Nitrogen isotope ratios (δ15N) in juvenile winter flounder, Pseudopleuronectes americanus, were used to examine changes in nitrogen inputs to several Rhode Island, USA estuarine systems. Fish were collected over two three-year periods with a ten-year interval between sampling periods (2002–2004 and 2012–2014). During that interval numerous changes to nutrient management practices were initiated in the watersheds of these estuarine systems including the upgrade of several major wastewater treatment facilities that discharge to Narragansett Bay, which significantly reduced nitrogen inputs. Following these reductions, the δ15N values of flounder in several of the systems decreased as expected; however, isotope ratios in fish from upper Narragansett Bay significantly increased. We believe that low δ15N values measured in 2002–2004 were related to concentration-dependent fractionation at this location. Increased δ15N values measured between 2012 and 2014 may indicate reduced fractionation or that changes in wastewater treatment processes altered the nitrogen isotopic ratios of the effluents.

The main goal of this study was to determine the concentrations of trace elements in the mineralogically contrasting shells of two Arctic bivalves: Chlamys islandica and Ciliatocardium ciliatum. Aragonite shells seem to be more susceptible to the binding of metal ions, which is most likely a result of their crystal lattice structure. We suggest that less biologically controlled aragonite mineralization tends to incorporate more metal impurities into the crystal lattice in waters with a lower pH, where metal ions are more available. Higher concentrations of impurities may further increase the lattice distortion causing lower crystal lattice stability and higher susceptibility to dissolution. Calcitic shells seem to be less prone to bind metal ions than aragonite shells most likely because under strict biological control, the uptake of ions from ambient seawater is more selective; thus, the final crystal lattice is less contaminated by other metals and is more resistant to dissolution.

Brominated flame retardants (BFRs) are chemicals that are now omnipresent in the environment and have been detected in different matrices from different parts of the world.They are semivolatile organic compounds (SVOCs), hence they partition between air, water, soil and sediment. Atmospheric long range transport (LRT) is commonly considered the swiftest route for SVOCs to reach remote environments. As a results, the Stockholm Convention on Persistent Organic Pollutants (POPs) advocates air monitoring as a key measure to assess the effectiveness of global control initiatives. There is little information of atmospheric BFR levels in the African continent, which makes it impossible to understand the regional as well as global perspective of these pollutants in the atmosphere. The aim of this review is therefore to establish scientific reasons to explain why it is necessary to have atmospheric research in Africa, and provide research gaps that need to be considered in further studies in order to better understand these pollutants in the atmosphere.To date there are about 57 published studies on BFRs in different matrices in various countries of the African continent, out of which, only three have concentrated on the atmosphere. The amounts are not as high as detected in other regions but are likely to increase due to the fact that the continent is developing at a fast rate thus an anticipated increase in BFRs use. The review therefore provides different recommendations which all clearly develop a foundation of the necessity of air monitoring of BFRs in the African continent.

Native mussels Mytilus galloprovincialis are used as bioindicator organisms to assess the concentration levels and toxic effects of persistent chemicals, polychlorobiphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), and heavy metals using biomarker responses, such as catalase (CAT), glutathione s-transferase (GST), and condition indices, for the Algerian coast. The results show that mussels of Oran Harbour are extremely polluted by PCBs and PAHs, i.e., 97.6 and 2892.1μg/kg d.w., respectively. Other sites present low levels of pollution. Furthermore, high concentrations of zinc, lead and cadmium are found in mussels from fishing, agricultural and estuarine sites, respectively, while low concentrations of copper are found in all of the sites studied. CAT activity is negatively correlated with Cd and Cu, and Zn is positively correlated with GST and CAT. Site classification tools reveal the potential toxicity of coastal areas exposed to anthropogenic pressure and a gradient of toxicity along the Algerian west coast.

Nanoparticle emission from gasoline driven vehicles is reported to be significantly lower compared to diesel vehicles. Accordingly, there is no threshold limit implemented by the regulatory authorities in India for gasoline driven vehicles. Recent studies however indicate that this is true as far as the mass concentration of the nanoparticles is concerned. The number concentration of nanoparticles particularly of smaller dimensions is reported to be significantly higher for gasoline driven vehicles under certain operating range of speed and load. Smaller the dimension of the particles more are their residence time in environment and more susceptible are these particles to be inhaled by human respiratory and cardiovascular system. Thus an estimate of the size distribution of nano-sized particulate matter emission from gasoline driven vehicle is of immense importance in context to Indian urban population. In this direction, laboratory measurements are reported for the nanoparticle size distribution emitted from a gasoline engine under different loading conditions. On-field measurements are carried out in the wake of a stationary vehicle under idling and throttling condition. Simultaneous measurement of vehicular acceleration and deceleration is also reported along with nanoparticle distribution in the wake of a moving vehicle. The measurements reported in this paper reveal the need for deciding threshold value of number concentration to be implemented for gasoline vehicles by the Indian regulatory authorities.

Our previous study in 2011 reported the detection of BPA and PFAAs in 20 species of marine and freshwater fishes. With an emerging evidence to suggest the metabolic-disrupting effects of BPA/PFAAs in animals, the present study was aimed to provide a time-trend analysis to determine the current concentrations of PFAAs and BPA in 20 commercially available Hong Kong species of fishes. Since the manufacture and use of BPA is being prohibited in most nations, the introduction of BPA alternatives has recently been incorporated in the markets. Therefore, the concentrations of BPB, BPF and BPS were determined. In the present study, all freshwater and seawater fish samples showed quantified concentrations [>Limit of Quantification (LOQ<0.5ng/g)] of BPA. BPF was detected in some marine (yellow seafin, bigeye, goldspotted rabbitfish, snubnose pompano, tongue sole, Bleeker's grouper and orange-spotted grouper) and freshwater fishes (mud carp, crucian carp, tilapia, catfish, mandarin fish, grass carp, grey mullet and spotted snakehead). Two of the compounds, BPS and BPB could only be identified in the marine fishes (snubnose pompano, yellow seafin). In PFAA analysis, PFOA, PFDA, PFOS, PFUdA and PFDoA were found in most of the marine and freshwater fishes. PFOS and PFOA were shown to be the two predominant PFAAs in fishes. On the basis of the measured concentrations of bisphenols, BPs (BPA, BPB, BPF, BPS) and PFAAs, the average daily intake for BPs (20.5–31.5ng/kgb.w./day) and PFAAs (1.17–1.83ng/kgb.w./day) were calculated and found to be lower than values of tolerable daily intake (TDI) established in Europe. However, as compared with our previous study in 2011, the present study revealed an approximate 10-fold increase in the concentrations of BPA in the fish samples. Although the hazard ratio of consuming fishes for BPA and PFAA exposure is expected to remain low, possible additive metabolic-disrupting effect of BPA and its analogues as well PFAAs should be taken into consideration for human health risk assessment.

The total pollutant load allocation (TPLA) can be transformed into an optimization problem with regards to water quality constraints. The optimization calculation may become very time consuming when the number of water quality constraint equations is great. A Trial and Error Method (TEM) to remove the redundant points was first introduced through iterative calculations under structure and non-structure model grids. The TEM was applied for the TPLA in the Bohai Sea in China. The calculation time was reduced to about 2min under the condition that 103,433 model grids met the water quality standards. In the best case, the optimization efficiency was improved by 98.9%. The allocation results showed that approximately 90% of total nitrogen (TN) load should be reduced in the 56 pollution sources around the Bohai Sea; of these values, roughly 85% of the reduction could come from 10 pollution sources.

We developed an inexpensive bottom water sampler that can be operated from a small boat in order to obtain high resolution vertical profiles of dissolved oxygen (DO), chlorophyll, suspended particulate matter (SPM). These vertical profiles allow us to examine bottom resuspension processes and to estimate their benthic fluxes of nutrients across the sediment–water interface in shallow coastal waters. The sampler consists of a 2m long thick-walled transparent tube with 26 sampling ports at 8–10cm intervals. Each sampling interval contains a minimum of 300–370ml water samples. Test sampling was conducted twice during different tidal phases, and differences in bottom DO, ammonium and SPM were found to be significant between the two tests. Our results suggest that this bottom sampler is essential in order to study sediment-pelagic coupling processes by obtaining high resolution of various parameters in the 2m water column above the sediment.

Large whales are frequently entangled in fishing gear and sometimes swim while carrying gear for days to years. Entangled whales are subject to additional drag forces requiring increased thrust power and energy expenditure over time. To classify entanglement cases and aid potential disentanglement efforts, it is useful to know how long an entangled whale might survive, given the unique configurations of the gear they are towing. This study establishes an approach to predict drag forces on fishing gear that entangles whales, and applies this method to ten North Atlantic right whale cases to estimate the resulting increase in energy expenditure and the critical entanglement duration that could lead to death. Estimated gear drag ranged 11–275N. Most entanglements were resolved before critical entanglement durations (mean±SD 216±260days) were reached. These estimates can assist real-time development of disentanglement action plans and U.S. Federal Serious Injury assessments required for protected species.

In this study, different types of indices were used to assess the ecological risk of trace metal contamination in sediments on the basis of sediment quality guidelines at Veraval Fishery Harbor. Sediment samples were collected from three sectors in pre-, post-, and monsoon seasons in 2006. Trace metal concentrations were higher in the inner sector during post-monsoon, and it showed the highest statistical significance (p<0.01) among the stations. Pollution load index was higher than unity, indicating alternation by effluent discharge from industries. Enrichment factor and geo-accumulation index showed that Cd, Pb, and Zn were enriched in the northern part of the harbor and Pb had accumulated in the harbor sediment. The ecological risk assessment index revealed that Ni, Zn, and Pb were higher than the effect range median values, indicating their potential toxicity to the aquatic environment in the Veraval Harbor. Hence, the harbor is dominated by anthropogenic activities rather than natural process.