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High-performance gas-phase adsorption of benzene and toluene on activated carbon: response surface optimization, reusability, equilibrium, kinetic, and competitive adsorption studies
2020
Baytar, Orhan | Şahin, Ömer | Horoz, Sabit | Kutluay, Sinan
In recent years, volatile organic compounds (VOCs) have become a group of major pollutants that endanger human health and the ecological environment. The main purpose of this study was to investigate the gas-phase adsorption processes of benzene and toluene, which are important VOCs, on the activated carbon (AC) produced from Elaeagnus angustifolia seeds by physical activation method. In this context, the central composite design (CCD) approach-based response surface methodology (RSM) was applied to examine and optimize the effects of process parameters on the adsorption of benzene and toluene by AC adsorbent. The characterization of the produced AC was performed by the Brunauer-Emmett-Teller surface area, scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray diffraction analysis. The optimum process parameters were achieved (adsorption time of 74.98 min, initial benzene concentration of 16.68 ppm, and temperature of 26.97 °C, and adsorption time of 73.26 min, initial toluene concentration of 18.46 ppm and temperature of 29.80 °C) for benzene and toluene, respectively. The maximum adsorption capacities of benzene and toluene on AC were determined to be 437.36 and 512.03 mg/g, respectively, under optimum parameters. The adsorption process kinetics and equilibrium isotherms were also evaluated. Besides, AC reusability studies were performed five times for the gas-phase adsorption and desorption of benzene and toluene. After five cycles, it was observed that the benzene and toluene adsorption capacity of the AC decreased slightly by 8.10% and 7.42%, respectively. The results revealed that the produced AC could be utilized successfully for the removal of benzene and toluene in the gas-phase adsorption systems because of its high surface area, high adsorption capacity, and high reusability performance. Furthermore, the adsorption processes of benzene and toluene were investigated, both sole components and in a binary mixture. It was concluded that the adsorption behaviors of benzene and toluene against AC were quite different when they were in the competition (in a binary mixture) and without competition (sole components). Graphical abstract
Показать больше [+] Меньше [-]Biochemical, hematological, and pathological related healing effects of Elaeagnus angustifolia hydroalcoholic extract in 5-fluorouracil-induced oral mucositis in male golden hamster
2017
Koohi-Hosseinabadi, Omid | Ranjbar, Zahra | Sepehrimanesh, Masood | AndisheTadbir, Azadeh | Poorbaghi, Seyedeh Leila | Bahranifard, Hajar | Tanideh, Nader | Koohi-Hosseinabadi, Maryam | Iraji, Aida
Oral mucositis (OM) is one of the cancer chemotherapy-related side effects which can affect the quality of life of affected patients. This study was designed to investigate the healing effect of Elaeagnus angustifolia in 5-flurouracil (5-FU)-induced OM in golden hamster. Fifty-six adult male golden hamsters received three intraperitoneal injections of 5-FU at a dose of 60 mg/kg on days 0, 5, and 10. The cheek pouch mucosa was scratched superficially under local anesthesia. Then, two horizontal scratches were made across the everted cheek pouch on days 3 and 4. All treatments were started on day 12 for equal number of animals in control group with no treatments, gel base group that was treated with carboxy methyl cellulose as gel base which used in preparation of the topical gel, topical gel group that used gel containing 10% hydroalcoholic extract of E. angustifolia (HEEA) topically, and dietary group which was treated with 300 mg/kg HEEA. At 2 and 5 days after treatment, blood and pouch tissue sampling were done and analyzed for blood composition, tissue malondialdehyde (MDA) level, and myeloperoxidase (MPO) and superoxide dismutase (SOD) activities plus histopathological evaluations. Both topically and orally HEEA-treated groups showed a significant relief in OM compared to the control and base gel groups. However, the systemic form had higher efficiency in some parts especially decreasing the MPO (0.27 ± 0.17 vs. 0.56 ± 0.17 IU/L) and increasing SOD (6.46 ± 0.15 vs. 5.36 ± 0.18 IU/L) activities in pouch tissue in comparison to topical form mostly at 5 days after treatment. It seems that hydroalcoholic extract of E. angustifolia can be used as an appropriate drug choice for the treatment of oral mucositis based on its healing stimulatory and anti-inflammatory properties.
Показать больше [+] Меньше [-]Green synthesis of Ag@AgCl/Elaeagnus angustifolia seed nanocomposite using Elaeagnus angustifolia leaves: an amazing nanophotocatalyst with highly photocatalytic activity under sunlight irradiation
2020
Rashidi, Mahnoosh | Islami, Mohammad Reza
In this investigation, Ag@AgCl nanoparticles were synthesized by a green and inexpensive method using Elaeagnus angustifolia leaves, as a reducing and stabilizing agent without using any toxic solvent, external halide source, harsh chemicals, or capping agents. In this protocol, the nanophotocatalyst was synthesized via immobilization of Ag@AgCl NPs on the surface of biowaste Elaeagnus angustifolia seed (EAS) as a green support, which prevents the agglomeration Ag@AgCl NPs and improves the catalytic activity. The biosynthesized nanophotocatalyst were characterized by UV-Vis spectroscopy, Fourier transform–infrared spectroscopy (FT-IR), X-ray diffraction (XRD), field emission scanning electron microscopy (FE SEM), energy dispersive X-ray spectroscopy (EDS), and transform electron microscopy (TEM) and inductively couple plasma mass spectrometry (ICP). In order to investigate the photocatalytic activity of the biosynthesized nanophotocatalyst, it was used in the degradation of methylene blue (MB) under sunlight. The results showed that nanophotocatalyst had an excellent photo activity without any agglomeration. In addition, the nanophotocatalyst can be easily be recycled and reused several times without losing its activity. Graphical abstract
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