An effective 3-step method for the quantification of mass of polyethylene terephthalate microplastics and nanoplastics (PET MNPs) in complex environmental matrices was developed based on a simplified in-matrix depolymerization. Liquid chromatography (LC) coupled with ultraviolet (UV) detection was used for detection and quantification. Recoveries for PET-spiked sand samples were 99 ± 2% (1 mg/L) and 93 ± 7% (30 mg/L). The limit of quantification (LOQ) for PET was 0.4 μg/g for sand, 1 mg/g for indoor dust and 0.2 μg/g for wet sludge. This method was applied to seven beach sand samples, 20 indoor dust samples and one sewage sludge sample. PET MNPs levels in sand samples were all below the limit of detection (LOD) of LC-UV (0.1 μg/g). The concentrations of PET MNPs in indoor dust samples ranged from 1.2 to 305 mg/g and the PET MNPs in liquid sludge was 1.5 mg/L.

Microplastic (MP) contamination is a serious threat to today's marine life. Therefore, this study investigates MP ingestion in three commercial fish species (European anchovy Engraulis encrasicolus, whiting Merlangius merlangus, and red mullet Mullus barbatus) from the Turkish coast of the Black Sea. Ninety-five MPs were detected in all examined fish (371). Fiber forms were detected in the majority of cases based on the MP morphology. Polyethylene and polypropylene were the most dominant polymer type. The mean of ingested MPs was found as 0.15 ± 0.04, 0.28 ± 0.06, 0.40 ± 0.07 in anchovy, whiting and red mullet, respectively. The size of the MPs ranged from 118 μm and 4854 μm. The MP waste was detected in each species, and the highest MP amount was determined in the red mullet, which was significantly higher than European anchovy. The present study's data might be a baseline on the ecological risk assessment of MPs in the fish and future experimental studies on the fish species living in the Black Sea.

This study was a baseline with quantitative data of marine litter along the Gulf of Nicoya, Costa Rica. The objective of the study was to quantify marine litter and its association with human activities in this estuarine gulf. A total of fourteen sandy beaches were cataloged by the degree of urbanization, tourism intensity, beach cleaning programs, and tributary rivers as possible drivers of marine litter presence. The items of the marine litter were separated and weighted by type. Analysis by the clean coastal index (CCI) and multivariate statistics were applied to find spatial patterns in marine litter in the gulf. On beaches with the highest touristic activity, cigarette butts and straws were the main components. Locations with river plume influence, less frequent cleanup, or waste cans showed more bottles, plastic parts, and sanitary waste than beaches in other conditions. A beach in a fisherman town had recently utilized plastic bags, household goods, and boat parts in the marine litter. A wildlife refuge beach showed only small plastic and coffee foam cup fragments that came with currents from other points in the estuary. River basin management, solid waste disposal programs, and environmental education to avoid single-use items combined with correct waste disposal are needed to reduce marine litter in tropical countries focused on ecological tourism.

Potassium cyanide (KCN), a highly water soluble and bioaccumulative cyanide salt, is examined to determine the toxic effects by using two green algae (Dunaliella viridis, Nannochloropsis oculata) and genetically different two sea urchin (Paracentrotus lividus, Arbacia lixula) species. To determine the toxic effects on the early developmental stages of sea urchin embryos, 72-hour embryotoxicity studies were conducted. Potassium cyanide toxicity at cellular level was also investigated and 6-hour embryos of both sea urchin species were used to determine genotoxic effects of KCN. Since plutei naturally feed on microalgae, two species of plankton were used to reveal phytotoxic effects of KCN. KCN was found to be embryo- geno- and phytotoxic. EC₅₀'s for P. lividus and A. lixula were found 7.96 and 6.52 μM. IC₅₀'s for N. oculata for 48 h and 72 h were found 23.66 and 80.45 μM. IC₅₀'s for D. viridis for 48 h and 72 h were found 14.31 and 23.36 μM.

This paper analyzed the long-term variations in nutrients in Liaodong Bay and their potential influencing factors based on historical data from 1978 to 2019. Under the influence of both human activities and natural changes, the concentration of DIN increased approximately 4-fold from the end of the 1990s to the mid-2010s, while DIP and DSi concentrations decreased from the beginning to the end of the 1980s and have since increased again. Asynchronous changes in nutrient levels have led to changes in the nutrient composition, which has caused a series of ecological effects. The total phytoplankton abundance decreased from the 1980s to the end of the 1990s and then increased again. Additionally, the phytoplankton composition shifted from a diatom-dominated to a dinoflagellate-dominated system, and the dominant species of zooplankton changed. Harmful algal blooms (HABs) rarely occurred before the 1980s but have frequently occurred since the end of the 1990s.

Occurrence, distribution, and potential ecological risks of ten organophosphate esters (OPEs) and nine synthetic musks (SMs) were investigated in sediments from the Yangtze River Estuary (YRE) and adjacent East China Sea (ECS). The total concentrations of OPEs in the surface sediments ranged from 0.977 to 19.0 ng/g dry weight (dw) with tris(2-chloro-propyl) phosphate being the dominant component. Total concentrations of SMs ranged from 0.176 to 7.25 ng/g dw, with 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta(g)-2-benzopyran and 7-acetyl-1,1,3,4,4,6-hexamethyl-1,2,3,4-tetrahydronaphthalene as the dominant SMs. Higher sedimentary concentrations of ΣOPEs and ΣSMs were found in the river mouths of the YRE, inter face of Hangzhou Bay, and mud area of the ECS; the results suggested that terrestrial discharge might be the main source of OPEs and SMs in the studied region. Risk assessment revealed that low ecological risks were posed by OPEs, and limited to low ecological risks were posed by SMs.

Almost everywhere in the marine ecosystem contains microplastics. Although their environmental contamination is a global problem, relatively little is known about their distribution and abundance in the Gulf of Guinea. This study looked at the spatial dynamics of microplastics in the sea surface water off the coast of Ghana. Four chosen areas were found to have non-variable concentrations ranging from 1.14 to 2.79 particles m⁻³ using a self-constructed Low-Tech Aquatic Debris Instrument (LADI) trawl (333 μm mesh). The most abundant shapes were fragments and pellets, while the most common colors were colored and transparent particles. The polymer types found in the microplastics selected for investigation using Fourier Transform Infrared spectroscopy in Attenuated Total Reflectance mode (ATR-FT-IR) were Polypropylene, Polyethylene, and Polystyrene. These results provide an important baseline on microplastic pollution along the Ghanaian coast suggesting the LADI trawl as an accurate quantitative sampling tool for microplastics from sea surface water.

Trindade is a remote island far from 1170 km of the Brazilian coast in the Atlantic Ocean, between South America and South Africa. The island has great biodiversity and scientific studies on the fauna and flora of Trindade are still scarce. Accordingly, since crustacean species of the island are also little known, this research features an unprecedented data set, which provides information on the level of potential toxic elements in two crab species: the Grapsus grapsus (herbivore) and the endemic species Gecarcinus lagostoma (omnivorous) which is in threatened status. Although Trindade has experienced contamination from human activities, mainly plastic debris, the element levels found in the samples suggest that there are no relevant inorganic sources into the island. Since minor and trace elements accumulated by marine invertebrates does not present a pattern behavior, our results can support other studies focused on the impact of global warming to the marine ecosystem.

Underwater volcanic eruptions are a type of natural contamination that affect all marine organisms at a local level. These eruptions usually begin and end a degassing stage of the volcano that, although they do not affect the magnitude of magma emanation, affect organisms to a lesser degree locally, such as cephalopods that due to their metabolism and trophic level, are good bioindicators of contamination. A total of 180 samples of three species of cephalopods were collected for the study: sixty Sepia officinalis, sixty Octopus vulgaris and sixty Loligo vulgaris in the area of the submarine volcano in El Hierro, Tenerife and Lanzarote in the Canary Islands (twenty samples per species in each location), and the metal concentrations (Al, Cd, Cr, Cu, Fe, Li, Ni, Pb and Zn) in each of the samples were analyzed. All species showed significant differences for all metals in El Hierro compared to Tenerife and Lanzarote. All the analyzed species from El Hierro had higher concentrations of the nine studied metals, this is due to the fact that they were caught near the Tagoro submarine volcano, which at the time was in a state of degassing and discharged many metal-rich compounds.