A wide range of chemicals and dyes are being used in textile industry, and are often found in the wastewater produced. This study attempts to investigate the reduction of COD, TSS, and dye in effluents from the dyeing and washing unit of textile industry, using electrocoagulation process. The reactor is equipped with 10 iron electrodes, connected to a direct current (DC) source in a monopolar electrode configuration. In each stage of the experiment, 2.5 l of the effluent enters the reactor and the effects of a number of important operational parameters such as voltage, pH, and reaction time is studied on the removal of COD, TSS, and dye parameters. Results show that the optimum operational conditions are reaction time of 120 min, voltage of 30 V, and pH of 7, which reduces COD, TSS, and dye by 87%, 91%, and 98%, respectively. Therefore, it has been concluded that the efficiency of pollutants removal from the wastewater improves as voltage and reaction time are increased.

We studied the effects of long-term exposure (nine years) of birch (Betula papyrifera) trees to elevated CO(2) and/or O(3) on reproduction and seedling development at the Aspen FACE (Free-Air Carbon Dioxide Enrichment) site in Rhinelander, WI. We found that elevated CO(2) increased both the number of trees that flowered and the quantity of flowers (260% increase in male flower production), increased seed weight, germination rate, and seedling vigor. Elevated O(3) also increased flowering but decreased seed weight and germination rate. In the combination treatment (elevated CO(2)+O(3)) seed weight is decreased (20% reduction) while germination rate was unaffected. The evidence from this study indicates that elevated CO(2) may have a largely positive impact on forest tree reproduction and regeneration while elevated O(3) will likely have a negative impact.

Recent studies have demonstrated that natural abundance 15N can be a useful tool for assessing nitrogen saturation, because as nitrification and nitrate loss increase, δ15N of foliage and soil also increases. We measured foliar δ15N at 11 high-elevation spruce-fir stands along an N deposition gradient in 1987-1988 and at seven paired northern hardwood and spruce-fir stands in 1999. In 1999, foliar δ15N increased from -5.2 to -0.7[per thousand] with increasing N deposition from Maine to NY. Foliar δ15N decreased between 1987-1988 and 1999, while foliar %N increased and foliar C:N decreased at most sites. Foliar δ15N was strongly correlated with N deposition, and was also positively correlated with net nitrification potential and negatively correlated with soil C:N ratio. Although the increase in foliar %N is consistent with a progression towards N saturation, other results of this study suggest that, in 1999, these stands were further from N saturation than in 1987-1988. Foliar δ15N increased with increasing N deposition from Maine to NY, but decreased between 1987-1988 and 1999

The evaluation of microbial availability of contaminants is of high importance for better reflecting the processes governing contaminant fate in soil and for establishing the risk associated with contaminated sites. A sub-critical water extraction technique was assessed for its potential to determine the microbially degradable fraction of [14C]phenanthrene-associated activity in two dissimilar soils at three different ageing times (14, 28 and 49 days). For the majority of determinations, no significant (p > 0.05) difference between sub-critical water-extracted 14C-activity at 160 °C and the fraction mineralized by catabolically active Pseudomonas sp. was observed. Collectively, the results suggested that the sub-critical water extraction technique was an appropriate technique for predicting the biodegradable fraction of phenanthrene-associated 14C-activity in dissimilar soils following increasing soil-contaminant contact time. Sub-critical water extraction reflects phenanthrene bioaccessibility in the soil.

During the last 50 years nitrate concentrations in Buttermere and Wastwater (Cumbria, UK) have risen significantly, by 70 and 100%, respectively. By estimating contemporary nitrate fluxes in the lakes' catchments and in sub-catchments and comparing them with the fractional areas of different soil types, it is deduced that the surface water nitrate is derived almost entirely from organic-rich ranker soils that have a limited ability to retain atmospherically-deposited nitrogen. Little or no nitrate leaches from the other major soil type, a brown podzol, despite it having a lower C:N ratio (12.0 g g-1) than the ranker (17.0 g g-1), nor is there much contribution from the small areas of improved (chemically fertilised) grassland within the catchments. Although some nitrate leaching is occurring, total N losses are appreciably smaller than atmospheric inputs, so the catchment soils are currently accumulating between 3 and 4 g N m-2 a-1. Increases in lakewater nitrate concentrations over 50 years are due to the limited ability of ranker soils to retain atmospherically-deposited nitrogen.

To evaluate sediment quality in different areas affected by oil spills, a weight of evidence approach was employed by including a complete set of parameters as part of four lines of evidence: sediment contamination, biological effects (including biomarkers) and bioaccumulation under laboratory conditions, toxicity in field conditions and benthic community structure. The methodology was applied to sediments from the Bay of Algeciras (S Spain) chronically impacted by different spills, and the Galician Coast (NW Spain) acutely impacted by an oil spill (Prestige 2002). Results obtained have elucidated the sources and fates of pollutants and the type of risk involved for the ecosystem. Factorial analysis revealed that the main factors were those containing toxicity, chemistry and benthic community variables indicating degradation in Algeciras. It has been demonstrated that the impact associated with chronic event of contamination by oil spills are significantly more dangerous and polluted than those related to acute effects. Chronic inputs due to the continuous entrance of contaminants result in much more harm to coastal ecosystems than major but precise environmental impacts.

We present direct evidence of the release of synthetic nanoparticles from urban applications into the aquatic environment. We investigated TiO2 particles as these particles are used in large quantities in exterior paints as whitening pigments and are to some extent also present in the nano-size range. TiO2 particles were traced from exterior facade paints to the discharge into surface waters. We used a centrifugation based sample preparation which recovers TiO2 particles between roughly 20 and 300 nm. Analytical electron microscopy revealed that TiO2 particles are detached from new and aged facade paints by natural weather conditions and are then transported by facade runoff and are discharged into natural, receiving waters. Microscopic investigations are confirmed by bulk chemical analysis. By combining results from microscopic investigations with bulk chemical analysis we calculated the number densities of synthetic TiO2 particles in the runoff. The release of synthetic TiO2 particles from exterior applications into the aquatic environment is demonstrated.

Elemental mercury (Hg0) is a metal with a number of atypical properties, which has resulted in its use in myriad anthropogenic processes. However, these same properties have also led to severe local subsurface contamination at many places where it has been used. As such, we studied the influence of various parameters on Hg(II) sorption onto pyrite (pH, time, Hg(II) concentration), a potential subsurface reactive barrier. Batch sorption studies revealed that total Hg(II) removal increases with both pH and time. X-ray absorption spectroscopy analysis showed that a transformation in the coordination environment at low pH occurred during aging over 2 weeks, to form an ordered monolayer of monodentate Hg–Cl complexes on pyrite. In column studies packed with pure quartz sand, the transport of Hg(II) was significantly retarded by the presence of a thin pyrite-sand reactive barrier, although dissolved oxygen inhibited Hg(II) sorption onto pyrite in the column. Pyrite may be an effective subsurface reactive barrier for Hg in groundwater.

We studied the effectiveness of remediation on microbial endpoints, namely microbial biomass and activity, microbial and plant species richness, of an As-contaminated mine spoil, amended with compost (C) alone and in combination with beringite (B) or zerovalent iron grit (Z), to increase organic matter content and reduce trace elements mobility, and to allow Holcus lanatus and Pinus pinaster growth. Untreated spoil showed the lowest microbial biomass and activity and hydrolase activities, and H. lanatus as sole plant species, whereas the presented aided phytostabilisation option, especially CBZ treatment, significantly increased microbial biomass and activity and allowed colonisation by several plant species, comparable to those of an uncontaminated sandy soil. Microbial species richness was only increased in spoils amended with C alone. No clear correlation occurred between trace element mobility and microbial parameters and plant species richness. Our results indicate that the choice of indicators of soil remediation practices is a bottleneck. Organo-mineral amendment and revegetation of a gold mine spoil increased microbial activity but did not increase microbial species richness.