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The first plastic produced, but the latest studied in microplastics research: The assessment of leaching, ecotoxicity and bioadhesion of Bakelite microplastics Полный текст
2022
Klun, Barbara | Rozman, Ula | Ogrizek, Monika | Kalčíková, Gabriela
Bakelite, the first synthetic plastic, is a rather unexplored material in the field of ecotoxicology, despite its long production and use. The aim of this study was to investigate the ecotoxicity of Bakelite microplastics (before and after leaching) and its leachates on four aquatic organisms: the crustacean Daphnia magna, the plant Lemna minor, the bacterium Allivibrio fischeri and the alga Pseudokirchneriella subcapitata. Bakelite microplastics before and after leaching and leachates affected all organisms, but to varying degrees. Leachates showed increased ecotoxicity to Daphnia magna, while Pseudokirchneriella subcapitata was more affected by particles. For Lemna minor and Allivibrio fischeri, the effects of particles before leaching and leachate were comparable, while the negative effect of particles after leaching was minimal or not present. All leachates were analysed, and phenol and phenol-like compounds were the predominant organics found. In addition, bioadhesion of Bakelite microplastics to the surface of Daphnia magna and Lemna minor was confirmed, but the particles were mainly weakly adhered. Results of this study suggest that, in addition to the recently studied microplastics from consumer products (e.g. from polyethylene and polystyrene), microplastics from industrial plastics such as Bakelite may be of increasing concern, primarily due to leaching of toxic chemicals.
Показать больше [+] Меньше [-]A selective hydrometallurgical method for scandium recovery from a real red mud leachate: A comparative study Полный текст
2022
Salman, Ali Dawood | Juzsakova, Tatjána | Jalhoom, Moayyed G. | Abdullah, Thamer Adnan | Le, Phuoc-Cuong | Viktor, Sebestyen | Domokos, Endre | Nguyen, X Cuong | La, D Duong | Nadda, Ashok K. | Nguyen, D Duc
The aim of this study was to recover Sc as the main product and Fe as a by-product from Hungarian bauxite residue/red mud (RM) waste material by solvent extraction (SX). Moreover, a new technique was developed for the selective separation of Sc and Fe from real RM leachates. The presence of high Fe content (∼38%) in RM makes it difficult to recover Sc because of the similarity of their physicochemical properties. Pyrometallurgical and hydrometallurgical methods were applied to remove the Fe prior to SX. Two protocols based on organophosphorus compounds (OPCs) were proposed, and the main extractants were evaluated: bis(2-ethylhexyl) phosphoric acid (D2EHPA/P204) and tributyl phosphate (TBP). The results showed that SX using diethyl ether and tri-n-octylamine (N₂₃₅) was efficient in extracting Fe(III) from the HCl leachate as HFeC1₄. Over 97% of Sc was extracted by D2EHPA extractant under the following conditions; 0.05 mol/L of D2EHPA concentration, A/O phase ratio of 3:1, pH 0–1, 10 min of shaking time, and a temperature of 25 °C. Sc(OH)₃ as a precipitate was efficiently obtained by stripping from the D2EHPA organic phase by 2.5 mol/L of NaOH with a stripping efficiency of 95%. In the TBP system, 99% of Sc was extracted under the following conditions: 12.5% vol of TBP, an A/O phase ratio of 3:1, 10 min of shaking time, and a temperature of 25 °C. The Sc contained in the TBP organic phase could be efficiently stripped by 1 mol/L of HCl with a stripping efficiency of 92.85%.
Показать больше [+] Меньше [-]Ecotoxicological assessment of sewage sludge-derived biochars-amended soil Полный текст
2021
Tomczyk, Beata | Siatecka, Anna | Bogusz, Aleksandra | Oleszczuk, Patryk
The study aimed to evaluate the ecotoxicity of soil (S) amended with biochars (BCKN) produced by the thermal conversion of sewage sludge (SSL) at temperatures of 500 °C, 600 °C, or 700 °C and SSL itself. The ecotoxicological tests were carried out on organisms representing various trophic levels (Lepidium sativum in plant, Folsomia candida in invertebrates, and Aliivibrio fischeri in bacteria). Moreover, the study evaluated the effects of three plants (Lolium perenne, Trifolium repens, and Arabidopsis thaliana) growing on BCKN700-amended soil on its ecotoxicological properties. The experiment was carried out for six months. In most tests, the conversion of sewage sludge into biochar caused a significant decrease in toxicity by adding it to the soil. The pyrolysis temperature directly determined this effect. The soil amended with the biochars produced at higher temperatures (600 °C and 700 °C) generally exhibited lower toxicity to the test organisms than the SSL. Because of aging, all the biochars lost their inhibition properties against the tested organisms in the solid-phase tests and had a stimulating influence on the reproductive ability of F. candida. With time, the fertilizing effect of the BCKN700 amended soil also increased. The aged biochars also did not have an inhibitory effect on A. fischeri luminescence in the leachate tests. The study has also demonstrated that the cultivation of an appropriate plant species may additionally reduce the toxicity of soil fertilized with biochar. The obtained results show that the conversion of sewage sludge to biochar carried out at an appropriate temperature can become a useful method in reducing the toxicity of the waste and while being safe for agricultural purposes.
Показать больше [+] Меньше [-]Selenite bioreduction and biosynthesis of selenium nanoparticles by Bacillus paramycoides SP3 isolated from coal mine overburden leachate Полный текст
2021
Borah, Siddhartha Narayan | Goswami, Lalit | Sen, Suparna | Sachan, Deepa | Sarma, Hemen | Montes Castillo, Milka Odemariz | Peralta-Videa, Jose R. | Pakshirajan, Kannan | Narain, Mahesh
A native strain of Bacillus paramycoides isolated from the leachate of coal mine overburden rocks was investigated for its potential to produce selenium nanoparticles (SeNPs) by biogenic reduction of selenite, one of the most toxic forms of selenium. 16S rDNA sequencing was used to identify the bacterial strain (SP3). The SeNPs were characterized using spectroscopic (UV–Vis absorbance, dynamic light scattering, X-ray diffraction, and Raman), surface charge measurement (zeta potential), and ultramicroscopic (FESEM, EDX, FETEM) analyses. SP3 exhibited extremely high selenite tolerance (1000 mM) and reduced 10 mM selenite under 72 h to produce spherical monodisperse SeNPs with an average size of 149.1 ± 29 nm. FTIR analyses indicated exopolysaccharides coating the surface of SeNPs, which imparted a charge of −29.9 mV (zeta potential). The XRD and Raman spectra revealed the SeNPs to be amorphous. Furthermore, biochemical assays and microscopic studies suggest that selenite was reduced by membrane reductases. This study reports, for the first time, the reduction of selenite and biosynthesis of SeNPs by B. paramycoides, a recently discovered bacterium. The results suggest that B. paramycoides SP3 could be exploited for eco-friendly removal of selenite from contaminated sites with the concomitant biosynthesis of SeNPs.
Показать больше [+] Меньше [-]Long-term landfill leachate exposure modulates antioxidant responses and causes cyto-genotoxic effects in Eisenia andrei earthworms Полный текст
2021
Sales Junior, Sidney Fernandes | Costa Amaral, Isabele Campos | Mannarino, Camille Ferreira | Hauser-Davis, Rachel Ann | Correia, Fábio Veríssimo | Saggioro, Enrico Mendes
It is estimated that approximately 0.4% of the total leachate produced in a landfill is destined for treatment plants, while the rest can reach the soil and groundwater. In this context, this study aimed to perform leachate toxicity evaluations through immune system cytotoxic assessments, genotoxic (comet assay) appraisals and antioxidant system (superoxide dismutase - SOD; catalase - CAT, glutathione-S-transferase - GST; reduced glutathione - GSH and metallothionein - MT) evaluations in Eisenia andrei earthworms exposed to a Brazilian leachate for 77 days. The leachate sample contained high organic matter (COD - 10,630 mg L⁻¹) and ammoniacal nitrogen (2398 mg L⁻¹), as well as several metals, including Ca, Cr, Fe, Mg, Ni and Zn. Leachate exposure resulted in SOD activity alterations and increased CAT activity and MT levels. Decreased GST activity and GSH levels were also observed. Antioxidant system alterations due to leachate exposure led to increased malondialdehyde levels as a result of lipid peroxidation after the 77 day-exposure. An inflammatory process was also observed in exposed earthworms, evidenced by increased amoebocyte density, and DNA damage was also noted. This study demonstrates for the first time that sublethal effect assessments in leachate-exposed earthworms comprise an important tool for solid waste management.
Показать больше [+] Меньше [-]Relative importance of aqueous leachate versus particle ingestion as uptake routes for microplastic additives (hexabromocyclododecane) to mussels Полный текст
2021
Jang, Mi | Shim, Won Joon | Han, Gi Myung | Cho, Youna | Moon, Yelim | Hong, Sang Hee
Microplastic pollution is emerging as a global environmental issue, and its potential for transferring hazardous chemicals to aquatic organisms is gaining attention. Studies have investigated the transfer of chemicals, mainly sorbed chemicals, through ingestion of microplastics by organisms, but limited information is available regarding chemical additives and uptake via the aqueous route through plastic leaching. In this study, we compared two bioaccumulation pathways of the additive hexabromocyclododecane (HBCD) by exposing mussels (Mytilus galloprovincialis) to two different sizes of expanded polystyrene (EPS): inedible size (4.2–5.5 mm) for leachate uptake and edible size (20–770 μm) for particle ingestion and leachate uptake. Over 10 days, the HBCD concentration increased significantly in mussels in the EPS exposure groups, indicating that EPS microplastic acts as a source of HBCD to mussels. The concentration and isomeric profiles of HBCD in mussels show that uptake through the aqueous phase is a more significant pathway for bioaccumulation of HBCD from EPS to mussels than particle ingestion. HBCD levels measured in EPS, leachate and exposed mussels from this study are environmentally relevant concentration. The fate and effects of chemical additives leached from plastic debris in ecosystem requires further investigation, as it may affect numerous environments and organisms through the aqueous phase.
Показать больше [+] Меньше [-]Reduction in VOC emissions by intermittent aeration in bioreactor landfills with gas-water joint regulation Полный текст
2021
Chu, Yi-Xuan | Wang, Jing | Tian, Guangming | He, Ruo
Landfill mining and reclamation is a new strategy for addressing the lack of space available for new landfills and realizing the sustainable development of landfills. A gas-water joint bioreactor landfill is regulated by injecting water and/or recirculating leachate, and a blasting aeration system to optimize waste stabilization. In this study, four landfill reactors were constructed to investigate the effects of ventilation methods, including continuous (20 h d⁻¹) and intermittent aeration (4 h d⁻¹ in continuous or 2-h aeration per 12 h, twice a day), on the degradation of organic matter and volatile organic compound (VOC) emissions in comparison with traditional landfills. A total of 62 VOCs were detected in the landfill reactors. Among them, halogenated compounds had the highest abundance (39.8–65.4 %), followed by oxygenated compounds, alkanes and alkenes, and aromatic compounds. Both intermittent and continuous aeration could accelerate the degradation of landfilled waste and increase the volatilization rate of VOCs. Compared with intermittent aeration, the degradation of landfilled waste was more quickly in the landfill reactor with continuous aeration. However, intermittent aeration could create anaerobic-anoxic-aerobic conditions, which were conducive to the growth and metabolism of anaerobic and aerobic microorganisms in landfills and thereby reduced more than 63.4 % of total VOC emissions from the landfill reactor with continuous aeration. Moreover, intermittent aeration could reduce the ventilation rate and decrease the cost of aeration by 80 % relative to continuous aeration. Firmicutes, Bacteroidetes, Proteobacteria and Tenericutes predominated in the landfill reactors. The environmental variables including organic matter and VOCs concentrations had significant influences on microbial community structure in the landfilled waste. These findings indicated that intermittent aeration was an effective way to accelerate the stabilization of landfilled waste and reduce the cost and environmental risks in bioreactor landfills with gas-water joint regulation.
Показать больше [+] Меньше [-]A new route for manufacturing poly(aminophosphonic)-functionalized poly(glycidyl methacrylate)-magnetic nanocomposite - Application to uranium sorption from ore leachate Полный текст
2020
Galhoum, Ahmed A. | Eisa, Wael H. | El-Tantawy El-Sayed, Ibrahim | Tolba, Ahmad A. | Shalaby, Zeinab M. | Mohamady, Said I. | Muhammad, Sally S. | Hussien, Shimaa S. | Akashi, Takaya | Guibal, Eric
A high-energy ball milling of magnetite nanoparticles with amino-phosphonic functionalized poly(glycidyl methacrylate) polymer is used for manufacturing a highly efficient magnetic sorbent for U(VI) sorption from aqueous solutions. The Uranyl ions were adsorbed through the binding with amine and phosphonic groups as confirmed by Fourier Transform infrared (FTIR) and X-ray photoelectron spectroscopy (XPS) analyses. The maximum sorption capacity (up to 270 mg U g⁻¹) occurred at pH = 3–4; Langmuir isotherm well describes the sorption process. Small-size particles allow achieving fast uptake (within ≈90 min of contact); and the kinetic profiles are modeled by the pseudo-second order rate equation. Uranium is successfully desorbed from loaded sorbent using 0.25 M NaHCO₃ solution: Sorbent can be recycled with minimal decrease in sorption and desorption efficiency for at least 6 cycles. The sorbent is efficiently used for U(VI) recovery from the acidic leachates of U-bearing ores (after precipitation pre-treatment). Sorption capacity approaches 190 mg U g⁻¹ despite the presence of high concentrations of Fe and Si: the sorbent has a marked preference for U(VI) (confirmed by distribution ratios and selectivity coefficients).
Показать больше [+] Меньше [-]Smoked cigarette butt leachate impacts survival and behaviour of freshwater invertebrates Полный текст
2020
Green, Dannielle Senga | Kregting, Louise | Boots, Bas
Smoked cigarette filters a. k.a. “butts”, composed of plastic (e.g. cellulose acetate) are one of the world’s most common litter items. In response to concerns about plastic pollution, biodegradable cellulose filters are being promoted as an environmentally safe alternative, however, once smoked, both contain toxins which can leach once discarded. The impacts of biodegradable butts as littered items on the receiving environment, in comparison with conventional butts has not yet been assessed. A freshwater mesocosm experiment was used to test the effects of leachate from smoked cellulose acetate versus smoked cellulose filters at a range of concentrations (0, 0.2, 1 and 5 butts L⁻¹) on the mortality and behaviour of four freshwater invertebrates (Dreissena polymorpha, Polycelis nigra, Planorbis planorbis and Bithynia tentaculata). Leachate derived from 5 butts L⁻¹ of either type of filter caused 60–100% mortality to all species within 5 days. Leachate derived from 1 butt L⁻¹ of either type resulted in adults being less active than those exposed to no or 0.2 butts L⁻¹ leachate. Cigarette butts, therefore, regardless of their perceived degradability can cause mortality and decreased activity of key freshwater invertebrates and should always be disposed of responsibly.
Показать больше [+] Меньше [-]Leaching behaviors and speciation of cadmium from river sediment dewatered using contrasting conditioning Полный текст
2020
Li, Tian | Shi, Yafei | Li, Xiaoran | Zhang, Huiqin | Pi, Kewu | Gerson, Andrea R. | Liu, Defu
Chemical conditioning is an effective strategy for improved river sediment dewatering affecting both the dewatering efficiency and subsequent resource utilization of the dewatered cake. Two types of conditioning agents, polyaluminium chloride (PAC)/cationic polyacrylamide (PAM) (coagulation precipitation conditioning agent, referred to as P–P conditioning) and ferrous activated sodium persulfate (advanced oxidation conditioning agent, referred to as F–S conditioning) were examined. With increasing leach liquid to solid (L/S) ratio the concentration of Cd for the real time leachates from the dewatered cakes decreased, but the leaching ratio of Cd in both P–P and F–S dewatered cakes increased. With the same L/S, the leaching ratio was reduced for both types of conditioning, as compared to no conditioning, with the leaching ratio being least with F–S conditioning. The leaching ratio of Cd in the dewatered cake with L/S of 100 L kg⁻¹ was reduced from 21.3% of the total Cd present for the un-conditioned sediment to 12.5% upon P–P conditioning and 11.6% upon F–S conditioning. Furthermore, the different conditioning methods affected the Cd speciation in the dewatered cakes reducing the easy-to-leach speciation of exchangeable and carbonate-bound Cd species and increasing the potential-to-leach speciation of iron-manganese oxide and organically bound Cd species and also the difficult-to-leach species. Risk assessment indicates that the risk due to Cd leaching from the dewatered cakes at L/S of 100 L kg⁻¹ was reduced from high risk to medium risk after P–P and F–S conditioning with reduced bioavailability.
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