Polycyclic aromatic hydrocarbons (PAHs) and nitro-polycyclic aromatic hydrocarbons (NPAHs) are toxic pollutants mainly produced during fossil fuel combustion. Domestic coal stoves, which emit large amounts of PAHs and NPAHs, are widely used in the Chinese countryside. In this study, emission factors (Efs) for 13 PAH species and 21 NPAH species for four raw coal (three bituminous and one anthracite), one honeycomb briquette, and one crop residue pellet (peanut hulls) samples burned in a typical Chinese rural cooking stove were determined experimentally. The PAH and NPAH Efs for the six fuels were 3.15–49 mg/kg and 0.32–100 μg/kg, respectively. Peanut hulls had very high Efs for both PAHs and NPAHs, and honeycomb briquettes had the lowest Efs. 2-Nitropyrene and 2-nitrofluoranthene, which are NPAHs typically found in secondary organic aerosol, were detected in the emissions from some fuels, suggesting that chemical reactions may have occurred in the dilution tunnel between the flue gas leaving the stove and entering the sampler. The 1-nitropyrene to pyrene diagnostic ratios for coal and peanut hulls were 0.0001 ± 0.0001 and 0.0005, respectively. These were in the same order of magnitude as reference ratios for emissions during coal combustion. The 6-nitrobenzo[a]pyrene to benzo[a]pyrene ratios for the fuels were determined, and the ratios for coal and peanut hulls were 0.0010 ± 0.0001 and 0.0014, respectively. The calculated potential toxic risks indicated that peanut hull emissions were very toxic, especially in terms of NPAHs, compared with emissions from the other fuels.

Both China and UNEP recommend replacing raw coal chunks with coal briquettes in household sector as clean coal technology (CCT), which has been confirmed by the decreased emissions of particulate matter and black carbon. However, the clean effect has never been systematically checked by other pollutants like polycyclic aromatic hydrocarbons (PAHs). In this study, 5 coals with different geological maturities were processed as both chunks and briquettes and burned in 3 typical coal stoves for the measurement of emission factors (EFs) of particle-bound PAHs. It was found that the EFs of 16 parent PAHs, 26 nitrated PAHs, 6 oxygenated PAHs, and 8 alkylated PAHs for coal briquettes were 6.90 ± 7.89, 0.04 ± 0.03, 0.65 ± 0.40, and 72.78 ± 18.23 mg/kg, respectively, which were approximately 3.1, 3.7, 1.9, and 171 times those for coal chunks, respectively. Such significant increases in PAH emissions increased human health risk and challenged the policy of CCT.

Polycyclic aromatic hydrocarbon (PAH) extracts of fine particles (PM₂.₅) collected from combustion of seven wood species and briquettes were tested for mutagenic activities using Ames test with Salmonella typhimurium TA98 and TA100. The woods were Pinus pinaster (maritime pine), Eucalyptus globulus (eucalypt), Quercus suber (cork oak), Acacia longifolia (golden wattle), Quercus faginea (Portuguese oak), Olea europea (olive), and Quercus ilex rotundifolia (Holm oak). Burning experiments were done using woodstove and fireplace, hot start and cold start conditions. A mutagenic response was recorded for all species except golden wattle, maritime pine, and briquettes. The mutagenic extracts were not correlated with high emission factors of carcinogenic PAHs. These extracts were obtained both from two burning appliances and start-up conditions. However, fireplace seemed to favour the occurrence of mutagenic emissions. The negative result recorded for golden wattle was interesting, in an ecological point of view, since after confirmation, this invasive species, can be recommended for domestic use.

Bioenergy, which originated from agricultural crop residue and industrial waste, has been studied for sustainable energy generation. As a raw material for briquettes production, agricultural-crop residue, industrial waste, sewage, sludge, or other plants can be used. Briquettes have numerous advantages as they directly help to reduce waste generation and handling. The possibilities of the briquetting, qualities, and other essential factors for briquette production have been discussed. The alternative methods of Briquetting have been addressed with the comparison. The characteristics of the raw materials for briquettes production have been discussed to identify the best agricultural crop residue for briquettes. The properties of binding agents for the briquetting process have been discussed to identify the most practically available binding agent.

The inadequate disposal of urban pruning residues can cause significant environmental impacts. The objective of the study presented herein was to quantify the carbon footprint and analyze four disposal scenarios for the urban pruning waste of the city of Joao Pessoa (Northeast Brazil). Software SimaPro was utilized for the quantification of the carbon footprint, with the IPCC 2013 GWP 100y impact evaluation method. The end-of-life treatments considered were sanitary landfilling (with and without collection of methane), simple municipal incineration, and reutilization of wood (transformation into briquettes). The results indicated that simple disposal in sanitary landfill generated 136.34 kg CO₂/t urban pruning waste collected (highest carbon footprint), sanitary landfill with methane collection emitted 113.43 kg CO₂/t waste, municipal incineration generated 71.31 kg CO₂/t waste, and reutilization of woody residues was the scenario with the lowest carbon footprint, with 27.82 kg CO₂/t waste. This study demonstrated that reutilization of biomass, besides being environmentally viable, presents the potential to contribute to the city’s environmental quality, including the possibility of being used to obtain carbon credits.

Dried leaves are a potential source of energy although these are not commonly used beside to satisfy daily energy demands in rural areas. This paper aims at preparing a leafy biomass feedstock in the form of briquettes which can be directly used for combustion or to extract the combustible gas using a gasifier. Teak (Tectona grandis) and rubber (Hevea brasiliensis) leaves are considered for the present study. A binder-assisted briquetting technique with tapioca starch as binder is adopted. Properties of these leafy biomass briquettes such as moisture content, calorific value, compressive strength, and shatter index are determined. From the study, briquettes with biomass-to-binder ratio of 3:5 are found to be stable. Higher mass percentage of binder is considered for preparation of briquettes due to the fact that leafy biomasses do not adhere well on densification with lower binder content. Ultimate analysis test is conducted to analyze the gasification potential of the briquettes. Results show that the leafy biomass prepared from teak and rubber leaves has calorific values of 17.5 and 17.8 MJ/kg, respectively, which are comparable with those of existing biomass feedstock made of sawdust, rice husk, and rice straw.

Residential coal combustion is one of the main sources of ambient polycyclic aromatic hydrocarbons (PAHs). Updating its emission estimation is limited by the shortages of emission factors, especially for them in different particle sizes and from different combustion conditions. PAH emission factors (EFs) for nine size-segregated particle segments emitted from smoldering and flaming combustion of residential coals (four kinds of raw coals (RCs) and three kinds of honeycomb coal briquettes (HCBs)) were obtained in China, using a dilution sampling system. EFs of PAHs for the flaming and smoldering of HCB ranged from 1.32 to 2.04 mg kg⁻¹ and 0.35 to 5.36 mg kg⁻¹, respectively. The EFs of PAHs for RC flaming combustion varied from 0.50 to 218.96 mg kg⁻¹. About 53.5–96.4% and 47.4–90.9% of PAHs concentrated in PM₂.₁ and PM₁.₁, respectively. Different fuel types and combustion conditions strongly affected the PAH EFs. The PAH EF for the RC was 0.3 times that for HCB in Guizhou, which implied that PAH EFs for RC combustion were not always higher than those from HCB burning. For different combustion conditions, the PAH EFs from flaming were more than 2.5 times higher than those from smoldering for HCB except in the Anhui region. Results indicated that current PAH EFs may not be universal, which may bias the establishment of control policies for toxic pollutants emitted from domestic coal burning. On average, 73.2 ± 15.5% of total PAH potential toxicity risks were concentrated in submicron particles. More size-segregated PAH EFs for residential coal combustion should be investigated considering combustion conditions with a uniform sampling method in China.

Cotton crops generate millions of tons of lignocellulosic waste in Brazil that could be used in energy generation; however, the main destination of this raw material is soil incorporation. The aim of this work was to perform an energetic characterization and evaluation of briquettes produced from different agricultural waste of naturally colored cotton for power generation. The cultivars Brasil Sementes (BRS) Jade and Topazio were studied, with white cotton (BRS 286) as standard for comparison purposes. Two different parts of each species, stalk and cotton shell, were analyzed by bulk density, proximate analysis, higher heating value, cellulose, hemicellulose, protein, fat and lignin content, thermogravimetric analysis, and briquette mechanical strength. The results of the energetic characterization indicated a higher energetic potential of the colored species when compared with the white cotton, especially because of the volatile matter content, fixed carbon, and higher heating value. The briquette mechanical strength was higher in the samples formulated by a mixture of stalk and shell. Finally, it was concluded that the waste from colored cotton cultivars, Jade and Topazio, is capable to generate briquettes with good mechanical and physico-chemical characteristics, especially those formed by the mixture of stalk and shell.