Combined promoting effects of low-Pd-containing and Cu-doped LaCoO3 perovskite supported on cordierite for the catalytic combustion of benzene

Chen, Y. W.; Li B.,; Niu, Q.; Li, L.; Kan, J. W.; Zhu, S. M.; Shen, S. B.

Combined promoting effects of low-Pd-containing and Cu-doped LaCoO3 perovskite supported on cordierite for the catalytic combustion of benzene

2016

The catalytic activities for benzene oxidation and resistance to SO₂ poisoning were tested for a series of Pd/La-Cu-Co-O/cordierite catalysts, which were prepared using a multiple-step impregnation method. The XRD, SEM, and IR characterization techniques were performed to investigate the relationship between the catalytic performance and its physicochemical properties. When Pd/La-Cu-Co-O/cordierite catalysts with Pd loadings of 0.06 and 0.08 % were prepared at a calcination temperature of 500 °C for 5 h, they exhibited similar catalytic activity and sulfur resistance. When the concentration of benzene was 1500 ppm and the GHSV was 20000 h⁻¹, the benzene conversion was above 95 % at a reaction temperature of 350 °C in SO₂ existing at 100 ppm. These results were mainly attributed to the cooperation between La-Cu-Co-O perovskite and the noble metal Pd. Specifically, the addition of copper can strengthen the catalytic activity of La-Co-O/cordierite catalysts by decreasing the crystalline size of the active ingredients. A moderate Pd addition can drastically improve the sulfur resistance and further improve the catalytic activity of the La-Cu-Co-O/cordierite catalyst.

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