Pd nanoparticles loaded on modified chitosan-Unye bentonite microcapsules: A reusable nanocatalyst for Sonogashira coupling reaction

Shafiei, Nasrin; Nasrollahzadeh, Mahmoud; Baran, Talat; Baran, Nuray Yılmaz; Shokouhimehr, Mohammadreza

Pd nanoparticles loaded on modified chitosan-Unye bentonite microcapsules: A reusable nanocatalyst for Sonogashira coupling reaction

2021

Shafiei, Nasrin | Nasrollahzadeh, Mahmoud | Baran, Talat | Baran, Nuray Yılmaz | Shokouhimehr, Mohammadreza

This work investigates the preparation of a catalytic complex of palladium nanoparticles supported on novel Schiff base modified chitosan-Unye bentonite microcapsules (Pd NPs@CS-UN). The complex has been characterized by FT-IR, EDS, XRD, TEM, HRTEM, Raman, ICP-OES and elemental mapping analyses. Pd NPs@CS-UN was used as a catalyst for Sonogashira coupling reactions between aryl halides and acetylenes, employing K₂CO₃ as the base and EtOH as a green solvent under aerobic conditions in which it showed high efficacy. Pd NPs@CS-UN was regenerated by filtration after the completion of the reaction. This catalytic process has many advantages including simple methodology, high yields, and easy work-up. The catalytic performance does not notably change even after five consecutive runs.

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