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Substantial decreases of light absorption, concentrations and relative contributions of fossil fuel to light-absorbing carbonaceous aerosols attributed to the COVID-19 lockdown in east China
2021
Lin, Yu-Chi | Zhang, Yan-Lin | Xie, Feng | Fan, Mei-Yi | Liu, Xiaoyan
To prevent spreads of Coronavirus disease-2019 (COVID-19), China adopted the lockdown measures in late January 2020, providing a platform to study the response of air quality and atmospheric chemical and physical properties to strict reduced emissions. In this study, the continuous measurements of aerosol light absorption were conducted in Nanjing, east China, from January 3 to March 31, 2020. Our results showed that the contribution of black carbon (BC) to light absorption at the different wavelengths was more than 75% and the rest light absorption was contributed by brown carbon (BrC), which was mainly originated from primary emissions. Secondary BrC absorption, which was mainly produced by photochemical oxidation, constituted a minor fraction (2–7%) of the total absorption. Compared with the sampling in the pre-lockdown, the significant decreases of BC (43%) and secondary BrC absorption (31%) were found during the lockdown period, resulting in a substantial decrease of solar energy absorbance by 36% on a local scale. The control measures also changed the diurnal variations of light absorption. Due to the reduced emissions, the relative fraction of fossil fuel to BC also dropped from 78% in the pre-lockdown to 71% in the lockdown. The concentrations of BC, PM₂.₅ and NO₂ decreased 1.1 μg m⁻³, 33 μg m⁻³ and 9.1 ppb whereas O₃ concentration increased 9.0 ppb during the COVID-19 lockdown period. The decreased concentrations of BC, PM₂.₅ and NO₂ were mainly contributed by both emission reduction (51–64%) and meteorological conditions (36–49%). Our results highlighted that the balance of control measures in alleviation of particulate matter (PM) and O₃ pollution, and meteorology should be seriously considered for improvement of air quality in this urban city of China.
Показать больше [+] Меньше [-]Energy and environmental applications of Sn4+/Ti4+ doped α-Fe2O3@Cu2O/CuO photoanode under optimized photoelectrochemical conditions
2021
Nagappagari, Lakshmana Reddy | Lee, Jaewon | Lee, Hyeonkwon | Jeong, Beomgyun | Lee, Kiyoung
The most promising technique for directly converting solar energy into clean fuels and environmental remediation by organic dye degradation is photoelectrochemical (PEC) process. We introduced Sn⁴⁺/Ti⁴⁺ doped α-Fe₂O₃@CuₓO heterojunction photoanode with complete optimization for PEC hydrogen (H₂) generation and organic dye degradation. Improvement of photocurrent photo and reducing overpotentials under optimized conditions lead to enhancing PEC performances, degradation efficiency of organic compounds, and H₂ generation generation rate. The optimized heterojunction photoanode (5TiFe@CuₓO-D) showed IPCE exceeding 42% compared with pristine hematite (Fe₀.₀₁–800₆ₕ) nanostructures (28%). Additionally, all the optimized photoanodes showed higher PEC stability for 10 h. Time-resolved PL spectra confirm the improved average lifetime for heterojunction photoanodes, supporting the enhanced PEC performance. Optimized 5TiFe@CuₓO-D material achieved PEC H₂ generation of ∼300 μL h⁻¹.cm⁻² which is two times higher than pristine hematite’s activity (150 μL h⁻¹.cm⁻²) and almost 99% degradation efficiency within 120 min of irradiation time. Therefore, a state-of-the-art study has been explored for hematite-based heterojunction photoanodes reflecting the superior PEC performance and hydrogen, methyl orange (MO) dye degradation activities. The improved results were reported because of stable morphology and better crystallinity acquired through systematic investigation of thermal effects and hydrothermal duration, improved electrical properties by Sn/Ti doping into the lattice of α-Fe₂O₃ and optimization of CuₓO deposition methods. The formation of well-defined heterojunction minimizes the recombination of the charge carrier and leads to effective transportation of excited electrons for the enhanced PEC performance.
Показать больше [+] Меньше [-]Ecological and human health risk assessment of metals leached from end-of-life solar photovoltaics
2020
Nain, Preeti | Kumar, Arun
Photovoltaic industry has shown tremendous growth among renewable energy sector. Though, this high installation rate will eventually result in generation of large volume of end-of-life photovoltaic waste with hazardous metals. In present study, reported leached metal contents from different photovoltaics in previous investigations were utilized for (i) potential fate and transport analysis to soil and groundwater and, (ii) estimating ecological and human health risks via dermal and ingestion pathways for child and adult sub-populations. The results indicate that the children are at highest risk, mainly due to lead (hazard quotient from 1.2 to 2.6). Metals, such as cadmium, lead, indium, molybdenum and tellurium pose maximum risks for child and adult sub-populations via soil-dermal pathway followed by soil-ingestion pathway. This is further proved by calculated high values of contamination factor and geo-accumulation index for cadmium (102.4), indium (238.9) and molybdenum (16.12). The estimated soil contamination is significant with respect to aluminium, silver, cadmium, iron, lead, however, groundwater contamination was insignificant. Exposure to polluted soils yields an aggregate hazard index (for non-cancer effects) > 1 for all four pathways, with soil dermal pathway as the major contributor. Lead poses significant cancer risk for all scenarios (average risk: 0.0098 to 0.047 (soil) and 2.1 × 10⁻⁵ to 3.5 × 10⁻⁵ (groundwater)), whereas acceptable non-cancer risk was observed for other metals from groundwater exposure. Further, variance contribution and spearman correlation coefficient analysis show that metal concentration, exposure frequency and ingestion rate are the main contributors towards overall uncertainty in risk estimates. More detailed assessment for environmentally-sensitive metals should be carried out by considering other field breakage scenarios also, although the assessment suggests low risk for majority of metals examined.
Показать больше [+] Меньше [-]Extensive solar light harvesting by integrating UPCL C-dots with Sn2Ta2O7/SnO2: Highly efficient photocatalytic degradation toward amoxicillin
2020
Le, Shukun | Yang, Weishan | Chen, Gonglai | Yan, Aoyu | Wang, Xiaojing
The carbon dots (C-dots) mediated Sn₂Ta₂O₇/SnO₂ heterostructures with spongy structure were successfully assembled by simple hydrothermal route. The photocatalytic removal efficiency of amoxicillin (AMX, 20 mg L⁻¹) over C-dots/Sn₂Ta₂O₇/SnO₂ was estimated to reach up 88.3% within 120 min simulated solar light irradiating. Meanwhile, the HPLC-MS/MS analysis and density functional theory (DFT) computation were examined to clarify the photo-degradation pathway of AMX. The mechanism investigation proposed that with the modification of C-dots, the photocatalysts improves the utilization of solar energy by harvesting the long wavelength solar light due to their unique up-converted photoluminescence (UCPL). In addition, the porous spongy structure and plenty of tiny C-dots promote the ability of adsorption by enlarged specific surface area. Furthermore, the C-dots mediated Z-type heterojunction of Sn₂Ta₂O₇/SnO₂ facilitates the efficient separation and transfer of photo-induced carriers. Our work affords a promising approach for the design of the high-efficient photocatalysts to remedy poisonous antibiotics in aqueous environment.
Показать больше [+] Меньше [-]3D graphene-based gel photocatalysts for environmental pollutants degradation
2019
Zhang, Fan | Li, Yue-Hua | Li, Jing-Yu | Tang, Zi-Rong | Xu, Yi-Jun
Enormous research interest is devoted to fabricating three-dimensional graphene-based gels (3D GBGs) toward improved conversion of solar energy by virtue of the intrinsic properties of single graphene and 3D porous structure characteristics. Here, this concise minireview is primarily focused on the recent progress on applications of 3D GBGs, including aerogels and hydrogels, in photocatalytic degradation of pollutants from water and air, such as organic pollutants, heavy metal ions, bacteria and gaseous pollutants. In particular, the preponderances of 3D GBG photocatalysts for environmental pollutants degradation have been elaborated. Furthermore, in addition to discussing opportunities offered by 3D GBG composite photocatalysts, we also describe the existing problems and the future direction of 3D GBG materials in this burgeoning research area. It is hoped that this review could spur multidisciplinary research interest for advancing the rational utilization of 3D GBGs for practical applications in environmental remediation.
Показать больше [+] Меньше [-]Drip fertigation significantly reduces nitrogen leaching in solar greenhouse vegetable production system
2019
Lv, Haofeng | Lin, Shan | Wang, Yafang | Lian, Xiaojuan | Zhao, Yiming | Li, Yingjie | Du, Jiuyue | Wang, Zhengxiang | Wang, Jingguo | Butterbach-Bahl, Klaus
Vegetable production in solar greenhouses in northern China results in the excessive use of nitrogen (N) fertilizers and water via flooding irrigation. Both factors result in low N use efficiency and high environmental costs because groundwater becomes contaminated with nitrate (NO3−). Four consecutive tomato (Lycopersicum esculentum Mill.) cropping seasons were tested whether drip fertigation and/or the incorporation of maize straw (S) may significantly reduce NO3− and dissolved organic N (DON) leaching while increasing the water-use efficiency (WUE) and partial factor productivity of applied N (PFPN) of the tomatoes. The following treatments were used: ① conventional flooding irrigation with overfertilization (CIF, 900 kg N ha−1 season−1), ② CIF + S, ③ drip irrigation with optimized fertilization (DIF, 400 kg N ha−1 season−1), ④ DIF + S. We found that (1) DIF significantly increases the PFPN and WUE by 262% and 73% without compromising the yield compared with CIF, respectively. (2) For CIF, approximately 50% of the total N input was leached at a NO3−/DON ratio of approximately 2:1. (3) Compared with CIF, DIF reduced NO3− and DON leaching by 88% and 90%, respectively. Water percolation was positively correlated with N leaching (p < 0.001). (4) Straw application only reduced NO3− leaching losses in the first year and did not affect DON leaching overall, although DON leaching was increased in DIF in the first growing season. In conclusion, DIF significantly reduces NO3− and DON leaching losses by approximately 90% compared with the current farmer practice (CIF). Considering the significant DON leaching losses, which have been overlooked because previous measurements focused on NO3−, DON should be considered as a primary factor of environmental pollution in conventional solar greenhouse vegetable production systems.
Показать больше [+] Меньше [-]Seasonal effects of atmospheric particulate matter on performance of different types of photovoltaic modules in sanliurfa, Turkey
2020
Dogan, Tuba Rastgeldi | Beşli, Nurettin | Aktacir, Mehmet Azmi | Dinç, Merve Nur | İlkhan, Mehmet Akif | Öztürk, Fatma | Yıldız, Melek
In Turkey, Southeastern Anatolia region is the highest in terms of solar radiation level. However, the provinces in the region are subject to Particulate Matter (PM) coming from the Sahara desert, the Syrian Desert and the Arabian Desert by atmospheric transport. The daily limit of PM₁₀ and PM₂.₅ set by WHO for health is often exceeded in Sanliurfa. PM₁₀ and PM₂.₅ pollutants also accumulate on the Photovoltaic (PV) panels and cause loss of PV panel performance. In this study, the effects of atmospheric dust deposition on the performance of PV panel was determined for both monocrystalline and polycrystalline technologies under Sanliurfa atmospheric conditions. Two panels with the same characteristics were used for each PV panel group from 2 different PV technologies. One of the panels in the group was cleaned by washing with distilled water every Monday while the other was not cleaned. Thus, the effect of the dust accumulation on the PV panel was determined by comparison to the cleaned PV panel. PV panel power is measured with I–V meter. Panel surface temperature, solar radiation and other meteorological parameters are measured simultaneously. The measurements were done every Monday, Wednesday and Friday at 12:00 am from May 1 to December 31, 2019. It is observed that the dust accumulation reduces the PV power output up to 8% depending on the amount of radiation. During the summer months, the power loss on the average is 4.33% for monocrystalline and 4.57% for polycrystalline. In the autumn months, it is less than 1.77%.
Показать больше [+] Меньше [-]Enhanced Solar Photovoltaic Power Production Approach for Electric Vehicle Charging Station: Economic and Environmental Aspects
2024
J. Techo, S. Techo, A. Palamanit, E. Saniso, A. A. Chand and P. Prasannaa
In recent years, Electric Vehicles (EVs) are contributing a major share in Thailand and benefit the environment. Most of the EV charging stations are sourced from solar energy as it becomes a carbon-free source of energy production. Secondly, Thailand is rich in solar irradiance, and higher irradiance leads to higher power production. On the other hand, in tropical conditions, solar Photovoltaic (PV) module temperature increases following the solar irradiance due to high ambient temperature, resulting negative impact on the efficiency and lifespan of photovoltaic (PV) modules. Further, to increase PV power production, in this study, different rates of cooling strategies are proposed. The study found that reducing the temperature by 5% to 25% resulted in increased average power outputs of 5947.94W, 6021.43W, 6094.92W, 6168.41W, and 6241W, respectively. Notably, 25% of the cooling rate achieved higher production. However, it is lower than the nominal power production. Following that, economic analysis and environmental impacts are analyzed for Thailand’s EV charging station using a different cooling rate of PV module. Overall, it is concluded that, depending on the economic viability of the EV charging station, cooling technology can be applied, and it will benefit the EV charging station both economically and environmentally. To further enhance the solar PV power production approach for EV charging stations in Thailand, it is imperative to prioritize future endeavors towards optimizing cooling technology, integrating energy storage, and implementing supportive policies.
Показать больше [+] Меньше [-]Design and Impact Analysis of a Grid-Connected Solar Photovoltaic System in Ibri, Oman
2024
Arshad Mehmood and Waleed Saif Abdullah Habib Al Kalbani
This study investigates the feasibility of establishing a grid-connected power system in Ibri, Oman. The primary goal is to address the rising energy demands and contribute to fighting climate change. By leveraging Ibri’s resources, the research highlights the feasibility of such a system, focusing on its economic, technological, and environmental benefits. Using PVsyst software for planning and evaluation, the study assesses climate conditions, component choices, and performance predictions to ensure optimal system performance. The proposed 10.81 kWp solar power system estimates an energy production of 16,981 kWh, achieving a system efficiency of 67.2% based on the performance ratio (PR). The financial analysis estimates a payback period of 7.5 to 8.3 years, with an internal rate of return (IRR) of 11.15% and a net present value (NPV) of $32,024.28, confirming the project’s viability. The system is expected to reduce carbon emissions by 379.939 tons over its lifetime, highlighting the significant ecological benefits of adopting solar energy (SE). The research demonstrates that incorporating PV systems in regions like Ibri is technically viable, economically beneficial, and environmentally advantageous. This study is a valuable resource for energy initiatives, promoting sustainable power production methods and encouraging the broader adoption of renewable technologies for a sustainable future.
Показать больше [+] Меньше [-]Experimental evaluation of a solar-driven adsorption desalination system using solid adsorbent of silica gel and hydrogel
2022
Abad, Mostafa Zarei Saleh | Behshad Shafii, Mohammad | Ebrahimpour, Benyamin
Nowadays, the world is facing a shortage of fresh water. Utilizing adsorbent materials to adsorb air moisture is a suitable method for producing freshwater, especially combining the adsorption desalination system with solar energy devices such as solar collectors. The low temperature of solar collectors has caused some water to remain in the adsorbents in the desorption process and has reduced the possibility of using these systems. In this research, for the first time, an evacuated tube collector (ETC) is used as an adsorbent bed so that the temperature of the desorption process reaches higher values and as a result, more fresh water is expected to produced. In this study, two adsorption desalination systems (ADS) are experimentally investigated. In the first system, a laboratory experimental setup using silica gel and hydrogel adsorbents is used to investigate freshwater production using each of the two adsorbents. The effect of different parameters such as variable adsorption and desorption time, variable temperature and humidity of inlet air, and variable adsorbent mesh sizes on the desalination process is evaluated. Then, in the second system, an innovative configuration of the solar-driven adsorption desalination system with an ETC full of silica gel is studied. In the laboratory experimental setup, the maximum amount of water produced by silica gel is 0.36 L/kg and by hydrogel is 0.58 L/kg. In the solar-driven adsorption desalination system, the largest amount of accumulated water production, daily efficiency, and cost per liter (CPL) of produced water are 1.518 kg/m² day, 11.25%, and 0.0699 $/L, respectively. Therefore, this new configuration for an adsorption desalination system seems feasible.
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