Enhancing the oxygen evolution reaction performance of NiFeOOH electrocatalyst for Zn-air battery by N-doping
2020
Li, Jiawang | Song, Jidong | Huang, Bo-Ying | Liang, Guofeng | Liang, Wanli | Huang, Guoju | Qi Jin, Yan | Zhang, Hao | Xie, Fangyan | Chen, Jian | Wang, Nan | Jin, Yanshuo | Li, Xi-Bo | Meng, Hui
Metal oxyhydroxides are regarded as active catalysts for oxygen evolution reaction (OER). Herein, we creatively report NiFeOOH is greatly activated by N-doping to get an efficient OER catalyst. The effect of N-doping in the resulted metal oxyhydroxides for the OER is revealed for the first time. N-doped NiFeOOH (N-NiFeOOH) is in-situ derived from N-(NiFe)₃S₂ precatalyst by electrochemical oxidation. N-NiFeOOH exhibits superior performance with a low overpotential of 278 mV at the current density of 100 mA cm⁻² and a small Tafel slope of 35.3 mV dec⁻¹, which is comparable to the most excellent non-noble catalysts. DFT calculations reveal that N-doping would lower the d-band center of the surface metal atoms and in turn increase the adsorption ability of *OH on NiFeOOH, thereby reducing the OER overpotential. The key role of N-doping in the NiFeOOH for enhancing OER performance is reported for the first time, which will shed light on the design of catalysts.
Показать больше [+] Меньше [-]Ключевые слова АГРОВОК
Библиографическая информация
Эту запись предоставил National Agricultural Library
