Arbuscular mycorrhizal (AM) fungi were of importance in mitigating soil erosion, which was highly influenced by biotic and abiotic factors, such as host plant growth and soil nutrient. To investigate the impact of nitrogen (N) fertilization on seasonal variance in AM colonization and soil erosion, we conducted a field experiment with rice cultivation under four N fertilizer levels (0 kg N ha⁻¹, 270 kg N ha⁻¹, 300 kg N ha⁻¹, and 375 kg N ha⁻¹ plus organic fertilizers) in the Taihu Lake region, China. We investigated AM colonization before rice transplantation, during rice growth, and after rice harvest. We also assessed soil splash erosion of intact soil cores sampled at tillering and after rice harvest. We found that AM colonization (indicated by percentage of root length colonization) varied from 15 to 73%, which was attributed to rice growth, N fertilization, and their interaction. Soil loss due to splash erosion was cut down by organic N fertilizer at tillering, while higher inorganic N fertilization significantly increased soil loss after rice harvest. Additionally, we found significantly negative relationships of AM colonization to soil loss but positive relationships to soil aggregate stability. We highlighted the potential role of AM fungi in decreasing soil erosion and suggested that high N fertilization should be considered carefully when seeking after high yields.

The role of a single water molecule on the atmospheric reaction of HONO + ClO is systematically investigated employing quantum chemical calculation combined with harmonic transition state theory. Two reaction pathways, cis-HONO + ClO and trans-HONO + ClO, are identified for the naked reaction, which depends on the configurations of HONO. When adding a single water molecule to this reaction, the rate constants of cis-HONO + ClO and trans-HONO + ClO pathways are 7.97 × 10⁻²¹ and 2.29 × 10⁻¹⁷ cm³ molecule⁻¹ s⁻¹, respectively, larger than the corresponding naked reaction. To further understand the role of water on the HONO + ClO reaction, it is necessary to calculate the effective rate constant by considering the concentration of water. It shows that the effective rate constants of water-assisted cis-HONO + ClO pathway are much smaller than those of the naked reaction, whereas the presence of water accelerates the trans-HONO + ClO at room temperature. This study demonstrates that water has a positive role in the pathway of trans-HONO + ClO by modifying the stabilities of reactant complexes and transition states through the hydrogen bond formation, which contributes to the sink of atmospheric HONO. In addition, the kinetic branching ratio indicates that the favorable reaction is the trans-HONO + ClO instead of the cis-HONO + ClO pathway, in contrast to the naked reaction. These results reveal the importance of water in the evaluation of the fate of active species in the atmosphere. Graphical Abstract

The shortage of drinking water is a major problem in the rural areas of the Mekong Delta, especially, when surface water, a main local direct drinking water source is being threatened by pesticide pollution and salinity intrusion. A hybrid process coupling electrodialysis (ED) and nanofiltration (NF) is proposed as an effective process easy to setup in a small plant to treat complex matrix with high salinity and pesticide concentration as is the Mekong Delta surface water. Performance of the ED–NF integration was evaluated with synthetic solutions based on the comparison with a single NF step generally used for pesticide removal. Both energy consumption and water product quality were considered to assess process efficiency. The ED stage was designed to ensure a 50% removal of salinity before applying NF. As expected, the NF rejection is better in the hybrid process than in a case of a single NF step, especially for pesticide rejection. The integration of a NF stage operated with NF270 membrane consumes less energy than that with NF90 membrane but its efficiency was observed not high enough to respect the Vietnamese guidelines. Using NF90, the optimal recovery rate of the NF stage varies from 30 to 50% depending on the salt content in the feed.

There has been a conflicting issue in rural China that whether or not encouraging the development of medium–large-scale biogas plants (MLBPs) to reduce household biogas digesters (HBDs) will be better for China in the long run. In this study, we investigate the difference between HBD users and MLBP users and the factors that affect the biogas use of these two user types on the basis of a survey of 1125 households in four provinces in China. The results indicate that compared to HBD users, MLBP users have a higher ratio (29%) of biogas use, obtain a higher subsidy-to-cost ratio (25%), and present a more positive evaluation of biogas service (3%). For HBD users, installation years and service evaluation are significant predictors of biogas use. For MLBP users, in addition to installation years and service, the subsidy-to-cost ratio affects biogas use negatively, and the biogas price is a key constraint for biogas use. These results provide valuable insights into the future development of biogas energy in rural China and guidance for the development of biogas in similar countries worldwide.

The objective of this study is to investigate the contributions of Mikania micrantha (chinese creeper) to remediate heavy metal pollutants present in an e-waste-contaminated soil. Different proportions of e-waste soil (0%, 25%, 50%, 75%, and 100% w/w) planted with Cynodon dactylon together with the test species were prepared for testing relative seed germination (RSG), relative root growth (RRG), and germination index (GI) tests. A significant higher value of GI (77.8%) was found in M. micrantha than that of the other species when planting in 100% e-waste-contaminated soil. A significant correlation (< 0.05) was found between heavy metal concentration and germination assays in M. micrantha. A significant decrease in heavy metal concentration of the polluted soil after the experiment indicated that biomolecule development studies to determine the aggregate benefit of M. micrantha for phytoremediation remain to be studied in future.

With increasing environment pollution and bacterial transmitted viral diseases globally, the development of new, effective, and low-cost materials/strategies is the current major challenge. To combat with this alarming problem, three new multi-functional and thermally stable SnO₂NPs@ZIF-8 composites (NC1, NC2, and NC3) were synthesized by a facile and sustainable approach involving in situ encapsulation of SnO₂NPs (150, 300, and 500 μL suspension in methanol) within zeolitic imidazole framework at room temperature. The morphology and crystallinity of ZIF-8 remained unchanged upon the proper encapsulation of SnO₂NPs in its matrix. Herein, for the first time, the antiviral potential of ZIF-8 and SnO₂NPs@ZIF-8 against chikungunya virus is reported by investigating their cytotoxicity against Vero cell line (employing MTT ((3-(4,5-dimethylthiazol-2-yl)-2, 5-diphenyltetrazolium bromide)) assay). The maximum non-toxic doses were 0.04 mg mL⁻¹ for ZIF-8 and SnO₂NPs@ZIF-8 and 0.1 mg mL⁻¹ for SnO₂NPs. Further, NC1 exhibited (based on plaque assay) reduction in viral load/titers up to > 80% during post-treatment and > 50% during pre-treatment, greater than that of ZIF-8 and SnO₂NPs due to synergistic effect. Further, NC1 (10 mg) exhibited enhanced photocatalytic efficiency (≥ 96%) for degradation of methylene blue (0.5 × 10⁻⁵ M) at pH ˃ 7.0. The probable mechanism for their antiviral activity and photocatalytic activity has been discussed. The multi-functional composites can effectively be used to reduce water pollution and as remedy for mosquito/bacterial transmitted viral diseases.

Real-time monitoring of source zone of light non-aqueous liquids (LNAPLs) is important for preventing accidental pollution and taking effective underground pollution remediation measures. As a high-precision monitoring technology, cross-hole electrical resistivity tomography (CHERT) has been widely used to obtain static information regarding underground stratigraphic structures and dynamic information regarding fluid motion. The time-lapse data processing method can be used to obtain pollution zone dynamic change information. Since the leakage rate directly affects the diffusion range of pollution, this study simulated the initial evolution process of LNAPL pollution source regions under two different leakage rates. The time-lapse monitoring of the above process was performed using CHERT. The test results show that CHERT can be used to observe the migration of LNAPLs and the initial evolution of the contaminated area. Differences in leakage rate will result in variation in soil wettability and fluid distribution, which will cause changes in soil resistivity in the corresponding region. The low-saturation LNAPL-contaminated area may exhibit low-resistivity characteristics and is easily overlooked in field investigations. In addition, the degree of contamination in the saturated zone can be quantitatively evaluated by CHERT; however, the pollution range and oil saturation value determined by CHERT are underestimated. The results showed the electrical variation characteristics of the initial evolution process of the fresh pollution source area and provide data that will enable early warnings of LNAPL leakage. This shows that CHERT is a promising tool for monitoring LNAPL pollution source leakage even if further research is needed to fully understand the effect of hydrological processes on electronic signals.

This study aims to examine the stochastic convergence of per capita carbon dioxide (CO2) emissions in 21 OECD countries and 19 emerging market economies. After approximating both sharp and smooth breaks, the panel unit root tests are performed to test the convergence. The empirical results suggest stochastic convergence for the two groups of countries. However, the results are different when tests for individual countries are conducted separately. Specifically, CO2 emissions of only four OECD countries and four emerging market economies show evidence of convergence if smooth breaks are not considered. With the inclusion of both sharp and smooth breaks, convergence is observed for 11 OECD countries and 10 emerging market economies. These findings may have implications for climate change policy making in selected economies.

The ecosystem of the Seocheon coastal wetland (SCW), one of the wetland protected areas in South Korea, was registered in the Ramsar Wetlands in 2009 as an area rich in biodiversity and inhabited by endangered wild animals and plants. Since then, preserving the ecosystem of the SCW has emerged as an important task. Thus, the South Korean government is carrying out various research and management projects to preserve the ecological integrity of the SCW. This article aims to analyze public willingness to pay for preserving the SCW. For this purpose, 1000 households were surveyed, applying the contingent valuation (CV) method during September 2017. The respondents clearly understood the CV question and gave meaningful answers. The results show that an average value for the preservation was statistically significantly estimated to be KRW 2341 (USD 2.04) for all respondents. The national value expanded from the sample to the population is worth KRW 47.79 billion (USD 42.15 million) per year. Therefore, it can be seen that the public have sufficient acceptance for preserving the SCW.

Several parts of the world have been facing the problem of nitrite and nitrate contamination in ground and surface water. The acute toxicity of nitrite has been shown to be 10-fold higher than that of nitrate. In the present study, aminated silica carbon nanotube (ASCNT) was synthesised and tested for nitrite removal. The synergistic effects rendered by both amine and silica in ASCNT have significantly improved the nitrite removal efficiency. The IEP increased from 2.91 for pristine carbon nanotube (CNT) to 8.15 for ASCNT, and the surface area also increased from 178.86 to 548.21 m² g⁻¹. These properties have promoted ASCNT a novel adsorbent to remove nitrite. At optimum conditions of 700 ppm of nitrite concentration at pH 7 and 5 h of contact with 15 mg of adsorbent, the ASCNT achieved the maximal loading capacity of 396 mg/g (85% nitrite removal). The removal data of nitrite onto ASCNT fitted the Langmuir isotherm model better than the Freundlich isotherm model with the highest regression value of 0.98415, and also, the nonlinear analysis of kinetics data showed that the removal of nitrite followed pseudo-second-order kinetic. The positive values of both ΔS° and ΔH° suggested an endothermic reaction and an increase in randomness at the solid–liquid interface. The negative ΔG° values indicated a spontaneous adsorption process. The ASCNT was characterised using FESEM–EDX and FTIR, and the results obtained confirmed the removal of nitrite. Based on the findings, ASCNT can be considered as a novel and promising candidate for the removal of nitrite ions from wastewater.