Atmospheric wet deposition of base cations (BCs) plays a significant role in providing plant nutrients and buffering acidification. However, the temporal dynamic of wet BC deposition in China during the past two decades remain unclear. Here, we used long-term monitoring and literature data since 2000 to assess the temporal dynamics (seasonal and inter-annual variation), spatial patterns, main influencing factors, source apportionment, and capacity to neutralize the acidity of wet BC depositions at site, regional, and national scales. The results showed that total wet deposition of BCs was, on average, 2.12 keq ha⁻¹ yr⁻¹, where Ca²⁺ accounted for 65.57% of the total deposition, followed by Na⁺ (13.21%), Mg²⁺ (13.68%), and K⁺ (7.55%). Qinghai-Tibet had significantly lower BC deposition fluxes than northern, southern, and central China, as well as Inner Mongolia. Exchangeable BCs in soil, PM₁₀ in the atmosphere, energy consumption, and cement production are significantly related to wet BC deposition, which account for 79.17% of the variation in the spatial deposition of BC. Influenced by the strategies to control acid rain and particulate matter in China, interannual variations showed a stabilization trend after a continuous decline from 2000 to 2017, which can be explained by inter-annual changes in PM₁₀, energy consumption and cement production. Statistical methods confirmed that 45.95% of wet BC deposition was derived from crustal contributions, 27.78% from sea salt sources, and 26.27% from anthropogenic sources. Furthermore, we found that wet deposition of BCs neutralized 84.85% of the acidity due to NO₃⁻ and SO₄²⁻ depositions. Under the emissions reduction strategy, there has been a decrease in the deposition of BC. However, SO₄²⁻ and NO₃⁻ depositions decreased faster than BC deposition, which buffered a higher proportion of acidic depositions. Our findings contribute to an improved understanding of wet BC deposition in China, an evaluation of their capacity to neutralize acidity, and important parameters for acidification models.

Food products are inevitably contaminated by flame retardants throughout their lifecycle (i.e., during production, use, and disposal). In order to evaluate the dietary intake of legacy and emerging halogenated flame retardants (HFRs) in typical market food in China, we investigate the distribution and profile of 27 legacy polybrominated diphenyl ethers (PBDEs) and 16 emerging HFRs (EHFRs) in 9 food categories (meat, poultry, aquatic food, eggs, dairy products, cereals, vegetables, nuts and fruits, and sugar). A total of 105 food samples collected from three markets in Nanjing, eastern China were included for evaluation. The highest concentrations of PBDEs and EHFRs were found in aquatic foods (means of 0.834 ng/g wet weight (ww) and 0.348 ng/g ww, respectively), and the lowest concentrations were found in sugar (means of 0.020 ng/g ww for PBDEs and 0.014 ng/g ww for EHFRs). 2,2′,4-tribromodiphenyl ether (BDE-17), a legacy HFR, and hexabromobenzene (HBBz), an EHFR, were the predominant pollutants in the investigated food samples. Concentrations of HBBz and 2,3-dibromopropyl tribromophenyl ether (DPTE) were comparable to those of some PBDEs in certain food samples. The concentrations of the total EHFRs and total PBDEs found in animal-based food samples were significantly greater than those in plant-based food samples. Comparison of the estimated total dietary intake of HFRs and their corresponding non-cancer reference dose (United States Environmental Protection Agency) suggests a low overall health risk. To the best of our knowledge, the present study is the first to simultaneously determine 27 PBDEs and 16 EHFRs in representative foods from Chinese markets. BDE-17, HBBz, and DPTE were the predominant congeners among the 43 investigated HFRs and meat and aquatic foods were the primary sources of PBDEs and EHFRs to the total local dietary intake.

The ammonium sulphate ((NH₄)₂SO₄) in-situ leaching process is the most widely used extraction technology for weathered crust elution-deposited rare earth ores (WCED-REOs). Highly concentrated (NH₄)₂SO₄, a representative leaching agent, is often used in the leaching process of WCED-REOs. However, this in-situ leaching process causes nitrogen pollution in the soil, surrounding surface and ground water due to the high concentrations of (NH₄)₂SO₄ solutions used as a long term leaching agent. To date, the mechanism behind the variations in ammonia nitrogen (AN) in deep soil profiles is unclear. We conducted vertical and lateral soil sampling and analyzed the collected samples for soil moisture, pH, ammonia forms, and AN contents in soil profiles deeper than 500 cm in an in-situ leaching mining area of Ganzhou, Jiangxi Province, southern China. The results show that primary chemical pollutants in the soil are derived from residual leaching agents with high acidities and concentrations of AN. Twelve years after the mining process was completed, the mean pH values of the tailings in the mining area were 3.90 and 4.87 in its lower reaches. Due to the presence of chemical residues, the AN concentration was 12–40 times higher than that of the raw ore soil before it was mined. The percentages of different ammonium forms in the rare earth tailing soil were 65%, 30%, and 5% for the water-soluble, exchangeable, and fixed ammonium forms, respectively. The results of this study support effective prevention and remediation treatment of environmental problems caused by AN pollution of the soil in WCED-REOs.

Methylmercury (MeHg) is a neurotoxic compound that is found in virtually all fish and biomagnifies in aquatic food webs. Although MeHg concentrations in marine and estuarine fish are often elevated, the impacts of MeHg on marine and estuarine fish have largely been understudied. To evaluate the impact of dietary MeHg on marine fish reproduction and effects on their offspring, female juvenile sheepshead minnows (Cyprinodon variegatus) at three months of age were experimentally exposed to MeHg-contaminated diets for two months and then paired with Hg-free males for spawning. Egg production, hatching success of embryos, time to hatching, survival of larvae, growth of larvae and swimming behavior of larvae were determined. Selenium (Se) was also measured and Se/Hg molar ratios were calculated to assess whether Se reduced MeHg toxicity. MeHg had no significant impact on fish reproduction or on survival and growth of larvae. Larvae produced by MeHg-exposed mothers had concentrations of Hg about 1 ppm (dry wt), or about 12% of that in the muscle of their mothers and consistently displayed 6–15% increased swimming speed relative to controls; the ecological significance of this moderate effect on swimming speed requires further study. The Se/Hg molar ratios in these fish, which were >1 in controls (adults and larvae) and MeHg-exposed larvae but <1 in Hg-exposed adults, did not correlate with MeHg effects. The sheepshead minnow, at a low trophic level, appears to have a high tolerance of MeHg; however, it can pass MeHg to higher trophic levels in marine ecosystems where upper level predators have MeHg concentrations sometimes exceeding US FDA safety limits of 1 ppm wet wt.

The Kızılırmak Delta is one of the most important agricultural production regions and it was included as part of the Ramsar Convention in 1998. The water used in agricultural irrigation is mostly supplied from drainage channels. In the present study, 120 water samples were collected from drainage channels and analyzed to characterize the groundwater chemistry and microbiological contamination. Sea water interface, discharge of sewage, wastewater from agricultural activities and livestock and uncontrolled solid waste landfills were identified as the most important pollutant sources in the delta. Serious microbiological pollution was detected in channel water samples. These results indicate that sewage waters mix with the channel waters in the delta. Also, the correlations of parameters such as EC, TDS, DO, Cl⁻ and SO₄²⁻ indicate that channel waters contain high dissolved minerals. It was concluded that especially agricultural pollution and waste water affects water resources negatively in the region.

In parts of developing countries, the over-exploitation of sands from inland waters has led to serious environmental concerns. However, understanding of the impacts of commercial sand dredging on inland water ecosystem functions remains limited. Herein, we assess the effects of this activity on the functional structure of the macroinvertebrate community and its recovery processes based on a 4-year survey, in the South Dongting Lake in China. Our result showed a simplified macroinvertebrate functional structures within the dredged area, as evidenced by a loss of certain trait categories (e.g., oval and conical body form) and a significant reduction in trait values due to the direct removal of macroinvertebrates and indirect alternations to physical environmental conditions (e.g., water depth and %Medium sand). Moreover, clear increases were observed in certain trait categories (e.g., small body size and swimmer) resulting from the dredging-related disturbance (e.g., increased turbidity) within the adjacent area. Furthermore, one year after the cessation of dredging, a marked recovery in the taxonomic and functional structure of macroinvertebrate assemblages was observed with most lost trait categories returning and an increase in the trait values of eight categories (e.g., body size 1.00–3.00 cm and oval body form) within the dredged and adjacent area. In addition, dispersal processes and sediment composition were the main driver for the structuring of the macroinvertebrate taxonomic and functional assemblages during the dredging stages, whilst water environmental conditions dominated the taxonomic structure and dispersal processes determined the functional structure during the recovery stage. Implications of our results for monitoring and management of this activity in inland waters are discussed.

Microplastic pollution has become an emergency issue in the global environment. However, little is known about the occurrence and distribution of microplastics in agroecological system. In this study, we investigated the pollution of microplastics in vegetable farmlands in suburb of Wuhan, central China. Results showed that the abundance of microplastics ranged from 320 to 12,560 items/kgdw. Microplastic pollution adjacent to the suburban roads was about 1.8 times as serious as that in the residential areas. Microplastics with size less than 0.2 mm were dominated, reaching 70% in total. The main types of microplastics were fibers and microbeads. Moreover, polyamide (32.5%) and polypropylene (28.8%) were the main types of polymer. This study proclaims the occurrence and characteristics of microplastic pollution in typical farmland soils of suburb land. It may provide significant basis for subsequent research about microplastics contaminant in the terrestrial ecosystem.

Perfluoroalkyl substances (PFASs) are a class of organohalogenated compounds of environmental concern due to similar characteristics as the well-studied legacy persistent organic pollutants (POPs) that typically show environmental persistence, biomagnification and toxicity. Nevertheless, PFAS are still poorly regulated internationally and in many aspects poorly understood. Here, we studied liver and muscle concentrations in five cetacean species stranded at the southeastern coast of Spain during 2009–2018. Twelve of the fifteen targeted compounds were detected in >50% of the liver samples. Hepatic concentrations were significantly higher than those in muscle reflecting the particular toxicokinetics of these compounds. Bottlenose dolphins Tursiops truncatus showed the highest hepatic ΣPFAS (n = 5; 796.8 ± 709.0 ng g⁻¹ ww) concentrations, followed by striped dolphin Stenella coeruleoalba (n = 29; 259.5 ± 136.2 ng g⁻¹ ww), sperm whale Physeter macrocephalus (n = 1; 252.8 ng g⁻¹ ww), short-beaked common dolphin Delphinus delphis (n = 2; 240.3 ± 218.6 ng g⁻¹ ww) and Risso’s dolphin Grampus griseus (n = 1; 78.7 ng g⁻¹ ww). These interspecies differences could be partially explained by habitat preferences, although they could generally not be related to trophic position or food chain proxied by stable N (δ¹⁵N) and C (δ¹³C) isotope values, respectively. PFAS profiles in all species showed a similar pattern of concentration prevalence in the order PFOS>PFOSA>PFNA≈PFFUnA>PFDA. The higher number of samples available for striped dolphin allowed for evaluating their PFAS burden and profile in relation to the stranding year, stable isotope values, and biological variables including sex and length. However, we could only find links between δ¹⁵N and PFAS burdens in muscle tissue, and between stranding year and PFAS profile composition. Despite reductions in the manufacturing industry, these compounds still appear in high concentrations compared to more than two decades ago in the Mediterranean Sea and PFOS remains the dominating compound.

Using mineral admixtures in cement composites as a way to improve their mechanical and sustainable environmental properties is a common practice in concrete technology. Among them nano-silica effectively influences the composite's early and long-term properties. In this study, the effect of different percentages of TiO2 (0, 2.5 and 5 %) on self-cleaning properties and water absorption of cement composites containing nano-silica were investigated. according to the use of different cementitious material (nano-silica) and TiO2 in mix proportions, to obtain mixtures with a desirable workability, superplasticizer was added in different volume percentages.Better size distribution and pore refinement lead to a denser cement matrix with low porosity which in turn considerably lower the water absorption of the cement composites. the maximum final water absorption according to ASTM C497 is 9% for method A and 8.5% for method B. Comparsions of water absorption tests as a result of adding of TiO2 and nano-silica in concrete show that the maximum final water absorption is 4.9% in N1 design mixture and the minimum final water absorption is 4.3% in N2 design mixture.The incorporation of TiO2 has positively affected the results for nano-silica containing specimens. A decrease of 6.5% and 11.1% between N1 and N3 respectively shows the positive effect of TiO2 on decrease of water absorption. The results show that TiO2 along with nanosilica has great potential for improving the environmental and self- cleaning properties of concrete facades of buildings in cities exposed to high levels of cleanliness.

The purpose of the research is to identify the types of environmental pollution crimes in Iran. This research is a theoretical type that has been done by survey and analysis and has been done in 3 stages. Initially, an initial list of environmental crimes was used by a semi-structured interview method. Sampling was determined by the targeted method and the sample size was 169 people. All interviews were implemented and coded as text. In the next step, using expert opinions and the method of pairwise comparison, environmental crimes of weighting and their importance coefficient were determined. Then, by inquiring from the legal offices of the relevant organizations, the statistics of violations and environmental crimes by the provinces of the country between the years 2017 to 2019 were obtained. The results showed that the main crimes of environmental pollution in Iran can be divided into 8 main categories. Also, 23 criteria were determined for them. Among the eight crimes of environmental pollution, the highest weight belonged to air pollution (0.876) and then water pollution (0.797). Also; the lowest weight was allocated to wave pollution (0.114). A comparative comparison between environmental pollution crimes showed that between 2017 and 2019, statistically, the highest rate of crime was related to waste pollution and then water pollution. Mazandaran province with 6674 cases of environmental crimes in the top provinces of the country and Khorasan Razavi province was introduced as the last province with 223 cases of environmental crimes.