Soil type affects migration pattern of airborne Pb and Cd under a spruce-beech forest of the UN-ECE integrated monitoring site Zöbelboden, Austria

Kobler, Johannes; Fitz, Walter J.; Dirnböck, Thomas; Mirtl, Michael

Soil type affects migration pattern of airborne Pb and Cd under a spruce-beech forest of the UN-ECE integrated monitoring site Zöbelboden, Austria

2010

Kobler, Johannes | Fitz, Walter J. | Dirnböck, Thomas | Mirtl, Michael

Anthropogenic trace element emissions have declined. However, top soils all over the world remain enriched in trace elements. We investigated Pb and Cd migration in forest soils of a remote monitoring site in the Austrian limestone Alps between 1992 and 2004. Large spatial variability masked temporal changes in the mineral soil of Lithic Leptosols (Skeltic), whereas a significant reduction of Pb concentrations in their forest floors occurred. Reductions of concentrations in the less heterogeneous Cambisols (Chromic) were significant. In contrast, virtually no migration of Pb and Cd were found in Stagnosols due to their impeded drainage. Very low element concentrations (<1 μg l−1) in field-collected soil solutions using tension lysimeters (0.2 μm nylon filters) imply that migration largely occurred by preferential flow as particulate-bound species during intensive rainfall events. Our results indicate that the extent of Pb and Cd migration in soils is largely influenced by soil type. Comparison between soil solid phase and soil solution concentrations imply that trace element migration largely occurred by preferential flow as particulate-bound species.

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