The Yangtze estuary is considered as an important eco-region of China, but it has been heavily disturbed by reclamation projects. We evaluated the effect of freshwater inflow on the self-restoration of macrobenthic diversity in 3-year-old vegetated, gravel, and mudflat habitats of reclaimed seaward intertidal wetlands. There was a significant self-restoration of species richness and diversity in vegetated and gravel habitats with no inflow of freshwater, but there were no significant changes in species diversity in three habitats subjected to freshwater inflow. Significant changes in community structures of macrobenthos occurred in vegetated and gravel habitats from pre- to post-restoration. Analysis of benthic health showed that gravel habitats were under moderate to high levels of disturbance in pre-restoration period. In contrast, there tended to be no evidence of disturbance in vegetated and mudflat habitats during two investigations. Restoration of macrobenthos is best achieved in vegetated habitats with on inflow of freshwater.

In the northern Great Plains, a potential road dust abatement is the application of oil-well produced water, also known as “brine.” However, little is known about the effectiveness of brine or its potential impacts on dispersion of road materials and the creation of dusts. This study aimed to investigate how sodium adsorption ratios (SAR), electrical conductivity (EC), and Ca/Mg ratios of simulated and non-simulated brine influenced dispersive reactions of three mineralogically different gravel road fine fractions. Ca/Mg ratios had little to no significant influence on the outcome of dispersion. Irrespective of the SAR or clay mineralogy, a threshold EC of 4 dS m⁻¹ was sufficient to control road fine fraction dispersion. Actual oil-well produced water effect on dispersion followed the same order as that treated by simulated solution and the dispersion value can be well-predicted from EC. This information is useful to managers, regulators, scientists, and industry professionals considering the use of brine as a road dust control abatement.

Mass transport and residence time of saline water from road salt applications in soil columns composed of Toyoura sand and weathered granite sand were investigated by simulations and in laboratory experiments. Both are sands found in Japan, especially the weathered granite sand. The Toyoura sand has a fairly uniform particle size of 0.1 to 0.4 mm diameter, and a saturated hydraulic conductivity Kₛ = 0.0296 cm/s, while the weathered granite sand used consisted of 13% fine materials (silt and clay) and 87% coarse materials (sand and gravel) with a saturated hydraulic conductivity Kₛ = 0.00393 cm/s. A model was developed to simulate rinsing of brine from a soil column. Assuming a steady, homogeneous flow induced by rainwater infiltration into the soil column, the model was found to match the experimental results for Toyoura sand very well. The normalized salt concentration in the effluent from the 40 cm tall soil column remained constant until about t = 500 s; the concentration then decreased with time quickly and, finally, approached zero. For the weathered granite sand, however, the salt concentrations in the effluent simulated by the model with assumption of homogeneous flow are inconsistent with the experimental data collected. A substantial delay occurs in mass transport of salt from the column, which is different from the Toyoura sand. The delay is attributed to shifts in “active” and “inactive pores” created in the soil due to fine particles such as silt and clay. The proportion of “active pores” and “inactive pores” is not constant but variable with time due to physical and/or electrochemical processes such as pore-size distributions and salt depletion in the soil. A modified model presented, using a time-variable active pore parameter k(t), can reproduce the experimental results for salt mass left in the soil better.

In this study, a new ecological dam based on the microbial fuel cell principle (MFCED) was designed to remove pollutants from river sediments and water bodies. Sediment organics were better removed in the MFCED mode in comparison with the other two modes (ecological dam with open circuit (OCED) and ecological dam filled with gravel in cathode chamber (GMFCED)). The difference of nitrogen source in water had little effect on the removal of chemical oxygen demand (COD) (70–80%), while nitrate was more readily removed in the MFCED. The voltage curve and power curve were measured to understand the bioelectricity generation of MFCED. During the stable operation phase of MFCED, the voltage was stabilized between 0.09–0.15 V. The results of high-throughput sequencing indicated that the anode and cathode diversities of MFCED were more than the other systems, and the species diversity of the anode was more than that of the cathode in the MFCED. Graphical abstract

The study was initiated to evaluate constructed wetland technology as a method for treating alkaline (pH 8.0–8.6) drainage high in Al, Mo, V, As and Ga originating from bauxite residue storage areas. Pilot-scale horizontal flow constructed wetlands were operated over a 40-week period using three filter materials (granitic gravel, bauxite and alum water treatment sludge), and half of the wetlands were planted with Phragmites australis and the other half left unplanted. Gravel was the least effective medium for removing the target elements, while of the two active media, water treatment sludge was more effective than bauxite. Plants removed only small amounts of elements into their above- and below-ground dry matter (0.4–4.9% of that added). Nonetheless, the presence of plants greatly increased the effectiveness of all three media since their presence decreased effluent pH values by 0.5–1.3 pH units and that of the filter media by 0.4 pH units. Removal of elements followed the order Al > Ga > V > As > Mo. For planted wetlands, total elemental removal ranged from 18 to 98% for gravel, 80 to 99% for bauxite, and 93 to 99% for water treatment sludge. The lowest removal was for Mo (ranging from 18% for gravel to 93% for water treatment sludge) and the highest for Al (ranging from 98% in gravel to 99% in water treatment sludge). A sequential fractionation scheme for As, V and Mo on filter material at the end of the experiment showed that for bauxite and water treatment sludge, V and As were concentrated in the NaOH extractable fraction while Mo was concentrated in the less strongly adsorbed NaHCO₃ extractable fraction. It was concluded that a constructed wetland with water treatment sludge as an active filter material is an effective technology for removal of the target elements from the alkali drainage.

The objective of the paper was to use transport model of selected pesticides (carbendazim, acetamiprid and imidacloprid) in determination of linear sorption coefficients in alluvial aquifer. For constructing transport model, results of a field experiment at the location of Kovin-Dubovac drainage system in Serbia were used in order to set hydraulic parameters (hydraulic conductivity, aquifer layer thickness of the observed area, effective porosity etc.). The field experiment consisted of a tracer test during which concentrations of non-reactive tracer (Cl⁻) and selected pesticides (carbendazim, acetamiprid and imidacloprid) were monitored. For better characterization of hydraulic parameters, a pumping test was conducted at the observed well and results were used in designing transport model. Simulation model was constructed with Lizza groundwater flow software and W.O.D.A. (Well Outline and Design Aid) solver. Obtained linear sorption coefficients in the sand and gravel water-bearing layer were 0.14 mL g⁻¹ for carbendazim and 0.11 mL g⁻¹ for acetamiprid and imidacloprid. Results from this study are a unique insight into mobility of observed pesticides in the alluvial groundwater in natural conditions and can be used in contamination assessment for drinking water wells.

The TREENET inlet is an emerging water-sensitive urban design technology that consists of a novel kerb side inlet coupled with a leaky well infiltration system. The inlets have been retrofitted to existing roads since 2006; however, there is currently little information available on the effectiveness of these inlet and leaky well systems. This study investigated the performance of the kerb side inlets and leaky well system for water quality improvement prior to infiltration to native soil. The leaky wells included four filter media types, namely gravel, water treatment solids, sandy loam and clay. To compare the performance of the four filter media types, batch and column studies were performed in the laboratory. The best performance was observed using the sandy loam as a filter media, followed by clay, water treatment solids and then gravel. The selection of effective media for removal of heavy metals is important as each media type has different pollutant removal capacity, infiltration and clogging performance.

In this study, the effects of medium carbon chain alcohol (1-heptanol)-enhanced air sparging (AS) on the remediation of benzene-contaminated aquifers in different media (medium sand, channelized flow; gravel, bubbly flow) were investigated by comparison with a commonly used surfactant (sodium dodecylbenzene sulfonate (SDBS)). The results showed that the addition of 1-heptanol and SDBS significantly increased the air saturation in AS process under different airflow modes. Combined with water retention curves, 1-heptanol had the same effect on reducing the surface tension of groundwater and stabilizing bubbles as SDBS. In the study of benzene pollution removal, when the removal efficiency of the benzene pollutant exceeded 95%, the time required for surfactant-enhanced AS (SEAS) and alcohol-enhanced AS (AEAS) in medium sand was shortened by 28.6% and 52.4%, respectively, and the time required for SEAS and AEAS in gravel media was shortened by 16.7% and 58.3%, respectively, compared with the time required for AS. This finding indicated that the addition of SDBS or 1-heptanol could significantly increase the removal rate of benzene pollutants. Under the same surface tension conditions, the removal effect of 1-heptanol on the benzene pollutant was better than that of SDBS. This difference was due to the disturbance of the flow field during AEAS process causing the 1-heptanol on the gas-liquid interface to volatilize in the carrying gas, thereby inducing Marangoni convection on the interface, enhancing the gas-liquid mass transfer rate, and increasing the removal rate of benzene on the interface. Therefore, 1-heptanol is promising as a new reagent to enhance AS to remediate groundwater pollution.

Advancements in the design and technology of constructed wetlands for efficient removal of wastewater contaminants are ever in progress to develop situation-based economical systems. Here, we entrenched two horizontal sub-surface flow constructed wetlands (HSFCW) with either chemical, viz. limestone (HSFCW-LS) or organic, viz. sawdust (HSFCW-SD) substrates, and compared them with biological method, viz. growing of water spinach in floating-bed-constructed wetland (FBCW-WS) to enhance the performance of CWs. Same sewage wastewater was used as influent in each fortified CW replicated thrice. Sewage was replaced weekly, for a total of 12 weeks of experimentation. Sampling of raw sewage from influent was undertaken at the inlet in the beginning, and that of treated effluent from the outlet after a week of treatments. Quality of raw sewage used weekly during experimentation remained almost uniform and near to the wastewater standards. Cumulative data of treated wastewater depicted that the FBCW-WS achieved the highest performance in the removal of total nitrogen (TN), [Formula: see text]–N, and total phosphorus (TP) with average removal efficiencies of 75.9, 90.5, and 94.3%, respectively. Whereas, HSFCW-SD performed better for [Formula: see text]–N, FC, and TSS with corresponding removal efficiency of 77.5, 64.3, and 74.2% while HSFCW-LS showed average performance. This study concludes that performance of biological method of macrophyte cultivation (FBCW-WS) is significantly superior to chemical and organic substrates, so it could be more effective, economical, and sustainable approach for sewage treatment.