The selection of emergent plants is of primary importance during the construction of floating treatment wetlands (FTWs). Focusing on the comparison of the nitrogen removal, pot-culture experiments were carried out in floating treatment wetlands constructed with Phragmites australis and Acorus calamus in northeast China, a cold temperate zone. Nitrogen removal and transformation processes were investigated to explore the pathways and factors that influence the nitrogen removal. FTWs showed a high capacity for nitrogen removal. In water with TN concentrations of 9.63 and 4.58 mg L⁻¹, the average TN removal efficiencies of the FTWs constructed with P. australis were 91.5 and 84.2%, respectively, and those of FTWs constructed with A. calamus were 84.2 and 82.8%, respectively. Plant uptake accounted for 36.4 to 77.1% of total N removal. The average TN removal rates of P. australis systems in the first 2 days were 4.20 and 1.77 mg L⁻¹ day⁻¹ for treatments with TN concentrations of 9.36 and 4.58 mg L⁻¹, respectively, significantly higher than those of the A. calamus system, which were 1.75 and 1.04 mg L⁻¹ day⁻¹, respectively. Our results suggested that plant uptake was the main pathway for nitrogen removal in FTWs, and P. australis was a suitable emergent plant species for use in FTW construction in a cold temperate zone.

Hexavalent chromium (Cr(VI)) in wastewater is a great risk to the quality of water sources and to human health. Meanwhile, Chinese herb-extraction residues (CHER) are the by-products from the extraction process of Chinese medicine. This study investigated the use of CHER to adsorb Cr(VI) from aqueous solution. Results indicated that adsorption was maximum at solution pH of 2.0 while the Cr(VI) removal efficiencies for chuanxiong rhizome residue (CRR) and Chinese wolfberry residue (CWR) were 86.56 and 99.93%, respectively. Isotherm data were modeled by using Freundlich, Langmuir, and Temkin isotherms. The maximum monolayer adsorption capacities for CWR and CRR were 79.60 and 36.21 mg g⁻¹, while their corresponding adsorption capacities obtained from experimental data were 37.30 and 32.42 mg g⁻¹, respectively. However, Freundlich isotherm fitted the data well. Both adsorption and reduction of Cr(VI) to Cr (III) forms followed by complexation onto the adsorbent surfaces favored removing Cr(VI). The results also suggested that the abundant and cheaply available CRR and CWR can be used as efficient adsorbent materials for Cr(VI) removal from wastewater.

According to our previous results on the magnesium-based exhaust gas cleaning system (Mg-EGCS), certain parameters of the desulphurization wastewater (such as chemical oxygen demand (COD), suspended solids (SS), total oil content and turbidity) were above the washwater discharge criteria set by the International Maritime Organization (IMO). In this work, a novel combined process of aeration-centrifugation and filter pressing was proposed, and a pilot-scale experiment was carried out to treat the desulphurization wastewater. The results demonstrated that the quality of wastewater treated by the combined process could meet the IMO’s washwater discharge standard, with COD of 115 mg/L, SS of <5 mg/L, polycyclic aromatic hydrocarbons (PAHs) of <1 μg/L, and total oil content of 5.1 mg/L, when the washwater flow rate was 0.45 m³/h.

Aeration of the biological reactor in wastewater treatment plants (WWTPs) represents one of the major cost items, which may account for more than 50% of the total energy consumption. Therefore, airflow rate must be supplied based on the real needs of the biological reactions and the goals to be achieved in terms of removal efficiency and effluent quality. Among the different strategies available to optimize energy consumption of air supply, the Oxy Fuzzy logic and oxidation reduction potential (ORP)-based control systems have proven to be efficient and reliable. The present study compares the effects of these two control systems in terms of energy consumption and efficiency of COD and ammonia oxidation in the activated sludge reactors of two WWTPs for domestic sewage. Both systems allowed to largely comply with the limits set on the effluent for COD and ammonia in spite of the dynamic pattern of the influent load. The Oxy Fuzzy system led to reducing energy consumption by 13% while the ORP control system only by 2%, as average per year. The Oxy Fuzzy system showed higher flexibility, being more capable of adapting the set-points in relation to the influent load. The ORP system seemed to be more suitable for plants where the influent load does not change significantly: the set-points are fixed and the input load can be properly managed only for limited variations.

This study analysed the effectiveness of innovative (basalt meal, brown algae extract) and conventional (barley straw) substances which hypothetically alleviate the inhibiting effect of Cd²⁺ on biochemical properties of soil, with particular regard to the activity of arylsulfatase. An analysis of their potential was carried out based on the activity of arylsulfatase and the number of Pseudomonas sp. determined on the 25th and 50th days of the study. Cd²⁺ was applied in the following doses: 0, 4, 40, 80, 120, 160, 200 mg Cd²⁺ kg⁻¹ of DM soil, in the form of CdCl₂·2.5H₂O. A complex formulation of the issue was obtained from the presentation of biochemical properties using the RS (resistance of soil) index. Cadmium caused permanent adverse effects in the soil environment, inhibiting the activity of arylsulfatase and the yield of spring barley. The consequences of stress connected with increasing Cd²⁺ pollution were intensified by an elongation of the accumulation time of the tested metal in the soil. Chances for regeneration of the soil may be sought, most of all, with the application of straw and, to a lesser degree, with basalt meal. Brown algae did not meet the expectations for its potential. An increase in the studied parameters also resulted from sowing the soil with spring barley.

Hexavalent chromium (Cr(VI)) and dyes are of particular environmental concern and need to be removed from water urgently due to their high toxicity. Herein, we explored the possibility of electron transferring from dye Orange II (OII) to Cr(VI) under UV and simulated solar light irradiation, expecting to simultaneously decolorize dyes and reduce Cr(VI). Experimental results show that light irradiation can partially decolorize OII but has no ability to reduce Cr(VI) in solution only with OII or Cr(VI). However, both dyes and Cr(VI) can effectively and simultaneously be decolorized and reduced in the solution containing both OII and Cr(VI) under light irradiation, and a low pH level and high OII/Cr(VI) concentration ratio significantly favor the co-removal. Additionally, insoluble organo–Cr(III) complexes identified by FTIR and XPS characterization were generated during the reaction. These complexes are beneficial to the removal of chromium and total organic carbon from water. The possible degradation pathway of OII is further proposed based on the detection of degraded products by GC-MS analysis. The results of this work offer an approach for simultaneously removing multiple contaminants.

In this study, the optimum conditions for the ammonia removal from aqueous solution by microwave-assisted air stripping have been investigated at pH 11. Ammonia solution with five different initial ammonia concentrations was prepared synthetically. The Taguchi method was applied to optimize the ammonia removal conditions. Initial ammonia concentration, air flow rate, temperature, stirring speed, microwave radiation power, and radiation time were defined as the optimization parameters. Experiments were carried out at five different levels for each operational parameter. The results of the experiments revealed that 1800 ppm of initial ammonia concentration, 7.5 L min⁻¹ of air flow rate, 60 °C of temperature, 500 rpm of stirring speed, and 500 W of microwave radiation power for 180 min. of microwave radiation time are optimum conditions for complete ammonia removal. In addition to present experimental data, the optimum operational conditions predicted by the balanced characteristics of orthogonal array were confirmed experimentally. Finally, the effect of optimization parameters was discussed in detail. Graphical Abstract ᅟ

Soil texture and soil organic carbon (OC) influence the bacterial microenvironment and also control herbicide sorption. A field-scale exploratory study was conducted to investigate the potential interaction between soil texture parameters, herbicides, and soil bacterial richness and diversity. Glyphosate and bentazon were used to evaluate the herbicidal effect on bacterial community under different conditions created by clay and OC gradients in a loamy field. Metabarcoding by high-throughput sequencing of bacterial rDNA was used to estimate bacterial richness and diversity using OTUs, abundance-based coverage (ACE), Shannon diversity index, and phylogenetic diversity. In general, bacterial richness and diversity increased after bentazon application and decreased after glyphosate application. There was no significant effect for field locations with Dexter n (the ratio between clay and OC) values below 4.04 (the median of the values in the field study). The correlation coefficient (r) between bacterial richness and clay decreased after bentazon application, but increased after glyphosate application. Correlations between Dexter n and bacterial indices followed the same pattern, decreasing after bentazon application and increasing after glyphosate application. This indicated that the specific chemical nature of individual herbicides affected bacterial communities. This study reinforced the importance of including soil physical and chemical characteristics to explain the influence of pesticides on the variation in soil bacterial communities in agroecosystems.

Dairy cattle manure has been implicated as a major source of fecal contamination in non-point source agricultural runoff in watersheds. Four different dairy farms in central Texas, each utilizing a different dairy manure management practice, in the Leon River watershed were sampled for E. coli using EPA Method 1603, with a percentage of isolates genotyped and phylotyped using the Clermont quadruplex PCR method. E. coli concentration was reduced as manure moved through the management process with tiered management systems lowering concentration the most. E. coli genotypes showed no correlation with sampling season or management practice. The highest percentage of unique genotypes was observed in dairy 2, which consisted of a settling basin then lagoon. One genotype was seen across all dairies and composed 15% of all genotypes characterized. E. coli phylotypes showed no seasonal or management practice trend. B1 was the most common phylotype isolated from all dairies and time periods, which was expected. Potentially pathogenic phylotypes were rarely observed, which could indicate isolation from pathogenic E. coli introduction. Dairy manure management practices that separate solid from liquid waste reduced E. coli concentrations the most based on these results.

Bioretention systems are of immense importance as they serve as small “sponges” for cities, cutting stormwater runoff, removing pollution, and using precipitation resources. However, performance data for these facilities are generally lacking, particularly at the field scale. This study investigated the runoff quantity regulation and pollutant removal performance of bioswale and rain garden systems from 2014 to 2017. A performance assessment of these facilities demonstrated that anti-seepage rain garden, bioswale-A, and bioswale-B effectively retained inflow volumes by the filter media, reducing runoff volumes by 54.08, 98.25, and 77.65%, respectively, on average, with only two events of overflowing. According to the water quality data in 24 rainfall events, the main pollutant indexes for the new city include total nitrogen and chemical oxygen demand, and the median values for their respective effluent event median concentrations were 1.29 and 40.13 mg/L for anti-seepage rain garden and 1.68 and 74.00 mg/L for bioswale-B systems. The mean values of pollutant removal of the three bioretention systems, except for infiltration rain garden, were 39.8–59.73% (median = 54.32%), 61.06–72.66% (median = 73.47%), and 76.67%–88.16% (median = 80.64%). Meanwhile, outflow volume of water was found to be most influenced by inflow volumes for the bioswales and anti-seepage rain garden. Mass removals were higher than concentrations owing to water volume attenuation. Based on the data of monitored pollution loads, this study estimated the annual pollutant load removal as 75.45 and 90.7% for anti-seepage rain garden and bioswale-B according to the percent of monitoring rainfall depth in total annual precipitation. This study also established the target pollutant service life model on the basis of accumulated annual load and media adsorption capacity. The results of this study will contribute to a greater understanding of the treatment performance of bioretention systems, assisting in the design, operation, and maintenance of them.