Evidence for long-term changes in the soil composition of selected organic compounds, brought about by exchanges with the atmosphere, is briefly reviewed. In the case of some compounds - such as benzo(a)pyrene and octachlorodibenzo-p-dioxin, soils may be significant long-term environmental sinks for atmospherically-derived material. In other cases - such as phenanthrene and some of the lighter PCBs, de-gassing or volatilisation from soil back to the air can occur under certain conditions. Hence the soil may act as a "short-term" sink, and a potential source to atmosphere. Indeed, for some 'semi-volatile' compounds used in large quantities in the past - such as PCBs, soil outgassing may actually be an extremely important source to contemporary air. Furthermore, soil outgassing from areas of former high use may provide an important driving mechanism for continued "global cycling" of a range of semi-volatile organochlorine compounds.

International audience | Wintertime anticyclonic conditions, associated with clear sky and cold nights, trigger the formation of persistent layers of stable air over the ground. In an urban area, these persistent layers lead to poor air quality, especially when the terrain is mountainous. This is particularly the case in the Arve River Valley near the city of Passy, located 20 km downstream of Chamonix-Mont-Blanc, where air quality stands among the poorest ones in France.Beyond the monitoring of air quality, as performed by the Auvergne-Rhône-Alpes air quality agency or within the scientific project DECOMBIO led by the Institute for Geosciences and the Environment (IGE), knowledge of the atmospheric dynamics at the valley scale should be gained to understand how pollutants are dispersed. This is the motivation of the Passy project, which started in 2014. It relies on the Passy-2015 field experiment, whereof presentation, along with the discussion of a few results, is the purpose of the present paper. The objective of this field experiment is to document the atmospheric dynamics in the Arve River Valley during wintertime pollution episodes.The work conducted during the Passy project and the analysis of the Passy-2015 field experiment will benefit from a several-year long collaboration among the different partners. The knowledge thus gained will contribute to refine weather forecast and air quality prediction in the Arve River Valley and, more generally, in mountain urban areas under stable conditions. From an operational perspective, our goal is to improve our ability to forecast critical events such as low temperatures, ice and fog formation, pollution events or locations subject to high pollutant concentration. | Les conditions anticycloniques hivernales (ciel clair, nuits froides) conduisent à la formation de couches stables persistantes qui favorisent les épisodes de pollution, particulièrement en terrain montagneux. La vallée de l’Arve est très sensible à ce phénomène, en particulier près de la ville de Passy (Haute-Savoie), située à 20 kilomètres en aval de Chamonix-Mont-Blanc, où la qualité de l’air est l’une des moins bonnes de France.Au-delà du suivi de la qualité de l’air, tel que réalisé par Atmo Auvergne-Rhône-Alpes ou par le projet DECOMBIO piloté par l’Institut des Géosciences et de l’Environnement (IGE), il est primordial d’améliorer la connaissance de la dynamique atmosphérique à l’échelle de la vallée en conditions stables pour mieux comprendre comment, couplée au cycle et à la géographie des émissions, elle pilote la dispersion des polluants. C’est la motivation du projet Passy, initié en 2014. Ce projet s’appuie sur les observations de la campagne Passy-2015, présentées dans cet article avec quelques premiers résultats. L’objectif général de cette campagne est de documenter la dynamique atmosphérique au sein de la vallée de l’Arve lors des épisodes de pollution hivernale.Les travaux menés dans le cadre du projet et de l’analyse des données de la campagne s’inscrivent au sein d’une collaboration sur plusieurs années entre les différents partenaires. Ils contribueront à affiner la prévision du temps et de la qualité de l’air dans ce type de vallée, et plus généralement en conditions stables. Il s’agit en particulier d’améliorer la capacité à prévoir des phénomènes critiques, comme les températures minimales, le verglas, le brouillard, les évènements de pollution ou encore les zones de pollution intense.

Les territoires périurbains, zones de transition entre les zones urbaines et rurales, sont soumis à de nombreuses pollutions à la fois gazeuses et particulaires. Ces pollutions proviennent de sources locales comme les activités résidentielles, le trafic routier et les activités agricoles, mais également de sources régionales issues des activités urbaines et des émissions des zones (pseudo-)naturelles adjacentes. Cet article présente une synthèse des différentes sources de pollution affectant la qualité de l’air en milieu périurbain. Il est évident que les pollutions purement anthropiques ne peuvent être dissociées de celles issues du fonctionnement des écosystèmes (pseudo-)naturels dans ces espaces. Enfin, les enjeux vis-à-vis de l’agriculture périurbaine, fortement présente et en développement du fait d’une volonté de consommer des productions locales, sont discutés. | Periurban areas, zone of transition between urban and rural areas, are submitted to several sources of pollution, both gaseous and particulate. These pollutions originate from local sources such as residential sector, traffic road and agricultural activities, but also from regional ones from adjacent urban and (pseudo-)natural areas. This paper presents a synthesis of the different sources affecting air quality in periurban areas. It is clear that pollutions from anthropogenic activities cannot be fully dissociated to those from (pseudo-)natural ecosystem functioning in these areas. Finally, the atmospheric pollution issues are discussed in emphasis with periurban agriculture, already present and under development in these areas due to the development of short food supply chains and local food consumptions.

International audience

International audience | Periurban areas, zone of transition between urban and rural areas, are submitted to several sources of pollution, both gaseous and particulate. These pollutions originate from local sources such as residential sector, traffic road and agricultural activities, but also from regional ones from adjacent urban and (pseudo-)natural areas. This paper presents a synthesis of the different sources affecting air quality in periurban areas. It is clear that pollutions from anthropogenic activities cannot be fully dissociated to those from (pseudo-)natural ecosystem functioning in these areas. Finally, the atmospheric pollution issues are discussed in emphasis with periurban agriculture, already present and under development in these areas due to the development of short food supply chains and local food consumptions. | Les territoires périurbains, zones de transition entre les zones urbaines et rurales, sont soumis à de nombreuses pollutions à la fois gazeuses et particulaires. Ces pollutions proviennent de sources locales comme les activités résidentielles, le trafic routier et les activités agricoles, mais également de sources régionales issues des activités urbaines et des émissions des zones (pseudo-)naturelles adjacentes. Cet article présente une synthèse des différentes sources de pollution affectant la qualité de l’air en milieu périurbain. Il est évident que les pollutions purement anthropiques ne peuvent être dissociées de celles issues du fonctionnement des écosystèmes (pseudo-)naturels dans ces espaces. Enfin, les enjeux vis-à-vis de l’agriculture périurbaine, fortement présente et en développement du fait d’une volonté de consommer des productions locales, sont discutés.

International audience | Consumption of water polluted by faecal contaminants is responsible for 2 million deaths annually, most of which occur in developing countries without adequate sanitation. In tropical aquatic systems, streambeds can be reservoirs of persistent pathogenic bacteria and high rainfall can lead to contaminated soils entering streams and to the resuspension of sediment-bound microbes in the streambed. Here, we present a novel method using fallout radionuclides (Be-7 and Pb-210(xs)) to estimate the proportions of Escherichia coli, an indicator of faecal contamination, associated with recently eroded soil particles and with the resuspension of streambed sediments. We show that using these radionuclides and hydrograph separations we are able to characterize the proportion of particles originating from highly contaminated soils and that from the resuspension of particle-attached bacteria within the streambed. We also found that although overland flow represented just over one tenth of the total flood volume, it was responsible for more than two thirds of the downstream transfer of E. coli. We propose that data obtained using this method can be used to understand the dynamics of faecal indicator bacteria (FIB) in streams thereby providing information for adapted management plans that reduce the health risks to local populations.

International audience | Consumption of water polluted by faecal contaminants is responsible for 2 million deaths annually, most of which occur in developing countries without adequate sanitation. In tropical aquatic systems, streambeds can be reservoirs of persistent pathogenic bacteria and high rainfall can lead to contaminated soils entering streams and to the resuspension of sediment-bound microbes in the streambed. Here, we present a novel method using fallout radionuclides (Be-7 and Pb-210(xs)) to estimate the proportions of Escherichia coli, an indicator of faecal contamination, associated with recently eroded soil particles and with the resuspension of streambed sediments. We show that using these radionuclides and hydrograph separations we are able to characterize the proportion of particles originating from highly contaminated soils and that from the resuspension of particle-attached bacteria within the streambed. We also found that although overland flow represented just over one tenth of the total flood volume, it was responsible for more than two thirds of the downstream transfer of E. coli. We propose that data obtained using this method can be used to understand the dynamics of faecal indicator bacteria (FIB) in streams thereby providing information for adapted management plans that reduce the health risks to local populations.

Atmospheric levels of chlorinated paraffins (CPs) at five remote, six rural and four urban sites in Australia were measured using XAD-2 passive air samplers (XAD-PAS). While long-chain CP (LCCP, C>₁₇) levels were below method detection limits (MDLs), short-chain CPs (SCCPs, C₁₀₋₁₃) and, for the first time, medium-chain CPs (MCCPs, C₁₄₋₁₇) and CPs with a carbon chain length of nine (CP–C9) were found at many sites (88%, 81% and 88%, respectively) across the Australian continent, representing a range of environmental conditions. Applying preliminary sampling rates of the XAD-PAS for CPs, gaseous CP levels in Australian air were <MDL-1.3 and <MDL-1.8 ng/m³ for ΣSCCPs and ΣMCCPs, respectively, with a significant decreasing trend from more densely to less densely populated areas. Atmospheric median levels in this study (0.37 and 0.47 ng/m³ for SCCPs and MCCPs, respectively) were at the lower end of the median range (0.32–10 and 3.0–4.2 ng/m³ for SCCPs and MCCPs, respectively) reported for CPs at predominantly urban or industrial sites elsewhere (apart from China and extremely remote sites such as Antarctica). Principal component analysis matched the SCCP and MCCP congener group patterns in samples with those found in commercial mixtures, indicating a prevalence of less chlorinated congener groups in the Australian atmosphere. Information about the Australian production, use and disposal of CPs as well as their levels in other environmental matrices, including humans, is needed for assessing their emissions, behaviour, fate and potential exposure.

Research on the atmospheric occurrence of short chain chlorinated paraffins (SCCPs) in industrialized areas is scarce. In this study, we investigated the concentrations, profile, and spatial distribution of SCCPs in the highly industrialized and developed areas of the Yangtze River Delta (YRD) in China using polyurethane foam passive air samplers. Sampling was performed during two separate periods in 2011. The concentrations of atmospheric SCCPs ranged from 6.1 to 63 ng m⁻³ in summer and 6.2–42 ng m⁻³ in winter. The C₁₀ and C₁₁ groups were the predominant carbon groups in all the samples. Different congener patterns between summer and winter were found, indicating that congeners in the air in winter may be influenced by local and external sources. The highest level of SCCPs was found in Suzhou, which is a highly industrialized area with many manufactories including electronic industries and plastic factories. Higher levels of SCCPs were found in the air than polychlorinated biphenyls (PCBs), organochlorine pesticides (OCPs), and polybrominated diphenyl ether (PBDEs), suggesting that the production and use of SCCPs were much higher than prohibited or restricted persistent organic pollutants (e.g., PCBs, OCPs, and PBDEs). Future studies should investigate the different sources of atmospheric SCCPs by conducting a comprehensive assessment of SCCP exposure.