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Remediation of DDT and Its Metabolites in Contaminated Sediment
2015
Chattopadhyay, Sandip | Chattopadhyay, Devamita
Chlorinated pesticides and chlorinated organics can be transformed or partially degraded in sediments under appropriate environmental conditions. Although 1,1,1-trichloro-2,2-bis[p-chlorophenyl]ethane (DDT) is very persistent in the environment, 1,1-dichloro-2,2-bis(p-chlorophenyl)ethylene (DDE), a degradation product of DDT, is generally the constituent most widely detected in the environment and DDE is also resistant to further biotransformation. DDT and its degradation products (DDTR) may be transported from one medium to another by sorption, bioaccumulation, dissolution, or volatilization. In sediments, DDT strongly adheres to suspended particles, but once metabolized, DDE, the primary product, is slightly soluble in water. The major migration process for DDTR in sediment-water systems is sorption to sediment or other organic matter and the primary distribution route is the transportation of the particulates to which the compound is bound. Understanding the fate and transport of DDTR in the natural environment based on its specific characteristics is important in determining appropriate remediation option. Common DDT-contaminated sediment remediation options include dredging, capping, and natural attenuation. Sediment washing and phytoremediation have also been used in contaminated sites. Dredging is the most common sediment remediation option to remove the contaminated benthic sediments but often suffers from technical limitations like incomplete removal, unfavorable site conditions, sediment resuspension, and disposal issues. Capping is an in situ, low-cost remediation option for immobilization of DDT in several contaminated sediment sites. Natural or anthropogenic materials containing reactive ingredients, as distinct from a conventional sand or gravel cap, involve placing reactive materials as part of the cap matrix to increase sorption, and to enhance chemical reactivity with DDTR, or accelerate degradation. Natural attenuation can treat the DDT-contaminated sediment, but the time frame for complete remediation may be relatively long. Addition of suitable co-metabolites and acclimatized microorganisms to DDTR-contaminated sediment and alteration of sediment-water micro-environment by manipulating soil pH, moisture content, and other chemical conditions may result in degradation of DDTR associated with sediments at rates faster than the natural attenuation rate.
Показать больше [+] Меньше [-]The effects of marine sand and gravel extraction on the sediment composition and macrofaunal community of a commercial dredging site (15 years post-dredging)
2015
Waye-Barker, Georgia A. | McIlwaine, Paul | Lozach, Sophie | Cooper, Keith M.
A prediction that faunal recovery of a marine aggregate extraction site subjected to high dredging intensity was likely to take 15–20years was investigated. Samples were collected at the high dredging intensity site and two reference sites in 2011 (15years post-dredging). Results indicated that the high site had similar sediment characteristics to the reference sites by 2011. Macrofaunal data analyses showed no difference between the values of all calculated univariate measures (abundance, number of taxa, biomass and evenness) between the high and reference sites. Multivariate analyses found that the macrofaunal community at the high site was comparable to those of the reference sites by 2011. Overall, the results supported the predicted recovery time. The findings of the study suggest that persistent physical impacts prolonged the biological recovery of the high site.
Показать больше [+] Меньше [-]A tracer study in an Alaskan gravel beach and its implications on the persistence of the Exxon Valdez oil
2011
Li, Hailong | Boufadel, Michel C.
Despite great efforts including bioremediation, the 1989 Exxon Valdez oil spills persist in many gravel beaches in Prince William Sound, Alaska, USA. To explore this mystery, a lithium tracer study was conducted along two transects on one of these beaches. The tracer injections and transports were successfully simulated using the 2-dimensional numerical model MARUN. The tracer stayed much longer in the oil-persisting, right transect (facing landwand) than in the clean, left transect. If the tracer is approximately regarded as oils, oils in the upper layer would have more opportunities to enter the lower layer in the right transect than in the left one. This may qualitatively explain the oil persistence within the right transect. When the tracer is regarded as nutrients, the long stay of nutrients within the right transect implies that the oil persistence along the right transect was not due to the lack of nutrients during the bioremediation.
Показать больше [+] Меньше [-]Benthic polychaete community structure in the Yellow Sea Bottom Cold Water zone (YSBCW): Species diversity, temporal-spatial distribution, and feeding guilds
2022
Kim, Sang Lyeol | Yu, Ok Hwan
The Yellow Sea Bottom Cold Water zone (YSBCW) is a unique seasonal phenomenon in the Yellow Sea, where sea-floor cold water formed in winter is maintained until summer. This survey was conducted at 36 sites from 2018 to 2020. We identified 130 species of polychaetes, with an average density of 275 individuals/m². The number of species and density were different outside and inside of the YSBCW, and the outside was generally high. The remaining dominant species were all deposit feeders, although differences were observed in the surface or subsurface (burrowers). Correlations between polychaete community and environmental variables strongly correlated with depth, temperature, gravel, and sand. This study investigated polychaete community distribution, environmental characteristics, and feeding guilds in the YSBCW and can be used as a basic database for comprehensive research related to the Yellow Sea in the future.
Показать больше [+] Меньше [-]Holocene ecosystem shifts and human-induced loss of Arca and Ostrea shell beds in the north-eastern Adriatic Sea
2018
Mautner, Anna-Katharina | Gallmetzer, Ivo | Haselmair, Alexandra | Schnedl, Sara-Maria | Tomašových, Adam | Zuschin, Martin
The molluscan assemblages in a sediment core from the north-eastern Adriatic show significant compositional changes over the past 10,000yrs related to (1) natural deepening driven by the post-glacial sea-level rise, (2) increasing abundance of skeletal sand and gravel, and (3) anthropogenic impacts. The transgressive phase (10,000–6000 BP) is characterized by strongly time-averaged communities dominated by infaunal bivalves. During the early highstand (6000–4000 BP), the abundance of epifaunal filter feeders and grazers increases, and gastropods become more important. Epifaunal dominance culminates during the late highstand (4000–2000 BP) with the development of extensive shell beds formed by large-sized Arca noae and Ostrea sp. bivalves. This community persists until the early 20th century, when it falls victim to multiple anthropogenic impacts, mainly bottom trawling, and is substituted by an infauna-dominated community indicative of instability, disturbance and organic enrichment. The re-establishment of this unique shell-bed ecosystem can be a goal for restoration efforts.
Показать больше [+] Меньше [-]Oil permeability variations on lagoon sand beaches in the Patos-Guaíba system in Rio Grande do Sul, Brazil
2017
Oliveira, Elaine Baroni | Nicolodi, João Luiz
Permeability is the ability of a sediment deposit to allow fluids to pass through it. It depends on the local types of sediments. When the fluid is oil, high permeability implies greater interaction with the site and more extensive damage, which makes recovery most difficult. Knowledge of permeability oscillations is necessary to understand oil behavior and improve cleanup techniques. The goal is to determine oil permeability variations on lagoon sand beaches. Oil permeability tests were performed at the beach face, using a Modified Phillip Dunne Permeameter and parameters were sampled. Permeability of lagoon beaches is driven by grain diameter and roundness, soil compaction, and depth of the water table. Factors that enhance permeability include: sand sorting, vertical distribution of sediments and gravel percentage. High permeability on lagoon beaches is related to polymodal distribution, to the sediment package, and to the system's low mobility.
Показать больше [+] Меньше [-]Quantitative distribution and functional groups of intertidal macrofaunal assemblages in Fildes Peninsula, King George Island, South Shetland Islands, Southern Ocean
2015
Liu, Xiaoshou | Wang, Lu | Li, Shuai | Huo, Yuanzi | He, Peimin | Zhang, Zhinan
To evaluate spatial distribution pattern of intertidal macrofauna, quantitative investigation was performed in January to February, 2013 around Fildes Peninsula, King George Island, South Shetland Islands. A total of 34 species were identified, which were dominated by Mollusca, Annelida and Arthropoda. CLUSTER analysis showed that macrofaunal assemblages at sand-bottom sites belonged to one group, which was dominated by Lumbricillus sp. and Kidderia subquadrata. Macrofaunal assemblages at gravel-bottom sites were divided into three groups while Nacella concinna was the dominant species at most sites. The highest values of biomass and Shannon–Wiener diversity index were found in gravel sediment and the highest value of abundance was in sand sediment of eastern coast. In terms of functional group, detritivorous and planktophagous groups had the highest values of abundance and biomass, respectively. Correlation analysis showed that macrofaunal abundance and biomass had significant positive correlations with contents of sediment chlorophyll a, phaeophorbide and organic matter.
Показать больше [+] Меньше [-]Sampling epifauna, a necessity for a better assessment of benthic ecosystem functioning: An example of the epibenthic aggregated species Ophiothrix fragilis from the Bay of Seine
2011
Lozach, Sophie | Dauvin, Jean-Claude | Méar, Yann | Murat, Anne | Davoult, Dominique | Migné, Aline
Sampling the sea bottom surface remains difficult because of the surface hydraulic shock due to water flowing through the gear (i.e., the bow wave effect) and the loss of epifauna organisms due to the gear’s closing mechanism. Slow-moving mobile epifauna, such as the ophiuroid Ophiothrix fragilis, form high-density patches in the English Channel, not only on pebbles like in the Dover Strait or offshore Brittany but also on gravel in the Bay of Seine (>5000indm⁻²). Such populations form high biomasses and control the water transfer from the water column to the sediment. Estimating their real density and biomass is essential for the assessment of benthic ecosystem functioning using trophic web modelling. In this paper, we present and discuss the patch patterns and sampling efficiency of the different methods for collecting in the dense beds of O. fragilis in the Bay of Seine. The large Hamon grab (0.25m⁻²) highly under-estimated the ophiuroid density, while the Smith McIntyre appeared adequate among the tested sampling grabs. Nowadays, diving sampling, underwater photography and videos with remote operated vehicle appear to be the recommended alternatives to estimate the real density of such dense slow-moving mobile epifauna.
Показать больше [+] Меньше [-]Response of multi-metric indices to anthropogenic pressures in distinct marine habitats: The need for recalibration to allow wider applicability
2014
Fitch, Jayne E. | Cooper, Keith M. | Crowe, Tasman P. | Hall-Spencer, Jason M. | Phillips, Graham
Sustainable exploitation of coastal ecosystems is facilitated by tools which allow reliable assessment of their response to anthropogenic pressures. The Infaunal Quality Index (IQI) and Multivariate-AMBI (M-AMBI) were developed to classify the ecological status (ES) of benthos for the Water Framework Directive (WFD). The indices respond reliably to the impacts of organic enrichment in muddy sand habitats, but their applicability across a range of pressures and habitats is less well understood. The ability of the indices to predict changes in response to pressures in three distinct habitats, intertidal muddy sand, maerl and inshore gravel, was tested using pre-existing datasets. Both responded following the same patterns of variation as previously reported. The IQI was more conservative when responding to environmental conditions so may have greater predictive value in dynamic habitats to provide an early-warning system to managers’. Re-calibration of reference conditions is necessary to reliably reflect ES in different habitats.
Показать больше [+] Меньше [-]The importance of both potency and mechanism in dose–response analysis: An example from exposure of Pacific herring (Clupea pallasi) embryos to low concentrations of weathered crude oil
2013
Neff, Jerry M. | Page, David S. | Landrum, Peter F. | Chapman, P. M.
This paper reanalyzes data from an earlier study that used effluents from oiled-gravel columns to assess the toxicity of aqueous fractions of weathered crude oil to Pacific herring embryos and larvae. This reanalysis has implications for future similar investigations, including the observance of two distinct dose–response curves for lethal and sublethal endpoints for different exposures in the same experiment, and the need to consider both potency and slope of dose–response curves for components of a toxicant mixture that shows potentially different toxicity mechanisms/causation. Contrary to conclusions of the original study, the aqueous concentration data cannot support the hypothesis that polycyclic aromatic hydrocarbons (PAHs) were the sole cause of toxicity and that oil toxicity increased with weathering. Confounding issues associated with the oiled gravel columns include changes in the concentration and composition of chemicals in exposure water, which interfere with the production of reliable and reproducible results relevant to the field.
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