Use of activated dry flowers (ADF) of Alstonia Scholaris for chromium (Vl) removal: equilibrium, kinetics and thermodynamics studies

Śarmā, Sumīta; Kothiyal, Navin Chandra

Use of activated dry flowers (ADF) of Alstonia Scholaris for chromium (Vl) removal: equilibrium, kinetics and thermodynamics studies

2013

Śarmā, Sumīta | Kothiyal, Navin Chandra

In this study, a natural adsorbent (activated dry flowers (ADF)) was prepared from plant-derived waste biomass by chemical activation and employed for chromium (VI) removal from aqueous medium using experimental batch technique. Experiments were carried out as function of adsorbent dosage, pH, and contact time. The maximum chromium (VI) removal was observed at initial pH 3 (~94% removal). The equilibrium data was fitted well to Langmuir isotherm. The adsorption capacity of ADF was found to be 4.40 (mg chromium (VI)/g) which was comparable to the adsorption capacity of some other adsorbents documented. Among various kinetic models applied, pseudo second-order model was found to explain the kinetics of chromium (VI) adsorption most effectively (R2>0.99). Thermodynamic parameters such as ΔG, ΔS, and ΔH shows that adsorption process was spontaneous and endothermic at all the concentration ranges studied. Desorption of chromium (VI) with 2 N NaOH was effective (~71%) and, hence, there exists the possibility of recycling the ADF. The major advantages of using ADF as an adsorbent are due to its effectiveness in reducing the concentration of chromium (VI) to very low levels. It requires little processing and is reversible as well as eco-friendly in contrast to traditional methods.

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