Elemental compositions of water, and surface and subsurface soils indicate characterization and mobilization of elements within soil profiles. The chemical variations of groundwater (n = 21) and surface and subsurface soils (n = 18 each) of the Polpithigama area were examined to determine elemental spatial variation in the area. Physico-chemical parameters (pH, electrical conductivity (EC), dissolved oxygen (DO), oxygen reduction potential (ORP)) and NO₃⁻, PO₄²⁻, Mn, Fe, and F were analyzed for the water samples in the field using field test kits. Soil samples were analyzed using X-ray fluorescence for 22 major and trace elements. Iron, Mn, NO₃⁻, and PO₄²⁻ concentrations in water are lower than the threshold values of WHO. The fluoride content was increased with high elevation even within a short distance. The fluoride and phosphate are highly variable between the soil layers and are preferably retained in the surface soil. The vertical variation is resulted by intensive weathering under tropical conditions, mobility of ions, variation of elements, and variation of soil constituents such as different contents of organic matter and clay content consisting of high total sulfur (TS) contents. Migration of some ions to the groundwaters of the area is possible due to high mobility of elements and thus the compositions of some elements show variations in the surface and subsurface soils.

In order to investigate the effects of canopy-dependent processes on throughfall chemistry, comparative studies on the chemical composition of throughfall were carried out in five characteristic forest types of the southeastern United States within Fort Benning Military Installation from January 2002 to August 2003. The concentrations and fluxes of and total organic carbon (TOC), total Kjeldahl nitrogen (TKN), and total phosphorus (TP) were determined in rainfall and throughfall. Seasonal variations in chemical fluxes were also evaluated. Throughfall concentrations of TOC, TKN, and TP in matured pine stand were higher than in rainfall and other forest stands. Throughfall nutrient concentrations in wetland were lowest as compared to rainfall as well as hardwood, mixed, plantation, and pine stands. The average TOC, TKN, and TP concentrations in the matured pine stand were 17.2, 0.74, and 0.057 mg/L, respectively. In wetland stands, average concentrations of TOC, TKN, and TP were 4.0, 0.54, and 0.034 mg/L, respectively. Hardwood stand had the lowest TKN concentration of 0.53 mg/L. Nutrient fluxes were generally higher during the dormant season (November–April) as compared to the growing season (May–October). The highest and lowest TOC fluxes during dormant season were contributed from pine stand (801.7 g/ha) and wetland stand (186.2 g/ha), respectively. Rainfall was the major contributor of TKN fluxes in growing season (32.3 g/ha) as well as in dormant season (34.1 g/ha). Similarly, highest TP flux was produced in mixed stand (2.7 g/ha) during the dormant season. Enrichment ratios of nutrients reveal that, in general, forest stands used up nutrients during growing season and washed off during the dormant season.

The paper presents the spatio-temporal variation of chemical compositions (organic carbon (OC), elemental carbon (EC), and water-soluble inorganic ionic components (WSIC)) of particulate matter (PM₁₀) over three locations (Delhi, Varanasi, and Kolkata) of Indo Gangetic Plain (IGP) of India for the year 2011. The observational sites are chosen to represent the characteristics of upper (Delhi), middle (Varanasi), and lower (Kolkata) IGP regions as converse to earlier single-station observation. Average mass concentration of PM₁₀ was observed higher in the middle IGP (Varanasi 206.2 ± 77.4 μg m⁻³) as compared to upper IGP (Delhi 202.3 ± 74.3 μg m⁻³) and lower IGP (Kolkata 171.5 ± 38.5 μg m⁻³). Large variation in OC values from 23.57 μg m⁻³ (Delhi) to 12.74 μg m⁻³ (Kolkata) indicating role of formation of secondary aerosols, whereas EC have not shown much variation with maximum concentration over Delhi (10.07 μg m⁻³) and minimum over Varanasi (7.72 μg m⁻³). As expected, a strong seasonal variation was observed in the mass concentration of PM₁₀ as well as in its chemical composition over the three locations. Principal component analysis (PCA) identifies the contribution of secondary aerosol, biomass burning, fossil fuel combustion, vehicular emission, and sea salt to PM₁₀ mass concentration at the observational sites of IGP, India. Backward trajectory analysis indicated the influence of continental type aerosols being transported from the Bay of Bengal, Pakistan, Afghanistan, Rajasthan, Gujarat, and surrounding areas to IGP region.

Lichens are known to synthesize a variety of secondary metabolites having multifunctional activity in response to external environmental condition. Two common lichen extrolites, atranorin and salazinic acid, are known to afford antioxidant as well as photoprotectant nature depending on the abiotic/biotic stress. The present investigation aims to study the influence of altitudinal gradient on the quantitative profile of atranorin and salazinic acid in three lichen species, Bulbothrix setschwanensis (Zahlbr.) Hale, Everniastrum cirrhatum (Fr.) Hale and Parmotrema reticulatum (Taylor) Choisy, Parmeliaceae using liquid chromatography-mass spectrometry (LC-MS/MS) technique. Samples were collected from high-altitude area, usually considered as non-polluted sites of Garhwal Himalaya. Characterization and quantification of the lichen substances in samples were carried out comparing with the standards of atranorin and salazinic acid. Results indicated significant variation in the chemical content with the rising altitude. All the three lichen species showed higher quantities of chemical substances with the altitudinal rise, while among the three lichen species, E. cirrhatum showed the highest quantity of total lichen compounds. The higher abundance and frequency of E. cirrhatum with increasing altitude as compared to B. setschwanensis and P. reticulatum may be attributed due to the presence of higher quantity of photoprotecting/antioxidant chemicals especially salazinic acid. Thus, the present study shows the prominent role of secondary metabolite in wider ecological distribution of Parmelioid lichens at higher altitudes.

Ecotoxicity tests are often conducted following standard methods, and thus carried out at a fixed water temperature under controlled laboratory conditions. Yet, toxicity of a chemical contaminant may vary in a temperature-dependent manner, depending on the physiology of the test organism and physicochemical properties of the chemical. Although an assessment factor of 10 (AF10) is commonly adopted to account for variability in toxicity data related to temperature in the development of water quality guidelines and/or ecological risk assessment, no one has ever rigorously assessed the appropriateness of AF10 to account for potential variation in temperature-dependent chemical toxicity to aquatic organisms. This study, therefore, aims to address this issue through a meta-analysis by comparing median lethal concentration data for nine chemicals (cadmium, copper, nickel, lead, silver, zinc, arsenic, selenium and DDT) on a range of freshwater ectothermic animal species at different temperatures, and to assess whether AF10 is under- or over-protective for tropical and temperate freshwater ecosystems. Our results reveal varying extents of interaction between temperature and different chemicals on organisms and the complexity of these interactions. Applying AF10 sufficiently protects 90 % of the animal species tested over a range of temperatures for cadmium, copper, nickel, silver, zinc and DDT in the tropics, but it is insufficient to adequately encompass a larger temperature variation for most studied chemicals in temperate regions. It is therefore important to set specific AFs for different climatic zones in order to achieve the desired level of ecosystem protection.