Elevating the charge separation of MgFe2O4 nanostructures by Zn ions for enhanced photocatalytic and photoelectrochemical water splitting
2021
Kumar, GMohan | Cho, H.D. | Lee, D.J. | Kumar, JRam | Siva, C. | Ilanchezhiyan, P. | Kim, D.Y. | Kang, T.W.
Magnesium ferrites (MgFe₂O₄) are important class of ferrites that have been receiving greater attention as promising excellent photocatalyst due to its low cost, wide light spectrum response and environment-friendly nature. However, its poor electronic conductivity and fast charge carrier recombination hinders its electrocatalytical applications. Hence, accelerating charge carriers separation efficiency is important to modify the photoelectrochemical performance of MgFe₂O₄. Herein, novel Zn ions doped MgFe₂O₄ nanospheres are fabricated for the first time. Zn ions are doped into MgFe₂O₄ nanostructures from surface to enhance their charge separation efficiency. The doped MgFe₂O₄ nanostructures show significant photocatalytic activity and enhanced photocurrent density than that of pristine MgFe₂O₄.The improved photoelectrocatalytic performance is attributed to doping effect, were Zn ions actually enhance the conductivity. Zn ions enhance the activity of MgFe₂O₄ and accelerate the charge transfer properties in MgFe₂O₄. The results highlight that Zn doped MgFe₂O₄ nanospheres could be a potential candidate for photocatalytic and photoelectrochemical applications.
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