Rice husk ash concrete (RHAC) is a new type of concrete that has been rapidly gaining acceptance in recent years. In this paper, the improvement effect of rice husk ash (RHA) on the sulfate erosion performance of concrete was confirmed. The ratio of rice husk ash concrete (RHAC) was optimized and compared with ordinary concrete (OC). The performance degradation of 9%RHAC (rice husk ash at 9% by weight of cement) and OC within 135 times erosion dry–wet cycles solution with Na₂SO₄ at 5% by weight of solution were studied, including the change of apparent phenomena, compressive strength, tensile strength, effective porosity, and dynamic elastic modulus. The microstructure changes of samples before and after sulfate dry–wet cycle were observed by using a scanning electron microscope (SEM). The results show that with the increase of sulfate dry–wet cycle times, the concrete specimen gradually peels off and expands in volume. The compressive strength and tensile strength increase first and then drop sharply, the effective porosity decreases first and then increases, and the relative dynamic elastic modulus increases and then decreases. The reason is that the ettringite and gypsum are formed by the reaction of sulfate intrusion and hydration products under wetting treatment. After drying treatment, ettringite and free water combine to form sodium sulfate. In the early of circulation, ettringite, gypsum, and sodium sulfate fill the internal pores of the concrete and improve the density. As the number of sulfate dry–wet cycles increases, expansion products accumulate, causing structural expansion damage and deterioration of mechanical performance. However, the hydrated calcium silicate hydrate gel was produced by mixing rice husk ash with concrete to improve the material strength and corrosion resistance. The deterioration degree of the 9%RHAC is better than that of OC at all stages. Finally, the damage constitutive models were established, and the accuracy is higher compared with the measured value.

The wide availability of pollutant by-products from the leather industries has been a key factor in driving the research into converting these low-cost by-products into high value-added collagen-based products. In this study, collagen hydrolysate (CH) was extracted from hide trimming waste from the tanneries and used to prepare biodegradable films with chitosan nanoparticles (CNPs) with different concentrations to develop an alternative product to non-biodegradable plastics. The effects of CNPs concentration on the thickness, mechanical, water barrier, thermal, light transmittance, color properties, and opacity of CH-based films were investigated. The results clearly show that the tensile strength and elastic modulus values of CH/CNPs films increase significantly as the concentration of CNPs increases, while the elongation at break, water solubility, and water vapor permeability values decrease. In addition, scanning electron microscopy (SEM) showed uniform distributions of CNPs in the CH-based films. Based on the results obtained, the extraction of CH from hide trimming wastes and reuse in the production of biodegradable films will both prevent these valuable wastes from being dispose into the landfills and will be an alternative to fossil-derived plastics in the future.

Calcium carbide residue (CCR) is generated from acetylene gas production, and it is highly alkaline and contains a very high amount of calcium. Nano silica (NS), on the other hand, is mostly used in combination with other pozzolanic materials in concrete to ignite the reactivity of the material and to improve the properties of the concrete. This study investigated the effect of CCR incorporated in concrete mixtures to partially replace cement content at 0 to 30% (interval of 7.5%). NS was used as an additive by weight of binder at levels 0 to 4% in increment of 1%. Thus, response surface methodology (RSM) was employed to investigate the effects of CCR and NS on the properties of the concrete, including compressive strength, flexural strength, splitting tensile strength, modulus of elasticity (MoE), and water absorption. The RSM was used for model development predicted concrete’s properties and carried out mixture multi-objective optimization by maximizing strengths, MoE, and minimizing water absorption. The results showed that using up to 15% CCR improved the strengths, MoE, and water absorption of the concrete. Adding up to 3% NS further enhanced the strengths, MoE, and water absorption significantly. The developed models for predicting the properties of the concrete using RSM were highly efficient with high degree of correlation. The optimization solutions indicated that the best optimum or best mix combination based on maximum strengths and MoE with minimum water absorption was achieved by replacing 10.6% cement with CCR and adding 1.95% NS by the weight of cementitious materials.

Steelmaking slag is one of the most massive industrial by-products generated during steelmaking processes. This paper presents the current steelmaking slag production status and its potential to use as mineral aggregates in base/sub-base layer of road pavement. The mechanical properties of steelmaking slag were confirmed by the test method specified in Vietnam specification. The volume stability test of the slag was conducted based on JIS A 5015-2018 (Japanese Industrial Standard: Iron and steel slag for road construction). From the results, it was confirmed that steelmaking slag can satisfy all the mechanical requirements specified in Vietnam specification and the requirements regarding stability specified in JIS A 5015-2018. In addition, it was found that the elastic modulus of steelmaking slag applied as a base or sub-base layer in pavement was higher than that of the conventional graded aggregate made from mineral aggregate. Therefore, the thickness of pavement can be reduced by using steelmaking slag, and the construction cost can be lower.

The quest for eco-sustainable binders like agro-wastes in concrete to reduce the carbon footprint caused by cement production has been ongoing among researchers recently. The application of agro-waste-based cementitious materials in binary concrete has been said to improve concrete performance lately. Coconut and groundnut shells are available in abundant quantities and disposed of as waste in many world regions. Therefore, the use of coconut shell ash (CSA) and groundnut shell ash (GSA) in a ternary blend provides synergistic benefits with Portland cement (PC) and may be sustainably utilized in concrete as ternary cementitious material (TCM). Therefore, this study presents concrete performance with CSA and GSA in a grade 30 ternary concrete. Two hundred ten numbers of standard concrete samples were cast for checking the fresh and mechanical properties of concrete at curing ages of 7, 28, and 90 days. After 28-day curing, the experimental results show an increment in compressive, tensile, and flexural strength by 11.62%, 8.39%, and 9.46% at 10% TCM cement replacement, respectively. The concrete density and permeability coefficient reduce as TCM’s content increases. The modulus of elasticity after 90 days improved with the addition of TCM. The concrete’s sustainability assessment indicated that the emitted carbon for concrete decreased by around 16% using 20% TCM in concrete. However, the workability of fresh concrete declines as TCM content increases.

Demand for particleboards keeps increasing and as such more trees are fell for its production, engendering deforestation. For the purpose of reducing falling of trees, this study, focused on recycling of waste paper in the development of paperboard as alternative to particleboards used for furniture and interior household applications. Kenaf fiber (KF) was blended at varying proportions of 0, 1, 2, 3, 4, and 5 wt.% with 20 wt.% constant cement and 20 wt.% constant coconut shell powder while the remaining was paper pulp. Board specimen developed were cured for 14, 28, and 90 days and mechanical properties were examined. Results obtained showed that fiber dosage improved bond strength and screw holding strengths as compared with the control mix. Similarly, modulus of rupture was enhanced with KF loading as compared with control mix while 1 to 3 wt.% KF spawned enhancement of modulus of elasticity. However, 4 and 5 wt.% KF led to a reduction in the modulus. Infusion of the fiber enhanced tensile strength from 1 to 3 wt.% content. 14-day and 28-day curing periods were observed to improve properties while the 90-day curing period is detrimental to all properties. Optimization via signal-to-noise ratio revealed an optimum mix of 2 wt.% obtained for fiber and an optimum curing duration of 28 days.

Concrete is one of the most important materials that are used in the construction industry all around the world. A larger part of the capacity in concrete is generally employed by the coarse aggregate. Due to the tremendous use of coarse aggregate in the construction industry, the material is getting degraded. In order to preserve the natural material, we are in search of an alternate material that can be used in concrete instead of the original one. So in this research work, it has been attempted to study the mechanical behaviour of lightweight concrete when we use waste coconut shell as coarse aggregate inside concrete. To improve the strength of the concrete, we also use the sisal fibres in various proportions ranging between 1 and 5% in accordance to the binder weight. After the mechanical property tests such as the compression test, spilt tensile strength, flexural test, modulus of elasticity test, and impact resistant test were conducted, finally it was concluded that there was increment in the compression strength up to 5%, and tensile strength was increased to 17% and elastic modulus to 7% when the fibre content used was 3%. Thus, with the use of these waste materials, it was found that the concrete’s strength gets increased and it leads to the formation of sustainable concrete thus reducing the pollution in the environment.

Zinc tailing waste is a type of mine waste generated during the extraction of zinc metal. Disposal of a huge amount of mine tailing waste is an open area and tailing dam causing a negative impact on the natural ecosystem and human health. In this research study, the mechanical properties and durability performance of concrete containing zinc mine tailing waste was investigated through an experimental and statistical analysis. The mechanically treated and untreated zinc tailing waste was used as a cement substitute in concrete production. Concrete specimens were fabricated by replacing cement (0%, 5%, 10%, 15%, and 20%) with the mechanically treated and untreated zinc mine tailing waste. The effect of the zinc mine tailing waste was investigated by conducting the various mechanical (compressive strength and elastic modulus) tests, durability (ultrasonic pulse velocity, water absorption, chloride penetration, carbonation, sulfate attack) tests. The X-ray diffraction (XRD) analysis and scanning electron microscopy (SEM) on concrete samples were also conducted for microstructure analysis. According to the various tests conducted, all concrete properties showed comparable results at the 5% cement substitution in concrete by mechanically treated zinc tailing waste. However, the zinc tailing waste concrete was shown to be more sulphate resistance than the control concrete. Test findings suggest that it is feasible to use 10% mechanically treated and 5% untreated zinc tailing waste as a substitute for cement in concrete to reduce the adverse effect on the environment.

This work is focused on the design and preparation of polymer inclusion membranes (PIMs) for potential applications for stannous cation sequestration from water. For this purpose, the membranes have been synthesized employing two polymeric matrices, namely, polyvinylchloride (PVC) and cellulose triacetate (CTA), properly enriched with different plasticizers. The novelty here proposed relies on the modification of the cited PIMs by selected extractants expected to interact with the target cation in the membrane bulk or onto its surface, as well as in the evaluation of their performances in the sequestration of tin(II) in solution through chemometric tools. The composition of both the membrane and the solution for each trial was selected by means of a D-Optimal Experimental Design. The samples such prepared were characterized by means of TG-DTA, DSC, and static contact angles investigations; their mechanical properties were studied in terms of tensile strength and elastic modulus, whereas their morphology was checked by SEM. The sequestering ability of the PIMs toward stannous cation was studied by means of kinetic and isotherm experiments using DP-ASV. The presence of tin in the membranes after the sequestration tests was ascertained by μ-ED-XRF mapping on selected samples.

The production of cement contributes to 10% of global carbon dioxide (CO₂) pollution and 74 to 81% towards the total CO₂ pollution by concrete. In addition to that, its low strength-to-weight ratio, high density and thermal conductivity are among the few limitations of heavy weight concrete. Therefore, this study was carried out to provide a solution to these limitations by developing innovative eco-friendly lightweight foamed concrete (LFC) of 1800 kg/m³ density incorporating 20–25% palm oil fuel ash (POFA) and 5–15% eggshell powder (ESP) by weight of total binder as supplementary cementitious material (SCM). The influence of combined utilization of POFA and ESP on the fresh state properties of eco-friendly LFC was determined using the J-ring test. To determine the mechanical properties, a total of 48 cubes and 24 cylinders were prepared for compressive strength, splitting tensile strength and modulus of elasticity each. A total of 24 panels were prepared to determine the thermal properties in terms of surface temperature and thermal conductivity. Furthermore, to assess the environmental impact and eco-friendliness of the developed LFC, the embodied carbon and eco-strength efficiency was calculated. It was determined that the utilization of POFA and ESP reduced the workability slightly but enhanced the mechanical properties of LFC (17.05 to 22.60 MPa compressive strength and 1.43 to 2.61 MPa tensile strength), thus satisfies the ACI213R requirements for structural lightweight concrete and that it can be used for structural applications. Additionally, the thermal conductivity reduced ranging from 0.55 to 0.63 W/mK compared to 0.82 W/mK achieved by control sample. Furthermore, the developed LFC showed a 16.96 to 33.55% reduction in embodied carbon and exhibited higher eco-strength efficiency between 47.82 and 76.97%. Overall, the combined utilization of POFA and ESP as SCMs not only enhanced the thermo-mechanical performance, makes the sustainable LFC as structural lightweight concrete, but also has reduced the environmental impacts caused by the disposal of POFA and ESP in landfills as well as reducing the total CO₂ emissions during the production of eco-friendly LFC.