich tuff (CHA) from the Bala deposit of Ankara region (Turkey) and its modified forms (CuCHA, AgCHA, FeCHA, and HCHA samples) were investigated at 273 and 298 K using volumetric apparatus up to 100 kPa. The chabazite samples were characterized by using thermal analysis (TG-DTG-DTA), X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy with detector X-ray energy dispersive (SEM-EDX), Fourier transform infrared (FT-IR), and N₂ adsorption methods. It was found that natural chabazite is composed of predominantly chabazite with small amounts of clinoptilolite and erionite. XRD showed that there are major structural changes to Fe- and H-exchanged chabazite samples. Capacity of chabazites for CH₄ ranged from 0.168 and 1.341 mmol/g. Among all the modified forms, it was observed that Ag form of chabazite zeolite had the greatest methane adsorption capacity at both temperatures.
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