Halogenation of Primary Alcohols Using a Tetraethylammonium Halide/[Et2NSF2]BF4 Combination
2012
Pouliot, Marie-France | Mahé, Olivier | Hamel, Jean-Denys | Desroches, Justine | Paquin, Jean-François
The halogenation of primary alcohols is presented. The use of a combination of tetraethylammonium halide and [Et₂NSF₂]BF₄ (XtalFluor-E) allows for chlorination and bromination reactions to proceed efficiently (up to 92% yield) with a wide range of alcohols. Iodination reactions are also possible albeit in lower yields.
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