Total and extractable concentrations of Cu, Pb, and Zn were determined in surface sediments of west Chaohu Lake (China) by HCl-HNO₃-HF-HClO₄digestion and an optimized BCR sequential extraction procedure, respectively. The metal pollution was evaluated by the enrichment factor approach, and the potential eco-risk was evaluated by the sediment quality guideline (SQG) and risk assessment code (RAC) assessments. The results indicated that both total and extractable metal concentrations were highly variable and were affected by sediment properties, even though the sediments were predominantly composed of <63-μm particles (>89 %). Enrichment factors of the metals based on the total and extractable concentrations all showed higher values in the northern lake area and decreasing values towards the south. This distribution indicated an input of anthropogenic metals via the Nanfei River. Anthropogenic Cu, Pb, and Zn in surface sediments showed comparable values for each metal based on the total and extractable concentrations, suggesting that anthropogenic Cu, Pb, and Zn resided predominantly in the extractable fractions. Sediment Cu had low eco-risk, and Pb and Zn had medium eco-risk by the SQG assessment, whereas the eco-risk rankings of Cu, Pb, and Zn were medium, low, and low–high, respectively, by the RAC assessment. Referencing to the labile (dilute acid soluble) metal concentrations, we deduced that the eco-risk of Cu may be largely overestimated by the RAC assessment, and the eco-risk of Pb may be largely overestimated by the SQG assessment. Overall, sediments Cu and Pb may pose low eco-risk, and Zn may pose low–high eco-risk.

Copper contamination is increasing in many aquatic ecosystems. One mode by which copper can be introduced into aquatic ecosystems is as an algaecide, such as Cutrine-Plus®. Using a mesocosm experiment, we examined the effects of Cutrine-Plus® on wood frog (Lithobates sylvaticus) tadpoles. In addition, we examined how the presence of a nonnative predator the Western mosquitofish (Gambusia affinis) may interact with exposure to Cutrine-Plus®. Exposure to our low and high Cutrine-Plus® treatments had a strong negative effect on the wood frog tadpoles, and survivorship was greatly decreased in the low treatment, and no tadpoles survived in the high treatment. Additionally, the tadpoles that survived the low treatment were significantly smaller than those in the control treatment. Mosquitofish had no effect on the survivorship or growth of wood frog tadpoles, and mosquitofish presence did not have a significant interaction with the Cutrine-Plus® treatments. Cutrine-Plus® clearly had a negative effect on wood frog tadpoles at the concentrations used in our experiment, which were at and below the label-recommended dosages, suggesting that the use of Cutrine-Plus® in natural ponds may have negative consequences for wood frog populations and possibly other amphibians.

Substance flow analysis (SFA) is applied to a case study of chlorine metabolism in a chlor-alkali industrial chain. A chain-level SFA model is constructed, and eight indices are proposed to analyze and evaluate the metabolic status of elemental chlorine. The primary objectives of this study are to identify low-efficiency links in production processes and to find ways to improve the operational performance of the industrial chain. Five-year in-depth data collection and analysis revealed that system production efficiency and source efficiency continued increasing since 2008, i.e., when the chain was first formed, at average annual growth rates of 21.01 % and 1.01 %, respectively. In 2011, 64.15 % of the total chlorine input was transformed into final products. That is, as high as 98.50 % of the chlorine inputs were utilized when other by-products were counted. Chlorine loss occurred mostly in the form of chloride ions in wastewater, and the system loss rate was 0.54 %. The metabolic efficiency of chlorine in this case was high, and the chain system had minimal impact on the environment. However, from the perspectives of processing depth and economic output, the case study of a chlor-alkali industrial chain still requires expansion.

We discuss the accuracy and performance of the adaptive neuro-fuzzy inference system (ANFIS) in training and prediction of dissolved oxygen (DO) concentrations. The model was used to analyze historical data generated through continuous monitoring of water quality parameters at several stations on the Johor River to predict DO concentrations. Four water quality parameters were selected for ANFIS modeling, including temperature, pH, nitrate (NO₃) concentration, and ammoniacal nitrogen concentration (NH₃-NL). Sensitivity analysis was performed to evaluate the effects of the input parameters. The inputs with the greatest effect were those related to oxygen content (NO₃) or oxygen demand (NH₃-NL). Temperature was the parameter with the least effect, whereas pH provided the lowest contribution to the proposed model. To evaluate the performance of the model, three statistical indices were used: the coefficient of determination (R ²), the mean absolute prediction error, and the correlation coefficient. The performance of the ANFIS model was compared with an artificial neural network model. The ANFIS model was capable of providing greater accuracy, particularly in the case of extreme events.

The phenomenon of coagulation settling in liquid suspensions has a variety of applications, including mineral processing, treatment of industrial effluents, and municipal sewage sludge purification. This study was to investigate the coagulation settling characteristics of fine-grind natural zeolite and evaluate the removal efficiency of contaminants simultaneously in static and turbulent flow. A series of column experiments were conducted to pattern the characteristics of spatial and temporal variation of coagulation settling and removal contaminants in static and turbulent flow. The results indicated that the suspended solid concentration presented an apparent exponential decay with coagulation settling time in static flow (R ² > 0.99), coagulation settling rate of the fine zeolite-suspended solid in static flow was between 0.005 and 0.05 cm/s obtained from the repeat depth suction method. The relation between average C/C ₀ of pollutants and suspended solid concentration was exponential before the settlement for 24 h and that was the line after the settlement for 24 h. Several various models were presented to highlight the coagulation settling characteristics of fine-grind natural zeolite in static and turbulent flow. Compared to hydrostatic settling experiments, zeolite-suspended solid presented better removal efficiency of pollutants and greater removal rate of pollutants in turbulent flow.

Individuals’ exposure to various persistent organic pollutants (POPs), including polychlorinated biphenyls (PCBs), and its adverse health effects have been a cause of concern. We measured blood PCB concentrations from samples taken from 507 Japanese individuals ranging from infants to those over 80 years of age. The blood PCB levels increased with age for both male (Spearman’s r = 0.69, p < 0.001) and female (Spearman’s r = 0.70, p < 0.001) participants. Adult men and nulliparous women showed similar increases with age. However, the PCB levels of multiparous women were lower than those of nulliparous women in their thirties (p = 0.005), probably because the PCBs were transferred from the mothers to their children during pregnancy and lactation. Among infants (<2 years of age), some had as high levels of accumulated PCB levels as those in adults >30 years of age. In some cases, the PCB levels were over 0.8 ng/g wet weight, similar to levels observed in adults over 50 years of age. In the future, it will be necessary to do research on the health of the children who are exposed by high concentration level of POPs.

The influents of plants treating complex industrial wastewaters from third parties may contain a large variety of often unknown or unidentified potentially harmful substances. The conventional approach of assessing and regulating the effluents of these plants is to set emission limit values for a limited set of physicochemical parameters, such as heavy metals, biological oxygen demand, chemical oxygen demand and adsorbable organic halogen compounds. The objective of this study was to evaluate the relevance of physicochemical parameters for setting emission limit values for such plants based on a comparison of effluent analyses by physicochemical and biological assessment tools. The results show that physicochemical parameters alone are not sufficient to evaluate the effectiveness of the water treatment plants for removing hazardous compounds and to protect the environment. The introduction of toxicity limits and limits for the total bioaccumulation potential should be considered to supplement generic parameters such as chemical oxygen demand and adsorbable organic halogens. A recommendation is made to include toxicity screening as a technique to consider in the determination of best available techniques (BAT) during the upcoming revision of the BAT reference document for the waste treatment industries to provide a more rational basis in decisions on additional treatment steps.

A novel photocatalytic reactor for wastewater treatment was designed and constructed. The main part of the reactor was an aluminum tube in which 12 stainless steel circular baffles and four quartz tube were placed inside of the reactor like shell and tube heat exchangers. Four UV–C lamps were housed within the space of the quartz tubes. Surface of the baffles was coated with TiO₂. A simple method was employed for TiO₂ immobilization, while the characterization of the supported photocatalyst was based on the results obtained through performing some common analytical methods such as X-ray diffraction (XRD), scanning electron microscope (SEM), and BET. Phenol was selected as a model pollutant. A solution of a known initial concentration (20, 60, and 100 ppmv) was introduced to the reactor. The reactor also has a recycle flow to make turbulent flow inside of the reactor. The selected recycle flow rate was 7 × 10⁻⁵ m³.s⁻¹, while the flow rate of feed was 2.53 × 10⁻⁷, 7.56 × 10⁻⁷, and 1.26 × 10⁻⁶ m³.s⁻¹, respectively. To evaluate performance of the reactor, response surface methodology was employed. A four-factor three-level Box–Behnken design was developed to evaluate the reactor performance for degradation of phenol. Effects of phenol inlet concentration (20–100 ppmv), pH (3–9), liquid flow rate (2.53 × 10⁻⁷−1.26 × 10⁻⁶ m³.s⁻¹), and TiO₂ loading (8.8–17.6 g.m⁻²) were analyzed with this method. The adjusted R ² value (0.9936) was in close agreement with that of corresponding R ² value (0.9961). The maximum predicted degradation of phenol was 75.50 % at the optimum processing conditions (initial phenol concentration of 20 ppmv, pH ∼ 6.41, and flow rate of 2.53 × 10⁻⁷ m³.s⁻¹ and catalyst loading of 17.6 g.m⁻²). Experimental degradation of phenol determined at the optimum conditions was 73.7 %. XRD patterns and SEM images at the optimum conditions revealed that crystal size is approximately 25 nm and TiO₂ nanoparticles with visible agglomerates distribute densely and uniformly over the surface of stainless steel substrate. BET specific surface area of immobilized TiO₂ was 47.2 and 45.8 m² g⁻¹ before and after the experiments, respectively. Reduction in TOC content, after steady state condition, showed that maximum phenol decomposition occurred at neutral condition (pH ∼ 6).

Agricultural products/by-products are natural sorbent materials that possess capacity for removing contaminants including heavy metals from wastewaters and hence can be exploited as replacement of costly methods for wastewater treatment. The sorption of heavy metals onto these biomaterials is attributed to constituent's proteins, carbohydrates, and phenolic compounds that contain functional groups such as carboxylate, hydroxyl, and amine. Natural efficiency of these materials for removing heavy metals can be enhanced by treating them with chemicals. The present review emphasizes their use in developing eco-friendly technology for a large-scale treatment of wastewater.

We determined the length, volume, dry biomass, and density in seeds of five castor bean cultivars and verified notable physicochemical trait differences. Seeds were then subjected to different toxic aluminum (Al) concentrations to evaluate germination, relative root elongation, and the role of root apices’ rhizosphere mucilage layer. Seeds’ physicochemical traits were associated with Al toxicity responses, and the absence of Al in cotyledons near to the embryo was revealed by Al-hematoxylin staining, indicating that Al did not induce significant germination reduction rates between cultivars. However, in the more sensitive cultivar, Al was found around the embryo, contributing to subsequent growth inhibition. After this, to investigate the role of mucilage in Al tolerance, an assay was conducted using NH₄Cl to remove root mucilage before or after exposure to different Al concentrations. Sequentially, the roots were stained with hematoxylin and a quantitative analysis of staining intensity was obtained. These results revealed the significant contribution of the mucilage layer to Al toxicity responses in castor bean seedlings. Root growth elongation under Al toxicity confirmed the role of the mucilage layer, which jointly indicated the differential Al tolerance between cultivars and an efficient Al-exclusion mechanism in the tolerant cultivar.