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Assessing environmental contamination of River Ganga using correlation and multivariate analysis Полный текст
2015
Bhutiani, Rakesh | Khanna, D.R. | Tyagi, Bharti | Tyagi, Prashant | Kulkarni, Dipali
The aim of this study was to assess the environmental impact of socio-cultural practices on the water quality of River Ganga at the foothills of the Garhwal Himalayas in Uttarakhand State, India. The physico-chemical parameters that contributed to the temporal variation and pollution in the river were identified in this study. Principal component analysis (PCA) and Cluster analysis (CA) were used in the identification of anthropogenic factors (industrial, urban sewage, agricultural, land use and mining activities) and natural factors (soil erosion, weathering). The results of this study show that total coliform, fecal coliform, nitrate, sodium, phosphate, sulphate, TDS (Total dissolved solids), temperature, BOD (Biochemical oxygen demand), calcium and chloride are parameters significantly contributing to pollution load.
Показать больше [+] Меньше [-]Vulnerability assessment of surface water quality with an innovative integrated multi-parameter water quality index (IMWQI) Полный текст
2015
Sikder, Md. | Tanaka, Shunitz | Saito, Takeshi | Hosokawa, Toshiyuki | Gumiri, Sulmin | Ardianor, Ardianor | Uddin, Md. | Tareq, Shafi | Shammi, Mashura | Kamal, AK | Kurasaki, Masaaki
The development of a surface water evaluation index is a critical factor in the assessment, restoration and protection of stream water quality. Quantifying water pollution in specific grade using dominant parameters is important, as this can explain the current state of water pollution with accuracy. As a result, an integrated multi-parameter water quality index has been developed. It is based on the 10 most prevailing parameters (pH, conductivity, nitrate ions, phosphate ions, Escherichia coli number, cadmium, chromium, lead, copper and manganese) with a scale of 1 to 4, wherein the grades are classified into 1: good; 1.1-1.5: slightly polluted; 1.6-2.0: moderately polluted; 2.1-2.9: heavily polluted and 3.0-4.0: gravely polluted. The measuring stick used was according to the 2011 background values of the World Health Organization (WHO) in which a value of 0.1 was attributed for each, so that the final grade can be calculated. Water quality data were successfully fitted in an integrated multi-parameter water quality index to measure the river water level of pollution, and effectively represented every water bodies. This innovative index is able to quantify pollution with respect to seasons, geography and geomorphology of the respective rivers. Although operative, this index still lacks scientific integrity and as such, more synoptic experiments in the rivers of developing countries are recommended to attain a pragmatic feature.
Показать больше [+] Меньше [-]Concentration and distribution of contaminants in lake trout and walleye from the Laurentian Great Lakes (2008–2012) Полный текст
2015
McGoldrick, Daryl J. | Murphy, Elizabeth W.
Biomonitoring programs for persistent, bioaccumulative, and/or toxic chemicals of concern in fish tissues have been operated by the governments of Canada and the United States in the Great Lakes since the 1970's. The objectives of these programs are to assess concentrations of harmful chemicals in whole body top predator fish as an indicator of ecosystem health and to infer potential harm to fish and fish consuming wildlife in the Great Lakes Basin. Chemicals of interest are selected based upon national and binational commitments, risk assessment, and regulation, and include a wide range of compounds. This review summarizes all available data generated by Environment Canada and the United States Environmental Protection Agency for chemicals measured in whole body homogenates of Lake Trout (Salvelinus namaycush) and Walleye (Sander vitreus) for the time period spanning 2008 to 2012 from each of the five Great Lakes. The summary shows that concentrations of legacy compounds, such as, POPs listed in the Stockholm Convention and mercury continue to dominate the chemical burden of Great Lakes fish. This assessment, and others like it, can guide the creation of environmental quality targets where they are lacking, optimize chemical lists for monitoring, and prioritize chemicals of concern under agreements such as the Great Lakes Water Quality Agreement and the Stockholm Convention.
Показать больше [+] Меньше [-]Predicting fecal indicator organism contamination in Oregon coastal streams Полный текст
2015
Pettus, Paul | Foster, Eugene | Pan, Yangdong
In this study, we used publicly available GIS layers and statistical tree-based modeling (CART and Random Forest) to predict pathogen indicator counts at a regional scale using 88 spatially explicit landscape predictors and 6657 samples from non-estuarine streams in the Oregon Coast Range. A total of 532 frequently sampled sites were parsed down to 93 pathogen sampling sites to control for spatial and temporal biases. This model's 56.5% explanation of variance, was comparable to other regional models, while still including a large number of variables. Analysis showed the most important predictors on bacteria counts to be: forest and natural riparian zones, cattle related activities, and urban land uses. This research confirmed linkages to anthropogenic activities, with the research prediction mapping showing increased bacteria counts in agricultural and urban land use areas and lower counts with more natural riparian conditions.
Показать больше [+] Меньше [-]Investigating social inequalities in exposure to drinking water contaminants in rural areas Полный текст
2015
Delpla, Ianis | Benmarhnia, Tarik | Lebel, Alexandre | Levallois, Patrick | Rodriguez, Manuel J.
Few studies have assessed social inequalities in exposure to drinking water contaminants. This study explores this issue in 593 rural municipalities of Québec, Canada. Quartiles of an ecological composite deprivation index were used as a proxy of socioeconomic status. Total trihalomethanes (TTHMs) and lead were chosen as proxies of chemical drinking water quality. The results show that the majority of deprived rural municipalities apply no treatment to their water (26%) or use a basic treatment (51%), whereas a relative majority of the wealthiest municipalities (40%) use advanced treatment. The proportion of municipalities having important lead (>5 μg/L) levels is highest in most deprived municipalities. Moreover, most deprived municipalities have a higher risk of high tap lead levels (RR = 1.33; 95%CI: 1.30, 1.36). Conversely, most deprived municipalities have a lower risk of high TTHMs levels (RR = 0.78; 95%CI: 0.69, 0.86). These findings suggest an environmental inequality in drinking water contaminants distribution in rural municipalities.
Показать больше [+] Меньше [-]Lake retention of manufactured nanoparticles Полный текст
2015
Koelmans, A.A. | Quik, J.T.K. | Velzeboer, I.
For twenty-five world lakes and three engineered nanoparticles (ENP), lake retention was calculated using a uniformly mixed lake mass balance model. This follows similar approaches traditionally used in water quality management. Lakes were selected such that lake residence times, depths and areal hydraulic loadings covered the widest possible range among existing lakes. Sedimentation accounted for natural colloid as well as suspended solid settling regimes. An ENP-specific mixed sedimentation regime is proposed. This regime combines ENP sedimentation through slow settling with natural colloids from the water column, with faster settling with suspended solids from a selected part of the water column. Although sedimentation data and hydrodynamic concepts as such were not new, their first time combination for application to ENPs shows in which cases lake retention is important for these particles. In combination with ENP emission data, lake retention translates directly into potential risks of ENPs for lake benthic communities.
Показать больше [+] Меньше [-]Increased RO concentrate toxicity following application of antiscalants – Acute toxicity tests with the amphipods Gammarus pulex and Gammarus roeseli Полный текст
2015
Feiner, Mona | Beggel, Sebastian | Jaeger, Nadine | Geist, Juergen
In reverse osmosis, a frequently used technology in water desalination processes, wastewater (RO concentrate) is generated containing the retained solutes as well as so-called antiscalants (AS), i.e. chemical substances that are commonly applied to prevent membrane-blocking. In this study, a risk assessment of a possible discharge of concentrate into a small stream was conducted. The acute toxicity of two concentrates containing two different ASs and of concentrate without AS to the amphipods Gammarus pulex and Gammarus roeseli was studied. Mortality of gammarids exposed to the concentrate without AS was not different to the control, whereas concentrates including ASs caused mortality rates up to 100% at the highest test concentrations after 168 h. Resulting EC50-values were 36.2–39.4% (v/v) after 96 h and 26.6–58.0% (v/v) after 168 h. These results suggest that the ecotoxicological relevance of antiscalants is greater than currently assumed.
Показать больше [+] Меньше [-]A column evaluation of Appalachian coal mine spoils' temporal leaching behavior Полный текст
2015
Orndorff, Zenah W. | Daniels, W Lee | Zipper, Carl E. | Eick, Matt | Beck, Mike
Appalachian surface coal mine overburden affects water quality as drainage percolates through spoil disposal fills. This study evaluated leaching potentials of 15 spoils from south-central Appalachia. Most bulk samples were non acid-forming, all were low in total-S, (≤0.34%), and initial saturated paste specific conductance (SC) ranged from 264 to 3560 μS cm−1. Samples were leached unsaturated (40 cycles) and leachates analyzed for pH, SC, and ion composition. Overall, leachates from unweathered spoils were higher in pH and SC than leachates from weathered spoils. Fine-textured spoils generally produced higher SCs than more coarsely textured spoils. Mean SC for all spoils decreased rapidly from an initial peak of 1468 μS cm−1 (±150) to 247 μS cm−1 (±23). Release patterns for most major ions reflected declining SC. Bicarbonate typically increased with successive leaches, replacing sulfate as the dominant anion. Column SC values were comparable to relevant published field data.
Показать больше [+] Меньше [-]Application of chemometric analysis and self Organizing Map-Artificial Neural Network as source receptor modeling for metal speciation in river sediment Полный текст
2015
Pandey, Mayank | Pandey, Ashutosh Kumar | Mishra, Ashutosh | Tripathi, B.D.
Present study deals with the river Ganga water quality and its impact on metal speciation in its sediments. Concentration of physico-chemical parameters was highest in summer season followed by winter and lowest in rainy season. Metal speciation study in river sediments revealed that exchangeable, reducible and oxidizable fractions were dominant in all the studied metals (Cr, Ni, Cu, Zn, Cd, Pb) except Mn and Fe. High pollution load index (1.64–3.89) recommends urgent need of mitigation measures. Self-organizing Map-Artificial Neural Network (SOM-ANN) was applied to the data set for the prediction of major point sources of pollution in the river Ganga.
Показать больше [+] Меньше [-]An investigation of the well-water quality: immunosensor for pathogenic Pseudomonas aeruginosa detection based on antibody-modified poly(pyrrole-3 carboxylic acid) screen-printed carbon electrode Полный текст
2015
Bekir, Karima | Bousimma, Feriel | Barhoumi, Houcine | Fedhila, Kais | Maaref, Abderrazak | Bakhrouf, Amina | Ben Ouada, Hafedh | Namour, Philippe | Jaffrezic-Renault, Nicole | Ben Mansour, Hedi | Laboratoire d’analyse, de traitement et de valorisation des polluants de l’environnement et des produits [Monastir] (LATVPEP) ; Faculté de Pharmacie [Monastir] (FPHM) | Laboratoire des Interfaces et Matériaux Avancés [Monastir] (LIMA) ; Faculté des Sciences de Monastir (FSM) ; جامعة المنستير - Université de Monastir - University of Monastir (UM)-جامعة المنستير - Université de Monastir - University of Monastir (UM) | Res Unit, Anal & Proc Appl Environm ; جامعة المنستير - Université de Monastir - University of Monastir (UM) | Milieux aquatiques, écologie et pollutions (UR MALY) ; Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA) | River Monitoring & Management - Suivi et gestion des rivières (2014-2016) ; Institut des Sciences Analytiques (ISA) ; Université Claude Bernard Lyon 1 (UCBL) ; Université de Lyon-Université de Lyon-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Claude Bernard Lyon 1 (UCBL) ; Université de Lyon-Université de Lyon-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS) | ISA-Interfaces & biosensors - Interfaces & biocapteurs ; Institut des Sciences Analytiques (ISA) ; Université Claude Bernard Lyon 1 (UCBL) ; Université de Lyon-Université de Lyon-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Claude Bernard Lyon 1 (UCBL) ; Université de Lyon-Université de Lyon-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS)
[Departement_IRSTEA]Eaux | International audience | In this report, we describe a new immunosensor designed for the detection and the quantification of Pseudomonas aeruginosa bacteria in water. The developed biosensing system was based on the immobilization of purified polyclonal anti P. aeruginosa antibodies on electropolymerized poly(pyrrole-3-carboxylic acid)/glassy carbon electrode. The building of the immunosensor step by step was evaluated by electrochemical measurements such as cyclic voltammetry (CV) and impedance spectroscopy (EIS). The electrochemical signature of the immunosensor was established by the change of the charge transfer resistance when the bacteria suspended in solution became attached to the immobilized antibodies. As a result, stable and high sensitive impedimetric immunosensor was obtained with a sensitivity of 0.19 k Omega/decade defined in the linear range from 10(1) to 10(7) CFU/mL of cellular concentrations. A low detection limit was obtained for the P. aeruginosa bacteria and a high selectivity when other bacteria were occasioned as well as Escherichia coli. The developed immunosensor was applied in detecting pathogenic P. aeruginosa in well-water.
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