Soil washing is an effective technology for the remediation of soils contaminated with various metals. However, the bioavailability of residual metals in soils and soil properties can be changed during the washing processes. In this study, we used four amendments to revitalize mixed chelator (MC)–washed soils (WS). These amendments included zeolite, CaCO₃, biochar, and chicken manure. Results showed that inorganic amendments reduced the available Cd and Zn concentrations, while organic amendments, particularly chicken manure, reduced the Pb bioavailability in WS. The combination of 0.2% CaCO₃ and 2% chicken manure amendments reduced the Cd, Pb, and Zn bioavailability by 45.8%, 77.8%, and 15.0% compared with the control treatment, respectively. The inorganic amendments should increase the seed germination rate of Chinese cabbage (Brassica rapa L.). However, the shoot growth decreased significantly. The combination of amendments cannot increase the seed germination but can significantly increase the shoot growth of Chinese cabbage compared with the control. The combination of amendments enhanced the fertility of WS, particularly available P and exchangeable K, which may improve plant growth. These results suggested that the combination of amendments, especially CaCO₃ (0.2%) and chicken manure (2%), can be used to revitalize MC-WS.

In the original publication’s Fig. 1b, the labels J and I, should be placed at approximately 2 ms and 30 ms respectively. Also, Fig. 3C y-axis title should be written as ψEₒ /(1- ψEₒ).

Calcium ion-incorporated hydrous iron(III) oxide (CIHIO) samples have been prepared aiming investigation of efficiency enhancement on arsenic and fluoride adsorption of hydrous iron(III) oxide (HIO). Characterization of the optimized product with various analytical tools confirms that CIHIO is microcrystalline and mesoporous (pore width, 26.97 Å; pore diameter, 27.742 Å with pore volume 0.18 cm³ g⁻¹) material. Increase of the BET surface area (> 60%) of CIHIO (269.61 m² g⁻¹) relative to HIO (165.6 m² g⁻¹) is noticeable. CIHIO particles are estimated to be ~ 50 nm from AFM and TEM analyses. Although the pH optimized for arsenite and fluoride adsorptions are different, the efficiencies of CIHIO towards their adsorption are very good at pH 6.5 (pHzₚc). The adsorption kinetics and equilibrium data of either tested species agree well, respectively, with pseudo-second order model and Langmuir monolayer adsorption phenomenon. Langmuir capacities (mg g⁻¹at 303 K) estimated are 29.07 and 25.57, respectively, for arsenite and fluoride. The spontaneity of adsorption reactions (ΔG⁰ = − 18.02 to − 20.12 kJ mol⁻¹ for arsenite; − 0.2523 to − 3.352 kJ mol⁻¹ for fluoride) are the consequence of entropy parameter. The phosphate ion (1 mM) compared to others influenced adversely the arsenite and/or fluoride adsorption reactions. CIHIO (2.0 g L⁻¹) is capable to abstract arsenite or fluoride above 90% from their solution (0 to 5.0 mg L⁻¹). Mechanism assessment revealed that the adsorption of arsenite occurs via chelation, while of fluoride occurs with ion-exchange.

This study has compared the harvesting efficiency of four flocculation methods, namely, induced by pH, FeCl₃, AlCl₃ and chitosan. No changes were observed on M. aeruginosa cells. Flocculation assays performed at pH 3 and 4 have shown the best harvesting efficiency among the pH-induced tests, reaching values above 90% after 8 h. The adjustment of zeta potential (ZP) to values comprised between − 6.7 and − 20.7 mV enhanced significantly the settling rates using flocculant agents, being FeCl₃ the best example where increments up to 88% of harvesting efficiency were obtained. Although all the four methods tested have presented harvesting efficiencies above 91% within the first 8 h after the optimization process, the highest performance was obtained using 3.75 mg L⁻¹ of FeCl₃, which allowed reaching 92% in 4 h.

To remove the extra ammonium-nitrogen (NH₃-N) and phosphorus (P) from contaminated water, a novel granular adsorbent (GAZCA) was fabricated with zeolite powders and Al–Mn binary oxide (AMBO) via the compression method. The SEM-EDS and mapping and XRD results illustrated the microstructure of GAZCA: the homogeneous aggregation of zeolite and AMBO nanoparticles with their crystal integrity and the uniform distribution of Al/Mn/Si/O elements on the adsorbent surface. FTIR and XPS results demonstrated the existence of impregnated sodium cations and hydroxyl groups, which were responsible for the removal of NH₃-N and P, respectively. The results of BET analysis and compression tests exhibited a high surface area (14.4 m²/g) and a satisfactory mechanical strength of GAZCA. Kinetic adsorption results showed a fast adsorption rate for NH₃-N and P, and mutual inference was not observed between the adsorption kinetics of NH₃-N and P in the bi-component system. The adsorption isotherm results demonstrated that the maximum adsorption capacities of NH₃-N and P were calculated as 12.9 mg/g and 9.3 mg/g via the Langmuir model, respectively. In the bi-component system, the adsorption capacities of NH₃-N and P were maintained at low and moderate concentrations and decreased at high concentrations due to the blockage effects of NH₄MnPO₄·H₂O precipitates. The removal efficiency of NH₃-N could be maintained in a wide pH range of 4~10, while P adsorption was inhibited at alkali conditions. The solution of sodium bicarbonate (0.4 M) was used for the regeneration of saturated adsorbents, which permitted GAZCA to keep 98% and 78% of its adsorption capacity for NH₃-N and P even after three regeneration and reuse cycles. Dynamic experiments illustrated that a satisfactory performance was obtained for the in situ treatment of simulated N- and P-contaminated water by using a column reactor packed with GAZCA, thus further confirming its great potential for the control of eutrophication.

The current research reports an efficient methodology of new sorbent (SSBC) synthesis based on neglected sepia shells for the sequestration of cationic dye (Methylene blue, MB) and an anionic dye (Reactive black 5, RB5) from aqueous solutions. The as-synthesized SSBC was produced by reaction of sepia shell powder with urea in the presence of formaldehyde. In the first part of the work, the sorbent was scrutinized by using scanning electron microscopy, energy-dispersive X-ray analysis, Fourier transform infrared spectrometry, and titration (for determining pHPZC). In the second step, the influence of several parameters including pH effect, sorbent dosage, temperature, and ionic strength on the two dyes’ sorption effectiveness was examined. The sorption isotherms and uptake kinetics were analyzed at the optimum pH. Outlined results showed that the dynamic experimental obtained data followed the Langmuir isotherm profile, while the kinetic profile fitted well to the pseudo-second-order rate equation. Maximum sorption capacities reach up to 0.794 mmol g⁻¹ (254.05 mg g⁻¹) for MB and 0.271 mmol g⁻¹ (269.18 mg g⁻¹) for RB5, at pH 10.5 and 2.3, respectively. By comparing the sorption properties at different temperatures, the endothermic nature of the sorption process was revealed. Sorption processing under microwave irradiation (microwave-enforced sorption, MES) enhanced mass transfer, and a contact time as low as 1 min is sufficient under optimized conditions (exposure time and power) reaching equilibrium, while 2–3 h was necessary for a “simple” sorption. Dye desorption was successfully tested using 0.5 M solutions of NaOH and HCl for the removal of RB5 and MB, respectively. The as-prepared sorbent can be reused for a minimum of 4 cycles of sorption/desorption. Finally, the sorbent was successfully tested on spiked tap water and real industrial wastewater.

Pyrethroids are used in agricultural to control pests on a variety of crops. Bifenthrin, a synthetic pyrethroid, is a broad spectrum insecticide. It acts mainly on the nervous system of vertebrates as well as invertebrates. It is susceptible to the biodegradation by some soil bacteria. The present paper deals with the toxicological studies of bifenthrin and its metabolites benzene 1,1(methylthio) ethylidine, resorcinol and monochloro trifluromethane that were produced by a newly isolated strain of Paracoccus siganidrum APGM1 on earthworms, which play an important role in the improvement of the soil fertility. The toxicity was assessed by 48 hrs filter paper contact test, 14 days soil test and histopathological methods. The results of filter paper contact test revealed that the earthworms were more susceptible to bifenthrin than their metabolites. The LC50 value of bifenthrin and its metabolites was 6 ppm and 20 ppm respectively. The soil test showed that at 6 ppm concentration of bifenthrin, half the number of earthworms died after 14 days and with the increase in the concentration, mortality increased. At 10 ppm concentration, all the earthworms died. However, half the number of earthworms died after 14 days at the metabolite concentration of 20 ppm. The adverse effects of bifenthrin and very little effect of their metabolites on the morphological properties and structural integrity of the tissues were observed in histopathological studies. Thus, the metabolites of bifenthrin were less toxic to earthworms than the bifenthrin.

Biochar is thought to be a good adsorption material for the adsorption of heavy metals. In this study, biochar derived from Torreya grandis nutshell was prepared through to be pyrolyzed under oxygen limited conditions in a muffle furnace. The adsorption experiments of Cr(VI) were carried out. Through Elemental Analyzer, Specific Surface Area Meter, Scanning Electron Microscopy, Transmission Electron Microscopy and Fourier Transform Infrared Spectroscopy, a fundamental understanding of the physical and chemical properties of biochar was gained. The results showed that it was a smooth sheet and irregular arrangement structure. The elements of C, H, O and N of biochar are 45.21%, 5.18%, 46.16% and 3.45% respectively. BET specific surface area of biochar is 42.24 m2/g. A lot of oxygencontaining functional groups (– OH, COO –, – C – OH and so on ) appeared on the surface of biochar. It can be described by the pseudo-second order kinetic rate model and Langmuir isotherm model. The adsorption process is a monolayer chemical process. The adsorption mechanism of biochar on heavy metal Cr(VI) contains the electrostatic attraction between biochar and Cr2O7 2-, HCrO4 - and CrO4 2- ions in aqueous solution and complexation reaction of oxygen-containing functional groups (– OH, – COOH and so on) and Cr2O7 2- , HCrO4 - and CrO4 2- ions on the surface of biochar.

Faced with the problems of hypolimnion dissolved oxygen (DO) depletion and water quality deterioration, a newly designed water quality improvement technology named water-lifting aerators (WLAs) was put into utilization to solve these problems in Jinpen Reservoir. During the hypolimnion oxygenation period, after 20 days operation of 8 WLAs with compressed air volume of 10 m3/h, the thickness of anaerobic layer was compressed from 17 m to 3.2 m. As for artificially induced mixing, after 18 days operation of 8 WLAs with compressed air volume of 50 m3/h (full capacity), the reservoir was mixed, and DO of the bottom water increased to more than 8 mg/L. Removal rates of TN, TP, NH4-N and TOC reached 25.5%, 50%, 29.8% and 19.4% respectively. Results of Biolog method showed that the activity of microbes and carbon source utilization were improved in the water of the controlled area compared with the uncontrolled area during the operation. WLAs have been proved to be an efficient technology in water quality improvement especially in hypolimnion oxygenation and artificially induced mixing.