Synergistical enhancement by Ni2+ and Tween-80 of nanoscale zerovalent iron dechlorination of 2,2’,5,5’-tetrachlorinated biphenyl in aqueous solution

Wu, Yingxin; Wu, Zihao; Huang, Xiongfei; Simonnot, Marie-Odile; Zhang, Tao; Qiu, Rongliang

Synergistical enhancement by Ni2+ and Tween-80 of nanoscale zerovalent iron dechlorination of 2,2’,5,5’-tetrachlorinated biphenyl in aqueous solution

2015

Effective dehalogenation by nanoscale zerovalent iron (nZVI) has been reported. In this study, the effects of Ni²⁺, Cu²⁺ ions, and the nonionic surfactant Tween-80 on dechlorination of 2,2’,5,5’-tetrachlorinated biphenyl (PCB-52) by nZVI were investigated in aqueous solution. The rate of dechlorination was significantly enhanced by Ni²⁺, while Cu²⁺ had a less significant catalytic effect. Ni²⁺ and Tween-80 used in combination synergistically enhanced dechlorination of PCB-52 by nZVI, although the enhancement by Tween-80 was inhibitory in the presence of Cu²⁺ and insignificant in the absence of both metal ions. Congener specificity in the dechlorination pathway resulted from the preferential retention of ortho-chlorine, which restricted the formation of environmentally toxic coplanar PCB congeners. The application of nZVI dehalogenation enhanced by Ni²⁺ and Tween-80 is a promising technique for posttreatment of PCB-contaminated soil washing solutions.

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