We analysed the variability of equivalent black carbon (BC) and ozone (O3) at the global WMO/GAW station Nepal Climate Observatory-Pyramid (NCO-P, 5079 m a.s.l.) in the southern Himalayas, for evaluating the possible contribution of open vegetation fires to the variability of these short-lived climate forcers/pollutants (SLCF/SLCP) in the Himalayan region.We found that 162 days (9% of the data-set) were characterised by acute pollution events with enhanced BC and O3 in respect to the climatological values. By using satellite observations (MODIS fire products and the USGS Land Use Cover Characterization) and air mass back-trajectories, we deduced that 56% of these events were likely to be affected by emissions from open fires along the Himalayas foothills, the Indian Subcontinent and the Northern Indo-Gangetic Plain.These results suggest that open fire emissions are likely to play an important role in modulating seasonal and inter-annual BC and O3 variability over south Himalayas.

A systematic study on the chemical characteristics of ambient PM2.5, collected during October-2011 to March-2012 from a source region (Patiala: 30.2°N, 76.3°E; 250 m amsl) of biomass burning emissions in the Indo-Gangetic Plain (IGP), exhibit pronounced diurnal variability in mass concentrations of PM2.5, NO3−, NH4+, K+, OC, and EC with ∼30–300% higher concentrations in the nighttime samples. The average WSOC/OC and SO42−/PM2.5 ratios for the daytime (∼0.65, and 0.18, respectively) and nighttime (0.45, and 0.12, respectively) samples provide evidence for secondary organic and SO42− aerosol formation during the daytime. Formation of secondary NO3− is also evident from higher NH4NO3 concentrations associated with lower temperature and higher relative humidity conditions. The scattering species (SO42− + NO3− + OC) contribute ∼50% to PM2.5 mass during October–March whereas absorbing species (EC) contribute only ∼4% in October–February and subsequently increases to ∼10% in March, indicating significance of these species in regional radiative forcing.

Pristine mountains are ideal settings to study transport and behavior of persistent organic pollutants (POPs) along gradients of climate and land cover. The present work investigated the concentrations and patterns of 28 organochlorine pesticides (OCPs), 25 polychlorinated biphenyl (PCBs), 13 polybrominated diphenyl ethers (PBDEs), and 3 hexabromocyclododecane (HBCDs) isomers in the air of the Shergyla Mountain, southeastern Tibetan Plateau. Endosulfan І, hexachlorobenzene, pentachlorobenzene, hexachlorocyclohexanes and dichlorodibenzotrichloroethane and its degradation products (DDTs) were the predominant compounds while PBDEs and HBCDs showed the lowest background concentrations. Most of the target POPs had significantly higher concentrations in summer than those in winter. Increasing trends of the concentrations of DDTs and endosulfan were found with increasing altitude on the western slope in the Shergyla Mountain. Potential forest filter effect was observed based on the lower air concentrations of the target POPs in the forest than the ones out of the forest.

Studies have been devoted to the transport and accumulation of persistent organic pollutants (POPs) in mountain environments. The Himalayas have the widest altitude gradient of any mountain range, but few studies examining the environmental behavior of POPs have been performed in the Himalayas. In this study, air, soil, and leaf samples were collected along a transect on the southern slope of the Himalayas, Nepal (altitude: 135–5100 m). Local emission occurred in the lowlands, and POPs were transported by uplift along the slope. During the atmospheric transport, the HCB proportion increased from the lowlands (20%) to high elevation (>50%), whereas the proportions of DDTs decreased. The largest residue of soil POPs appeared at an altitude of approximately 2500 m, and may be related to absorption by vegetation and precipitation. The net deposition tendencies at the air–soil surface indicated that the Himalayas may be a ‘sink’ for DDTs and PCBs.

Long–range transport of the Saharan dust plumes during May–August of each year is a prominent feature over the tropical North Atlantic. Observations of temperature profiles are highly desirable in clarifying the impacts of the Saharan dust plumes over the tropical North Atlantic. In this work we evaluate positive temperature anomalies (inversions in the lower troposphere) in the North Atlantic low troposphere originating from Western Africa, and to examine the correspondence of these events to Saharan dust plumes, using several temperature sources and satellite–detected measurements of Aerosol Index. We combine profiles of temperature observations from FORMOSAT–3/COSMIC (F3C) with aerosol observations from Ozone Monitoring Instrument (OMI) to provide direct evidence of the Saharan dust plumes modifying environmental stability. The F3C observations show good profile measurements compared with the radiosondes in the lower troposphere, with the average temperature differences less than 0.5K. The F3C results were also compared with the Aqua Advanced Infrared Radiation Sounder (AIRS) and meteorological analyses from the National Centers for Environmental Predictions (NCEP), the United Kingdom Met Office (UKMO), and the European Centre for Medium Range Weather Forecast (ECMWF). Our results show that hot air plumes are associated with the Saharan dust plumes during their transport across the tropical North Atlantic. There were eleven distinctive hot air plumes during May–August 2007 and 2008, respectively. These hot air plumes increase environmental temperatures below 5–km altitudes, with the maximum increase of 1–2K around 2–km. This leads to increase of environmental stability below 2–km altitudes and decrease of environmental stability between 2– and 5–km altitudes. By changing the vertical distribution of environmental stability, the Saharan dust plumes act to stabilize environmental air below 2–km while destabilize environmental air from 2– to 5–km altitudes. These results are distinctively presented in the F3C and AIRS observations but less obvious in the meteorological analyses.

There is a growing concern of seawater intrusion to freshwater aquifers due to groundwater overexploitation in the eastern coastal belt of Southern India. The problem becomes complex in the regions where industrial effluents are also contaminating the freshwater aquifers. In order to understand the hydrochemical complexity of the system, topographic elevation, static water level measurements, major ion chemistry, ionic cross plots, water type contours and factor analysis were applied for 144 groundwater samples of shallow and deep sources from Quaternary and Tertiary coastal aquifers, located within the industrial zone of 25 km2 area near Cuddalore, Southern India. The ionic cross plots indicates dissolution of halite minerals from marine sources and seawater mixing into inland aquifers up to the level of 9.3%. The factor analysis explains three significant factors totaling 86.3% of cumulative sample variance which includes varying contribution from marine, industrial effluent and freshwater sources.

We compared succession and characteristics of the macrobenthic community in a small-scale experimental intertidal sandflat constructed in the artificial diversion channel of the Ohta River Estuary with those of three natural intertidal sandflats at lower elevation in the same channel. The macrobenthic population density in the man-made intertidal sandflat increased significantly between 3 and 9months after construction. Simplisetia erythraeensis was dominant (98% of individuals) after 9months, but its proportion gradually declined with the increase in biodiversity until 26months, indicating that succession of the macrobenthic community was nearly complete by 26months. The macrobenthic community in the man-made intertidal sandflat differed from those of the three natural intertidal sandflats, and its population density was about double that at the natural sites, with smaller temporal fluctuation. The different structures of the macrobenthic communities in the man-made and natural intertidal sandflats were likely caused by differences in elevation.

The vertical concentration profiles and source contributions of polycyclic aromatic hydrocarbons (PAHs) and n-alkanes in respirable particle samples (PM₄) collected at 10, 100, 200 and 300-m altitude from the Milad Tower of Tehran, Iran during fall and winter were investigated. The average concentrations of total PAHs and total n-alkanes were 16.7 and 591 ng/m³, respectively. The positive matrix factorization (PMF) model was applied to the chemical composition and wind data to apportion the contributing sources. The five PAH source factors identified were: ‘diesel’ (56.3 % of total PAHs on average), ‘gasoline’ (15.5 %), ‘wood combustion, and incineration’ (13 %), ‘industry’ (9.2 %), and ‘road soil particle’ (6.0 %). The four n-alkane source factors identified were: ‘petrogenic’ (65 % of total n-alkanes on average), ‘mixture of petrogenic and biomass burning’ (15 %), ‘mixture of biogenic and fossil fuel’ (11.5 %), and ‘biogenic’ (8.5 %). Source contributions by wind sector were also estimated based on the wind sector factor loadings from PMF analysis. Directional dependence of sources was investigated using the conditional probability function (CPF) and directional relative strength (DRS) methods. The calm wind period was found to contribute to 4.4 % of total PAHs and 5.0 % of total n-alkanes on average. Highest average concentrations of PAHs and n-alkanes were found in the 10 and 100 m samples, reflecting the importance of contributions from local sources. Higher average concentrations in the 300 m samples compared to those in the 200 m samples may indicate contributions from long-range transport. The vertical profiles of source factors indicate the gasoline and road soil particle-associated PAHs, and the mixture from biogenic and fossil fuel source-associated n-alkanes were mostly from local emissions. The smaller average contribution of diesel-associated PAHs in the lower altitude samples also indicates that the restriction of diesel-fueled vehicle use in the central area of Tehran has been effective in reducing the PAHs concentration.

The snow capacity for storage of a large number of pollutants such as polybromodiphenyl ethers (PBDE), including BDE-209, polycyclic aromatic hydrocarbons (PAHs), polychlorobiphenyls (PCBs), hexachlorocyclohexanes (HCHs; α- and γ-isomers), endosulfans (α- and β-isomers and the sulphate residue) and hexachlorobenzene (HCB), in a steep altitudinal gradient (1,101–2,500 m above sea level (asl); maximum planar distance 16 km) in a typical European mountain system, the Tyrolean Alps (Austria), was studied here for the first time. Snow samples representing the whole snowpack accumulated at the end of the cold season were collected in all cases. The snow specific surface area (SSA) of these samples, 140–260 cm² g⁻¹, was characteristic of aged snow with low retention capacity. PAHs were the pollutant group in highest concentrations (500–8,400 pg L⁻¹). PCBs and PBDEs were found in concentrations of 460–900 and 8.5–290 pg L⁻¹, respectively. From the fourteen investigated BDE congeners, only BDE-47, BDE-99, BDE-100 and BDE-209 were found above the detection limit, which is consistent with the results found in the only previous study in the Tatra Mountains (Slovakia) which also involved a steep gradient (1,683–2,634 m asl; maximum planar distance 5 km; Arellano et al. 2011) and confirm the capacity of these low-volatile compounds for long-range transport from distant sources. HCB was found in a concentration range of 34–55 pg L⁻¹. Snow deposition fluxes of PCB-118, PCB-153, γ-HCH, α-endosulfan and BDE-47 showed statistically significant correlations with altitude, involving higher values at higher elevation. This trend may reflect cold trapping effects in view of the snow particle contents and SSA values. However, these gradients were only significant for this limited number of compounds within each pollutant group which may be explained by differences in physical-chemical properties of the compounds and the limited capacity of the aged snow for organic pollutant retention. In some other cases, for example benzo[a]pyrene, the observed vertical gradients may reflect higher preservations at lower temperatures.

Carbon monoxide (CO) is of great interest as a restriction factor for pollutants related to incomplete combustions. This study attempted to evaluate CO emission in East China using the analytical Bayesian inverse method and observations at Mount Hua in springtime. The mixing ratio of CO at the receptor was calculated using 5-day source-receptor relationship (SRR) simulated by a Lagrangian Particle Dispersion Model (FLEXPART) and CO emission flux. The stability of the inversion solution was evaluated on the basis of repeated random sampling simulations. The inversion results demonstrated that there were two city cluster regions (the Beijing–Tianjin–Hebei region and the low reaches of the Yangtze River Delta) where the difference between a priori (Intercontinental Chemical Transport Experiment-Phase B, INTEX-B) and a posteriori was statistically significant and the a priori might underestimate the CO emission flux by 37 %. A correction factor (a posteriori/a priori) of 1.26 was suggested for CO emission in China in spring. The spatial distribution and magnitude of the CO emission flux were comparable to the latest regional emission inventory in Asia (REAS2.0). Nevertheless, further evaluation is still necessary in view of the larger uncertainties for both the analytical inversion and the bottom-up statistical approaches.