Enantioselective synthesis of N-heterocycles via intramolecular Pd(0)-catalysed allylic amination
2013
Olszewska, Beata | Kryczka, Bogusław | Zawisza, Anna
An efficient and stereoselective synthesis of pyrrolidine-, piperidine-, and azepane-type N-heterocycles is described by the intramolecular Pd(0)-catalysed cyclisation of amino allylic carbonates. The use of chiral ligands gave the corresponding heterocyclic derivatives having er values that were from moderate to good.
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