Flux model to estimate the transport of mercury species in a contaminated lagoon (Ria de Aveiro, Portugal)

Stoĭchev, Teodor; Tessier, Emmanuel; Almeida, Cristina Marisa R.; Basto, Maria Clara P.; Vasconcelos, Vitor M.; Amouroux, David

Flux model to estimate the transport of mercury species in a contaminated lagoon (Ria de Aveiro, Portugal)

2018

The concentrations of dissolved and particulate inorganic mercury (IHg(II)) and methylmercury (MeHg) from the contaminated Laranjo Bay (main freshwater discharge from the Antuã River) were measured by species-specific isotope dilution during six sampling campaigns at high and at low tide. Different effective riverine concentrations were calculated, based on salinity profiles, for specific hydrological conditions. The export fluxes of total Hg and MeHg (324 and 1.24 mol year⁻¹, respectively) from the bay to the rest of the Aveiro Lagoon are much higher than the input fluxes from the Hg source (3.9 and 0.05 mol year⁻¹) and from the Antuã River (10.4 and 0.10 mol year⁻¹). Resuspension of contaminated sediments from Laranjo Bay is crucial for the transport of both IHg(II) and MeHg. Methylation and/or selective enrichment into biogenic particles is responsible for the mobilization of MeHg. Sorption of dissolved IHg(II) onto suspended particles limits its export flux. This is one of the rarest examples where both speciation fluxes and partitioning of mercury are studied in a contaminated coastal environment. Despite the lower fraction of total MeHg (relative to total Hg), the contaminated lagoon may have an impact on coastal areas, particularly if change in the lagoon geometry occurs, due to sea level rise.

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