One of the major factors, contributing to the emission of greenhouse gases in the environment is generation of pollutant gases in municipal landfills. As for the design and building of a gas collecting system, it is necessary to properly estimate the amount and type of the landfill emissions. By means of LandGEM model, this study predicts the amount and type of the landfill gases, produced for 30 years (from 2016 to 2045) in Jiroft. Results show that in 2045, 3, 324, 274 tons of waste will be disposed in municipal landfills of Jiroft and the total amount of produced gas, methane, carbon dioxide, and non-methane organic compounds will be 32, 994, 8813, 24,181, and 378.8 tons/year, respectively. Furthermore, the rate of landfill gas emissions from 2016 to 2045 has been achieved. Maximum concentrations of methane, carbon dioxide and non-methane organic compounds in 2045, in 700 meters from landfill, will be 40, 590, 112, 700, and 1765 tons/m3 respectively. Based on the results, obtained from this article, landfill pollutants such as CH4, CO2, and NMOC's can reach up to 15 kilometers from landfill, thus social places should be located farther than 15 kilometers from the landfill site of Jiroft. The results, obtained in this paper, can be used to identify the effect of Jiroft landfill in global emission of greenhouse gases and proper management of the landfill gas not only reduces greenhouse gas emissions, diminishing their effects on public health, but can be also used as a sustainable energy source.

Emissions from the transportation sector are rapidly changing worldwide; however, the interplay of such emission changes in the face of climate change are not as well understood. This two-part study examines the impact of projected emissions from the U.S. transportation sector (Part I) on ambient air quality in the face of climate change (Part II). In Part I of this study, we describe the methodology and results of a novel Technology Driver Model (see graphical abstract) that includes 1) transportation emission projections (including on-road vehicles, non-road engines, aircraft, rail, and ship) derived from a dynamic technology model that accounts for various technology and policy options under an IPCC emission scenario, and 2) the configuration/evaluation of a dynamically downscaled Weather Research and Forecasting/Community Multiscale Air Quality modeling system.By 2046–2050, the annual domain-average transportation emissions of carbon monoxide (CO), nitrogen oxides (NOx), volatile organic compounds (VOCs), ammonia (NH3), and sulfur dioxide (SO2) are projected to decrease over the continental U.S. The decreases in gaseous emissions are mainly due to reduced emissions from on-road vehicles and non-road engines, which exhibit spatial and seasonal variations across the U.S. Although particulate matter (PM) emissions widely decrease, some areas in the U.S. experience relatively large increases due to increases in ship emissions. The on-road vehicle emissions dominate the emission changes for CO, NOx, VOC, and NH3, while emissions from both the on-road and non-road modes have strong contributions to PM and SO2 emission changes. The evaluation of the baseline 2005 WRF simulation indicates that annual biases are close to or within the acceptable criteria for meteorological performance in the literature, and there is an overall good agreement in the 2005 CMAQ simulations of chemical variables against both surface and satellite observations.

In this study, the effects of descent flight path angle (between 1.25° and 4.25°) on aircraft gaseous emissions (carbon monoxide, total hydrocarbons and nitrogen oxides) are explored using actual flight data from aircraft flight data recording system and emissions indices from the International Civil Aviation Organization. All emissions parameters are corrected to flight conditions using Boeing Fuel Flow Method2, where the ambient air pressure, temperature and humidity data are obtained from long-term radiosonde data measured close to the arrival airport. The main findings highlight that the higher the flight path angle, the higher the emission indices of CO and HC, whereas the lower the emissions index of NOx and fuel consumption. Furthermore, during a descent, a heavier aircraft tends to emit less CO and HC, and more NOx. For a five-tonne aircraft mass increase, the average change in emissions indices are found to be −4.1% and −5.7% (CO), −5.4% and −8.2% (HC), and +1.1% and +1.6% (NOx) for high and low flight path angle groups, respectively. The average emissions indices for CO, HC and NOx during descent are calculated to be 24.5, 1.7 and 5.6 g/kg of fuel, whereas the average emissions for descending from 32,000 ft (9.7 km) and 24,000 ft (7.3 km) are calculated to be 7–8 kg (CO), ∼0.5 kg (HC) and ∼3 kg (NOx).

In the Mediterranean ecosystem, wildfires are very frequent and the predicted future with a probable increase of fires could drastically modify the vegetation scenarios. Vegetation fires are an important source of gases and primary emissions of fine carbonaceous particles in the atmosphere. In this paper, we present gaseous and particulate emissions data from the combustion of different plant tissues (needles/leaves, branches and needle/leaf litter), obtained from one conifer (Pinus halepensis) and one deciduous broadleaf tree (Quercus pubescens). Both species are commonly found throughout the Mediterranean area, often subject to wildfires. Experiments were carried out in a combustion chamber continuously sampling emissions throughout the different phases of a fire (pre-ignition, flaming and smoldering). We identified and quantified 83 volatile organic compounds including important carcinogens that can affect human health. CO and CO₂ were the main gaseous species emitted, benzene and toluene were the dominant aromatic hydrocarbons, methyl-vinyl-ketone and methyl-ethyl-ketone were the most abundant measured oxygenated volatile organic compounds. CO₂ and methane emissions peaked during the flaming phase, while the peak of CO emissions occurred during the smoldering phase. Overall, needle/leaf combustion released a greater amount of volatile organic compounds into the atmosphere than the combustion of branches and litter. There were few differences between emissions from the combustion of the two tree species, except for some compounds. The combustion of P. halepensis released a great amount of monoterpenes as α-pinene, β-pinene, p-cymene, sabinene, 3-carene, terpinolene and camphene that are not emitted from the combustion of Q. pubescens. The combustion of branches showed the longest duration of flaming and peak of temperature. Data presented appear crucial for modeling with the intent of understanding the loss of C during different phases of fire and how different typologies of biomass can affect wildfires and their speciation emissions profile.

Arable soils are a significant source of nitric oxide (NO), a precursor of tropospheric ozone, and thereby contribute to ozone pollution. However, their actual impact on ozone formation is strongly related to their spatial and temporal emission patterns, which warrant high-resolution estimates. Here, we combined an agro-ecosystem model and geo-referenced databases to map these sources over the 12 000 km2 administrative region surrounding Paris, France, with a kilometric level resolution. The six most frequent arable crop species were simulated, with emission rates ranging from 1.4 kg N–NO ha−1 yr−1 to 11.1 kg N–NO ha−1 yr−1. The overall emission factor for fertilizer-derived NO emissions was 1.7%, while background emissions contributed half of the total NO efflux. Emissions were strongly seasonal, being highest in spring due to fertilizer inputs. They were mostly sensitive to soil type, crops' growing season and fertilizer N rates. The use of an agro-ecosystem model at regional scale makes it possible to map the emissions of nitric oxide from arable soils at a resolution compatible with tropospheric ozone models.

An agricultural ammonia (NH3) emission inventory in the North China Plain (NCP) on a prefecture level for the year 2004, and a 5 × 5 km2 resolution spatial distribution map, has been calculated for the first time. The census database from China's statistics datasets, and emission factors re-calculated by the RAINS model supported total emissions of 3071 kt NH3–N yr−1 for the NCP, accounting for 27% of the total emissions in China. NH3 emission from mineral fertilizer application contributed 1620 kt NH3–N yr−1, 54% of the total emission, while livestock emissions accounted for the remaining 46% of the total emissions, including 7%, 27%, 7% and 5% from cattle, pigs, sheep and goats, and poultry, respectively. A high-resolution spatial NH3 emissions map was developed based on 1 × 1 km land use database and aggregated to a 5 × 5 km grid resolution. The highest emission density value was 198 kg N ha−1 yr−1. The first high-resolution spatial distribution of ammonia emissions for the North China Plain showed rates up to 200 kg NH3–N ha−1 yr−1.

Although post-combustion emissions from power plants are a major source of air pollution, they contain excess CO₂ that could be used to fertilize commercial greenhouses and stimulate plant growth. We addressed the combined effects of ultrahigh [CO₂] and acidic pollutants in flue gas on the growth of Alternanthera philoxeroides. When acidic pollutants were excluded, the biomass yield of A. philoxeroides saturated near 2000 μmol mol⁻¹ [CO₂] with doubled biomass accumulation relative to the ambient control. The growth enhancement was maintained at 5000 μmol mol⁻¹ [CO₂], but declined when [CO₂ rose above 1%, in association with a strong photosynthetic inhibition. Although acidic components (SO₂ and NO₂) significantly offset the CO2 enhancement, the aboveground yield increased considerably when the concentration of pollutants was moderate (200 times dilution). Our results indicate that using excess CO₂ from the power plant emissions to optimize growth in commercial green house could be viable. Diluted post-combustion emission gas from fossil fuel fired power plants stimulate the growth of C₃ plant.

Volatile Organic Compounds (VOCs) emitted from vegetation (particularly isoprenoids) represent an important source of atmospheric hydrocarbons almost double the anthropogenic source. When biogenic VOC mix with NOx in the presence of UV radiation, ozone (O3) is formed. In Italy, optimal conditions for O3 formation in terms of VOC/NOx ratios and abundance of UV radiation occur for long periods of the year. Moreover, Italian vegetation includes several species that are strong and evergreen isoprenoid emitters, and high temperatures for part of the year further stimulate these temperature-dependent emissions. We review emission of isoprenoids from Italian vegetation, current knowledge on the impact of rising O3 levels on isoprenoid emission, and evidence showing that isoprenoids can increase both the O3 flux to the plant and protection against oxidative stress because of their antioxidant functions. This trait not only influences plant tolerance to O3 but also may substantially alter the flux of O3 between atmosphere and biosphere. The capacity to emit isoprenoids confers to plants tolerance to O3 and alters the flux of O3 between atmosphere and biosphere.

Mercury (Hg) emissions from the soils taken from two different sites (deciduous and coniferous forests) in the Adirondacks were measured in outdoor and laboratory experiments. Some of the soil samples were irradiated to eliminate biological activity. The result from the outdoor measurements with different soils suggests the Hg emission from the soils is partly limited by fallen leaves covering the soils which helps maintain relatively high soil moisture and limits the amount of heat and solar radiation reaching the soil surface. In laboratory experiments exposure to UV-A (365 nm) had no significant effect on the Hg emissions while the Hg emissions increased dramatically during exposure to UV-B (302 nm) light suggesting UV-B directly reduced soil-associated Hg. Overall these results indicate that for these soils biotic processes have a relatively constant and smaller influence on the Hg emission from the soil than the more variable abiotic processes. Hg emission measurements from soils indicate that abiotic processes were more important than biotic processes in reducing Hg and controlling emissions.

We present a user-friendly tool for footprint calculations of flux measurements in the surface layer. The calculations are based on the analytical footprint model by Kormann, R. and Meixner, F.X. [2001. An analytical footprint model for Non-neutral Stratification. Boundary-Layer Meteorology 99, 207-224]. The footprint density function of a flux sensor is determined using readily available data from standard eddy covariance measurements. This footprint density function is integrated over defined surface areas given as quadrangular polygons representing e.g. agricultural fields. We illustrate the use and performance of the tool by applying it to CO2 flux measurements with three eddy covariance system at the Swiss CarboEurope grassland site. Two flux towers were positioned in the centre of two neighbouring fields, respectively, that showed a very different CO2 flux during the study period. The third tower was located near the border of the two fields and was frequently influenced by both fields to a similar degree. The calculated footprint fractions were used to simulate the latter flux from the other two systems. The measured and simulated fluxes showed a good agreement and thus support the reliability of the footprint calculation. The presented simple footprint tool can be used as a routine quality check for flux monitoring stations influenced by surface areas with varying vegetation covers and/or land-use. A simple tool for operational footprint calculations is presented and its reliability is assessed using CO2 flux measurements in a patchy agricultural landscape.