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Результаты 1-10 из 83
Development of water quality criteria for phenanthrene and comparison of the sensitivity between native and non-native species
2015
Wu, Jiang-Yue | Yan, Zhen-Guang | Liu, Zheng-Tao | Liu, Ji-dong | Liang, Feng | Wang, Xiao-Nan | Wang, Weili
Phenanthrene (PHE) is a priority polycyclic aromatic hydrocarbon (PAH) which is toxic to aquatic organisms. However, there has been no paper dealing with water quality criteria (WQC) of PHE due to the shortage of toxicity data of different taxonomic levels. In the present study, toxicity data were obtained from 8 acute toxicity tests and 3 chronic toxicity tests using 8 Chinese native aquatic species from different taxonomic levels, and the water quality criteria was derived using 3 methods. Furthermore, differences of species sensitivity distributions (SSDs) between native and non-native species were compared. A criterion maximum concentration of 0.0514 mg/L and a criterion continuous concentration of 0.0186 mg/L were developed according to the US EPA guidelines. Finally, by using risk quotient (RQ) to assess the site-specific ecological risk in Liao River, the results indicated that the PHE might pose no risk to local aquatic species.
Показать больше [+] Меньше [-]Distribution of persistent organic pollutants (PAHs, Me-PAHs, PCBs) in dissolved, particulate and sedimentary phases in freshwater systems
2015
Rabodonirina, Suzanah | Net, Sopheak | Ouddane, Baghdad | Merhaby, Dima | Dumoulin, David | Popescu, Tudor | Ravelonandro, Pierre
The occurrence of three groups of hazardous organic contaminants (PCBs, PAHs, Me-PAHs) in fifteen watercourses and rivers located in highly urbanized and industrialized zones was studied. The distribution of 62 organic contaminants was determined in three matrices: in the dissolved phase, associated with suspended solid matter (SSM) and in sediment. Their distributions in the aquatic environment depend strongly on their physicochemical properties. Low molecular weight PAHs were predominant in the dissolved phase while those with high molecular weight accumulated preferentially in SSM and sediments. Among the 28 PCBs congeners, only PCB153 was detected. The results showed that the contamination of these areas originated mainly from combustion processes. The three the most polluted sites identified are surrounded by big cities. Ecotoxicological assessment based on the international Sediment Quality Guidelines (SQGs) showed that the toxic effects of the sediment in these watercourses and rivers occurred due to high levels of hydrocarbons.
Показать больше [+] Меньше [-]Particulate Matter deposition on Quercus ilex leaves in an industrial city of central Italy
2015
A number of studies have focused on urban trees to understand their mitigation capacity of air pollution. In this study particulate matter (PM) deposition on Quercus ilex leaves was quantitatively analyzed in four districts of the City of Terni (Italy) for three periods of the year. Fine (between 0.2 and 2.5 μm) and Large (between 2.5 and 10 μm) PM fractions were analyzed. Mean PM deposition value on Quercus ilex leaves was 20.6 μg cm−2. Variations in PM deposition correlated with distance to main roads and downwind position relatively to industrial area. Epicuticular waxes were measured and related to accumulated PM. For Fine PM deposited in waxes we observed a higher value (40% of total Fine PM) than Large PM (4% of total Large PM). Results from this study allow to increase our understanding about air pollution interactions with urban vegetation and could be hopefully taken into account when guidelines for local urban green management are realized.
Показать больше [+] Меньше [-]Effects of unionised ammonia on tropical freshwater organisms: Implications on temperate-to-tropic extrapolation and water quality guidelines
2015
Wang, Zhen | Leung, Kenneth M.Y.
Unionised ammonia (NH3) is highly toxic to freshwater organisms. Yet, most of the available toxicity data on NH3 were predominantly generated from temperate regions, while toxicity data on NH3 derived from tropical species were limited. To address this issue, we first conducted standard acute toxicity tests on NH3 using ten tropical freshwater species. Subsequently, we constructed a tropical species sensitivity distribution (SSD) using these newly generated toxicity data and available tropical toxicity data of NH3, which was then compared with the corresponding temperate SSD constructed from documented temperate acute toxicity data. Our results showed that tropical species were generally more sensitive to NH3 than their temperate counterparts. Based on the ratio between temperate and tropical hazardous concentration 10% values, we recommend an extrapolation factor of four to be applied when surrogate temperate toxicity data or temperate water quality guidelines of NH3 are used for protecting tropical freshwater ecosystems.
Показать больше [+] Меньше [-]Estimating nitrous oxide emission flux from arable lands in China using improved background emission and fertilizer-induced emission factors
2015
Chen, Jinsong | Cao, Wenzhi | Li, Ying | Cao, Di | Wang, Feifei
A nitrous oxide (N2O) emission database was compiled for arable land (284 measurements from 62 studies) to establish predictive models for building a greenhouse gas emission inventory in China. Arable lands were grouped into dry land and rice paddy based on the IPCC 2006 guidelines. The results of the meta analysis show that the annual mean N2O fluxes from dry land and rice paddy were 4.69±4.62 (SD) and 5.89±3.23kg N2O–N ha–1 yr–1. Fertilizer–induced N2O emission factors were 0.68±0.41% for dry land, and 0.49±0.43% for rice paddy. The relationship between N2O flux from arable lands and various environmental variables were analyzed, and the magnitude of N2O emissions from zero mineral N addition control plots (background emission) was determined based on precipitation. Based on the above background emissions and correlation coefficients, two new predictive models were established to estimate N2O emissions from arable lands in China. Comparison showed that the precipitation–rectified background emissions could largely improve the model predictions, and the two new models had better performance than the 1996 IPCC guideline method. Therefore, it is strongly recommended that the important local environmental variables be included in the estimates when compiling a national N2O emission inventory.
Показать больше [+] Меньше [-]Polycyclic aromatic hydrocarbons in sediments at dredged material disposal sites around England: Concentrations in 2013 and time trend information at selected sites 2008–2013
2015
Rumney, Heather S. | Bolam, Stefan G. | Law, Robin J.
The maintenance of navigation channels to ports and the development of their facilities present a need to conduct dredging operations, and the subsequent disposal of dredged material at sea. Contaminant concentrations in candidate dredged material are determined and their possible impacts considered during the licensing process, which can result in the exclusion of some material from sea disposal. Monitoring of disposal sites is conducted in order to ensure that no undesirable impacts are occurring. In this study we consider the levels of polycyclic aromatic hydrocarbons (PAHs) in sediments at a number of disposal sites monitored in 2013 and variations in concentrations over time at three sites during the period 2008–2013. These were assessed using established sediment quality guidelines. Elevated PAH concentrations were generally observed only within the boundaries of the disposal sites studied.
Показать больше [+] Меньше [-]Characterizing spatial distribution and temporal variation of PM10 and PM2.5 mass concentrations in an urban area of Southwest China
2015
Huang, Wei | Long, Enshen | Wang, Jun | Huang, Ruyi | Ma, Li
To investigate the temporal and spatial behavior of particulate matter (PM10 and PM2.5), daily data of PM10 and PM2.5 mass concentrations were collected from five air–quality monitoring stations in Chengdu from March 2013 to February 2014. In this period, the daily average concentrations of PM10 and PM2.5 were 156.6 and 99.5μg/m3, respectively, which exceeded both the Chinese ambient air–quality standards for PM and the guidelines of the World Health Organization (WHO). Higher mass concentrations of both PM10 and PM2.5 were observed in winter and spring, indicating that meteorological parameters play an important role. Although PM mass concentrations were evidently lower than reported in previous studies, the average PM2.5/PM10 ratio in this study was higher, indicating that fine particulate (PM2.5) pollution has become more serious. Weekly variations of PM concentrations were analyzed to estimate the impact of traffic restriction policies. The results show that the highest concentrations of particles were observed on Mondays and the lowest on Thursdays. Weekend effects were also obvious, which were mainly attributed to human activities.
Показать больше [+] Меньше [-]A review of standards and guidelines set by international bodies for the parameters of indoor air quality
2015
Abdul–Wahab, Sabah Ahmed | Chin Fah En, Stephen | Elkamel, Ali | Ahmadi, Lena | Yetilmezsoy, Kaan
Standards and guidelines as defined by various international agencies are employed by the researchers to evaluate an acceptable quality of air in indoor as well as outdoor environments. The main objective of this paper is to establish a comprehensive review of Indoor Air Quality (IAQ) guidelines and other standard values that are implemented currently. For this purpose, the present study summarizes the main standards and guidelines related to key indoor air pollutants and levels of thermal comfort developed by different agencies around the world. These agencies and organizations include the American Society of Heating, Refrigerating and Air– Conditioning Engineers (ASHRAE), the Hong Kong Environmental Protection Department (HKEPD), the World Health Organization (WHO), and the National Health and Medical Research Council (NHMRC) of Australia. Common indoor air pollutants that are found to frequently affect indoor populations are, carbon dioxide (CO2), nitrogen dioxide (NO2), formaldehyde (HCHO), carbon monoxide (CO), sulfur dioxide (SO2), and particulate matter in sizes <2.5 and 10 μm (PM2.5 and PM10, respectively). Other factors that affect IAQ are the moisture content of the air (i.e., relative humidity), the temperature of the indoor air, and the air speed or movement. Sick building syndrome (SBS) describes the various interactions between these major pollutants and factors of IAQ that cause adverse health effects on humans. In addition, this paper reviews various stipulated guidelines that are implemented by the relevant regulatory institutions and agencies to prevent SBS.
Показать больше [+] Меньше [-]Sample port design for ballast water sampling: Refinement of guidance regarding the isokinetic diameter
2015
Wier, Timothy P. | Moser, Cameron S. | Grant, Jonathan F. | First, Matthew R. | Riley, Scott C. | Robbins-Wamsley, Stephanie H. | Drake, Lisa A.
By using an appropriate in-line sampling system, it is possible to obtain representative samples of ballast water from the main ballast line. An important parameter of the sampling port is its “isokinetic diameter” (DISO), which is the diameter calculated to determine the velocity of water in the sample port relative to the velocity of the water in the main ballast line. The guidance in the U.S. Environmental Technology Verification (ETV) program protocol suggests increasing the diameter from 1.0× DISO (in which velocity in the sample port is equivalent to velocity in the main line) to 1.5–2.0× DISO. In this manner, flow velocity is slowed—and mortality of organisms is theoretically minimized—as water enters the sample port. This report describes field and laboratory trials, as well as computational fluid dynamics modeling, to refine this guidance. From this work, a DISO of 1.0–2.0× (smaller diameter sample ports) is recommended.
Показать больше [+] Меньше [-]Spatial variation, fractionation and sedimentary records of mercury in the East China Sea
2015
Duan, Li-Qin | Song, Jin-Ming | Yu, Yu | Yuan, Hua-Mao | Li, Xue-Gang | Li, Ning
Surface and core sediments were collected to study distributions, phases and potential environmental risk of Hg and to reconstruct anthropogenic Hg change over the past one hundred years in the East China Sea (ECS). Hg contents in surface sediments displayed a decreasing gradient from the Changjiang Estuary to the outer sea. Sequential extraction analysis showed that Hg mainly existed as residual fraction (70.18% of total), and while organic matter fraction (22.96% of total) was the main component of labile fraction, indicating the strong adsorption of organic matters on Hg. Enrichment factor and sediment quality guidelines suggested that Hg in sediments of ECS were at minor enrichment and low adverse effect. Temporal distributions of total Hg content, labile fraction, burial flux and anthropogenic Hg flux showed that anthropogenic Hg input increased since the 1960s, which was related to riverine input and atmospheric transport.
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