Photo-oxidation of particle phase iron species dominates the generation of reactive oxygen species in secondary aerosol

Jiang, Sabrina Yanan; Gali, Nirmal Kumar; Ruan, Huada Daniel; Ning, Zhi

Photo-oxidation of particle phase iron species dominates the generation of reactive oxygen species in secondary aerosol

2020

Jiang, Sabrina Yanan | Gali, Nirmal Kumar | Ruan, Huada Daniel | Ning, Zhi

This study presents an experimental investigation on the photochemical transformation of iron species in aerosol including dissolution of insoluble iron species into soluble fraction, and soluble ferric oxidation to ferrous form. This process has significantly contributed to the aerosol oxidative potential in generation of reactive oxygen species (ROS). We conducted both laboratory experiment of UV irradiation and real world solar irradiation on large variation of aerosol samples for the characterization of iron speciation in insoluble and soluble fractions to investigate their transformation under photooxidation process. The results showed that the real world solar irradiation significantly increased the soluble Fe(II) fraction, and this is corroborated by laboratory simulation of UV irradiation showing increasing soluble Fe(II) fraction with elongating aging time. The results further exhibited that the dissolution of iron component into soluble fraction was a dominant process, followed by the conversion of soluble ferric to ferrous ions. Further, the study confirmed that the oxidative potential of particulate matter (PM) is attributed dominantly to the abundance of transition metals, i.e. Fe, and the incremental ROS generation after photochemical process is attributed largely to the transformation of solid phase iron species to soluble Fe(II). The results suggest that transition metals, for example by iron in this study, play an important role in secondary aerosol process.

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