Disentangling disorder in the three-dimensional coordination network of {Ag₃[Tris(2-pyridylmethyl)cyclotriguaiacylene]₂}(PF₆)₃

Sumby, C.; Hardie, M.

Disentangling disorder in the three-dimensional coordination network of {Ag₃[Tris(2-pyridylmethyl)cyclotriguaiacylene]₂}(PF₆)₃ | Disentangling disorder in the three-dimensional coordination network of {Ag(3)[Tris(2-pyridylmethyl)cyclotriguaiacylene](2)}(PF(6))(3)

2005

Sumby, C. | Hardie, M.

The crystalline complex {Ag3[Tris(2-pyridylmethyl)cyclotriguaiacylene]2}(PF6)3 has been synthesized and shown by X-ray crystallography to have a disordered three-dimensional cubic coordination network structure. The coordination network features a back-to-back stacking of the molecular host-type ligands into tetrahedral clusters, and the PF6- anions act as both intracavity guests and lattice-type guests. Disentangling the network disorder gives a 4-fold interpenetrating (10,3)-a net.

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Christopher J. Sumby and Michaele J. Hardie

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