N-Heterocyclic carbene ligands bearing poly(ethylene glycol) chains: effect of the chain length on palladium-catalyzed coupling reactions employing aryl chlorides
2015
Fujihara, Tetsuaki | Yoshikawa, Takahiro | Satou, Motoi | Ohta, Hidetoshi | Terao, Jun | Tsuji, Yasushi
N-Heterocyclic carbenes bearing poly(ethylene glycol) chains of different lengths have been designed and employed as ligands in palladium-catalyzed coupling reactions. The catalyst system having longer chains was found to be highly efficient for Suzuki–Miyaura coupling and borylation reactions employing aryl chlorides under mild reaction conditions.
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