In the present work, abundance, spatial distribution and qualitative composition, of benthic marine litter, were investigated in five study areas from the Eastern Mediterranean and Black Seas (Saronikos, Patras and Echinades Gulfs; Limassol Gulf; Constanta Bay). Surveys were performed using the monitoring protocol proposed by the Technical Group for Marine Litter. Densities ranged from 24 items/km(2) to 1211 items/km(2), with the Saronikos Gulf being the most affected area. Plastics were predominant in all study areas ranging from 45.2% to 95%. Metals and Glass/Ceramics reached maximum values of 21.9% and of 22.4%. The size distribution of litter items showed that >= 50% fall into medium size categories (10 x 10 cm, 20 x 20 cm) along with an elevated percentage of small-sized (<5 x 5 cm) plastic litter items. The comparative analysis of the data highlighted the dependence of the marine litter problem on many local factors (human sources and oceanographic conditions) and the urgent need for specific actions.

The annual variation in neustonic plastic particles and zooplankton was studied in the Bay of Calvi (Corsica) between 30 August 2011 and 7 August 2012. Plastic particles were classified into three size classes, small microplastics (0.2–2 mm), large microplastics (2–5 mm) and mesoplastics (5–10 mm). 74% of the 38 samples contained plastic particles of varying composition: e.g. filaments, polystyrene, thin plastic films. An average concentration of 6.2 particles/100 m2 was observed. The highest abundance values (69 particles/100 m2) observed occurred during periods of low offshore wind conditions. These values rose in the same order of magnitude as in previous studies in the North Western Mediterranean. The relationships between the abundance values of the size classes between zooplankton and plastic particles were then examined. The ratio for the intermediate size class (2–5 mm) reached 2.73. This would suggest a potential confusion for predators regarding planktonic prey of this size class.

PCB levels in plankton were investigated in the Bay of Marseille, Western Mediterranean Sea, between September 2010 and October 2011. Concentrations of PCB congeners (CB 18, CB 52, CB 101, CB 118, CB 138, CB 153, CB 180) were determined in three plankton size-classes (60–200, 200–500 and 500–1000 μm) together with different parameters: chlorophyll content, plankton dry-weight biomass, carbon and nitrogen stable isotope ratios and plankton-community structure. The ∑PCB7 concentrations ranged between 14.2 and 88.1 ng g−1 d.w., for all size classes and all sampling periods. The results do not show the biomass dilution effect and indicate moderate but significant biomagnification with plankton trophic position estimated by δ15N signatures. Equilibrium with water phase may notably contribute in controlling the PCB levels in the plankton. More generally, presented results imply that PCB accumulation in the plankton is an effect of abiotic and trophic complex interactions in the Bay of Marseille.

Life Cycle Assessment (LCA) has been introduced in the evaluation of chemical processes and or products in order to take into account the Supply Chain and its environmental constraints and burdens. Regarding to the environmental assessment of chemical processes and/or products two main variables need to be taken into account: Natural Resources Sustainability (NRS) and Environmental Burdens Sustainability (EBS). NRS includes the use of energy, water and materials whereas EBS is given by the environmental sustainability metrics developed by the Institution of Chemical Engineers (IChemE). The main components of EBS have been classified in 5 environmental impacts to the atmosphere (acidification, global warming, human health effects, stratospheric ozone depletion and photochemical ozone formation), 5 aquatic media impacts (aquatic acidification, aquatic oxygen demand, ecotoxicity (metals), ecotoxicity (others) and eutrophication) and 2 land impacts (hazardous and non-hazardous waste disposal). To reduce the number of variables and thus, the complexity, the development of a normalisation and weighting procedure is required. This work proposes the normalization of EB based on the threshold values of the European Pollutant Release and Transfer Register (E-PRTR) and a similar procedure based on the values given by the BREF document on waste incineration for the NRS normalisation. This procedure will help in the decision making process in the waste management field and in the particular, in Municipal Solid Waste Incineration (MSWI).

The aim of this work is to develop an integrated process for the sustainable management of reverse osmosis brines generated in desalination plants. The core of the proposed process is the bipolar membrane electrodialysis (BMED), which has proved to be a technically feasible option for the conversion of RO desalination brines into HCl and NaOH. However, the overall process should also integrate the brine purification treatment. Precipitation with NaOH, using the reactant produced in BMED, would be the most suitable option for hardness removal. On the other hand, the presence of sulphate affects negatively the quality of the hydrochloric acid product and the current efficiency of BMED. Therefore, in this work nanofiltration (NF) has been applied in order to retain sulphate. This work reports the mathematical model that describes the transport of binary aqueous solutions of chloride and sulphate anions through the NF270 nanofiltration membrane. The relevance and the difficulty of the task lie on the high concentrations of both anions, as it occurs in the RO brines generated in the desalination of brackish water, and the variety of valence charge of the species, monovalent chloride and divalent sulphate, that introduces significant differences in the interaction of both anions with the charged membrane surface. | This work has been financially supported by projects CTQ2008-0690, ENE2010-15585 and CTM2011-23912 (co-financed by ERDF Funds).

Sugarcane is a major crop in Brazil that generates huge amounts of organic residues that are usually left deposited in, or applied to the soil, and thereby affect the behavior of herbicides. This study assessed the effects of sugarcane residues (straw, ash, and compost) and residence time (“aging”) on the sorption of alachlor and diuron in two contrasting soils (LVd and LVAd), as well as the effects of these residues on the leaching of alachlor. Adding straw and compost had no effect, whereas adding ash significantly increased sorption of both herbicides. Aging (28 days) increased apparent sorption distribution coefficients (Kd,ₐₚₚvalues) by 1.2 to 2.3 times. Straw and ash amendments resulted in less leaching of alachlor (<1.0 % of the applied amount) than compost or control soil (~6 % of the applied amount). The straw retained ~80 % of the applied alachlor during leaching. Although this may be overrated due to an artifact of the methodology adopted, alachlor retention in the straw could not be predicted by the use of Kd,ₐₚₚ. The transport potential of alachlor may be overestimated if aging and sugarcane straw management are not factored into the models.

In a study on the behaviour of pesticides in a soil–plant–water system, the quick, easy, cheap, effective, rugged and safe (QuEChERS) method for analysing pesticide or metabolite residues in soil and maize (leaves, roots and kernels) was optimized and validated. The pesticides bentazone, chloridazon and terbuthylazine and their metabolites bentazone-methyl, chloridazon-desphenyl, chloridazon-methyl-desphenyl, terbuthylazine-desethyl and terbuthylazine-2-hydroxy were selected in this study. The QuEChERS extracts obtained from soil and maize matrices and the collected leachate were analysed by liquid chromatography–electrospray ionization–tandem mass spectrometry (LC–ESI–MS/MS) using a high-performance liquid chromatography and an ultra-high-performance liquid chromatography (UHPLC) analytical column. As expected, shorter run times and higher sensitivity were achieved with the UHPLC column. Validation studies focused on recovery, repeatability, matrix effects, limits of detection and quantification. Recoveries (and repeatability relative standard deviation (RSD)) of the spiked samples were in the range of 55 to 98 % (7.4–18) in soil, 23 to 101 % (1.7–20) in maize and 82 to 105 % (4.4–25) in leachate. Quantification limits were lower than 3.0 μg kg⁻¹ in soil, 7.3 μg kg⁻¹ in maize and 0.080 μg l⁻¹ in leachate.