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The Impact of RDF Valorization on the Leachate Quality and on Emissions from Cement Kiln (Case Study of a Region in Morocco) Полный текст
2021
Ouigmane, Abdellah | Boudouch, Otmane | Hasib, Aziz | Ouhsine, Omar | Abba, El Hassan | Isaifan, Rima J. | Berkani, Mohamed
Energy recovery is a sustainable method of municipal solid waste (MSW) management. The co-incineration of refuse derived fuel (RDF) has shown several economic and environmental advantages. The objective of this research is to assess the impact of RDF recovery on leachate quality using leachate tests and calculation of greenhouse gases (GHG) reduction in the kilns of a cement plant. The qualitative results of the eluate show that there is an impact on leachate quality depending on the type of waste. The values of the chemical oxygen demand (COD), biological oxygen demand (BOD5), electrical conductivity and pH of the leachate from the raw waste after 120 hours of leaching are 29.33 gO2/kg DM, 14.00 g O2/kg DM, 4.27 ms/cm and 7.57. On the other hand, the values of the same quality parameters of the eluate generated by the waste without RDF are 19.33 g O2/kg DM, 20.67 g O2/kg DM, 2.77 ms/cm and 7.13; respectively. The calculation of GHG reduction shows that the substitution of 83,000 tonnes per year of petroleum coke by 15% of RDF (25,493 tonnes per year) can reduces 28,970 tCO2 eq.
Показать больше [+] Меньше [-]Efficacy of Photocatalytic HEPA Filter on Reducing Bacteria and Fungi Spores in the Presence of UVC and UVA Lights Полный текст
2021
Mousavi, Tahereh | Golbabaei, Farideh | Kohneshahri, Mehrdad Helmi | Pourmand, Mohammad Reza | Rezaie, Sassan | Hosseini, Mostafa | Karimi, Ali
The Indoor Air Quality (IAQ) of a hospital is very important to properly protect both patients and the staff against hospital infections. The present study aims at evaluating the efficiency of photocatalytic filters as well as the impact of important factors such as the type of UV wavelength (UVC, UVA) with different intensities and loading rates of TiO2 in HEPA Filters on reducing airborne microorganisms. For so doing, it has prepared photocatalytic filters by dipping them into 2% and 4% titanium dioxide suspensions as low and high loading, respectively. The experiments have been carried out on four species’ microorganisms, namely Epidermidis, Subtilis, Niger, and Penicillium. Fungi and bacteria suspensions have been prepared with concentrations of 106, 107 CFU/m3, respectively. In terms of microorganism removal, the efficiency of HEPA filters in both types of TiO2 loading and UVC and UVA radiations with two intensities at three times intervals (60, 90, and 120 min) have been investigated. Results show that lower penetration microorganism belong to PCO (TiO2 + UV), compared to photolysis (UV alone) at all intervals of UV radiation. TiO2 loading has no significant effect on percentage removal in all microorganisms. The percentage penetration of microorganisms under UVC radiation is lower than UVA radiation. Also, increasing the radiation intensity in both types of UV shows that it has higher effectiveness for removing bacteria and fungi. Therefore, the use of photocatalytic HEPA filters with UVC radiation can play an influential role in reduction of the microorganisms in different places such as hospitals, cleanrooms, etc.
Показать больше [+] Меньше [-]Effect of Biochar Amended Vermicomposting of Food and Beverage Industry Sludge along with Cow dung and Seed Germination Bioassay Полный текст
2021
Tasnim, Umme Fariha | Shammi, Mashura | Uddin, Md. Khabir | Akbor., Md. Ahedul
Transformation of food and beverage industrial sludge into vermicompost into value-added product simultaneously can control gaseous emission. Addition of biochar in the vermicomposting as a bulking agent increases fertilizer value. This research aimed to investigate the effect of biochar amendment on vermicomposting of the food and beverage industry sludge (FBIS) and cow dung (CD) in a different ratio using earthworm Eisenia fetida. We had further investigated the survival rate of E. fetida and the cocoon productions after 35 days of the vermicomposting. Besides, we have also evaluated the seed germination bioassay using Malabar spinach (Basella alba) to determine the toxicity and maturity of produced compost. The survival and cocoon production of E. fetida were higher in vermicompost amended with 10% biochar. Vermicomposting with biochar resulted in a slight pH shift. Reduction in organic carbon (OC) percentage not so significant in biochar added FBIS and CD. An increase in phosphorus and potassium content and a decrease in nitrogen percentage observed; vermicomposting with biochar resulted in higher seed germination, root elongation, and germination index than vermicomposting without biochar.
Показать больше [+] Меньше [-]Extraction of Keratin from Human Hair Waste as Adsorbent: Characterization, Thermodynamic and Kinetic Study for Removal of Chromium (VI) ions Полный текст
2021
Abbasi, Fereshteh | Farrokhnia, Abdolhadi | Abbasi, Zahra
In this paper, human hair, as a waste material, was utilized in order to prepare keratin nanoparticles. The characterization of keratin nanoparticles was performed applying Transmission electron microscopy (TEM), Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR) and X-Ray diffraction (XRD). The average diameter of keratin nanoparticles was found to be 63.7 nm, using particle size analyzer. Subsequently, the keratin nanoparticles were employed for Cr (VI) ions adsorption. The batch experiment was carried out to find the optimum conditions; i.e. contact time, pH, adsorbent dose and initial concentration of Cr (VI) ions. The adsorption capacity was extremely pH-dependent, and the maximum adsorption of Cr (VI) happened in the acidic pH range. The results demonstrated that the maximum adsorption capacity, obtained in acidic pH, was 161.29 mg/g. The equilibrium data were well fitted by Freundlich isotherm. The kinetic studies were performed with the Lagergren’s first-order, Pseudo-second order, Elovich, and Intra-particle diffusion models. In this sense, in order to describe kinetic data, we came to this understanding that Pseudo-second order model was the best choice. The thermodynamic parameters of the adsorption process indicated that the Cr (VI) adsorption on keratin nanoparticles is endothermic and spontaneous.
Показать больше [+] Меньше [-]Identification and Characterization of Phenolic and Flavonoids Compounds Extracted from Tunisian Pomegranate Fruit Peel Exposed to Air Pollution: Gabes City, Tunisia Полный текст
2021
Ben Amor, Afef | Ben Atia Zrouga, Khaoula | Chaira, Nizar | Ben Yahia, Leila | Nagaz, Kamel
The pomegranate (Punica granatum) fruit peel exposed to mixture air pollutants were collected from two sites with different air quality around the industrial area of Gabes city, Tunisia. The first site presented the ‘Polluted site’, which is situated in the oasis close to the industrial area. While, the second site referred to the ‘Control site’ located at 37 km from the industrial area. Using HPLC ES-MS, 21 phenols were identified and quantified in methanol extract from pomegranate fruit peel. The results showed that various phytochemical substances, including phenols acids and flavonoids, were identified and quantified in the peel extract. The polyphenols content and the flavonoids contents in peel obtained from polluted site were higher than that collected from the control site. The concentrations of the identified polyphenols were ranged between 0.39 and 7803.68 mg/ kg DW. The stimulation of some free phenolic compounds such syringic acid, transfrulic acid, epicatechin, rutin and quercetin was enregistred only in peel collected from contaminated environment. The quali-qualitative changes between sites are probably related to the difference in the air quality. The increase of polyphenols could be implicated during adaptive mechanisms under air pollution. Phenolic composition changes in Punica granatum peel could be also suggested as useful approach air pollution monitoring.
Показать больше [+] Меньше [-]Water Quality Assessment in Urban Wetlands and Suitability for Fish Habitat: A Case Study Полный текст
2021
Dixit, Arohi | Siva Siddaiah, Neelam | Singh Chauhan, Jogindar | Ullah Khan, Waseem
In this study, water from three urban wetlands of Gurugram – Sultanpur (WS), Damdama (WD), and Basai (WB), was studied for various physicochemical parameters to assess their suitability for the healthy survival of fishes and the results were compared with the limits of these parameters for fish farming. The parameters studied were colour, temperature, pH, alkalinity, hardness, Ca2+- Mg2+ ratio, NO3-, Cl-, SO42-, PO43-, and heavy metals (Fe, Mn, Cr, Cu, Zn, Ni and Pb). The results of the study indicate the majority of studied parameters are beyond the desirable limits in WB; thus, water is most unsuitable for fishes in WB. WB is unsuitable for parameters: colour, alkalinity, hardness, Ca -Mg ratio, NO3-, Cl-, SO42-, PO43-, Cr, Cu, Fe, Mn, Ni and Zn. WS needs consideration for temperature, NO3-, Cu, Ni and Zn, whereas WD needs improvement in temperature, TDS, NO3-, Cr, Cu, Fe, Mn, Ni and Zn concentration for better fish growth. Most of the parameters are high in summer as compared to winter, which is due to the dilution after rainfall. Hence, we recommend timely action for effective measures to improve the water quality of wetlands and their regular monitoring for improved fish habitat.
Показать больше [+] Меньше [-]Assessment of Groundwater Based Public Drinking Water Supply System of Kamrup District, Assam, India using a Modified Water Quality Index Полный текст
2021
Goswami, Jayanta | Bhattacharjya, Rajib Kumar
This work aims to assess the Water Quality Index (WQI) of the groundwater-based public drinking water supply system of Kamrup District (Rural) of Assam, India. For assessing WQI, water samples have been collected, both raw water and treated water, from seventy-eight public drinking water supply projects over the district for comprehensive physicochemical analysis. The WQI was calculated based on the weightage derived from the literature survey and based on the doctors’ weightage. The derived WQI showed that the water quality falls from poor to very poor quality. However, the concentration of the water quality parameters except Iron, Fluoride, and Manganese are within the permissible limit in all the water supply projects. It shows that the WQI calculated based on the weightage derived, as stated above, is not displaying the actual water quality of the supplied water. As such, a modified method is proposed to calculate the WQI of the supplied water considering the permissible limit of the parameters in deriving the weightage for the parameters. The WQI values calculated using the modified method falls in the range of good water quality to poor water quality and shows the true water quality of the supplied water. The statistical analysis of the water quality parameters and WQI shows that the WQI has a very high correlation with Manganese with a coefficient of correlation value of 0.86, followed by 0.4 with Chloride and 0.34 with Fluoride.
Показать больше [+] Меньше [-]Assessment of water quality of Oum Er Rabia River by Microbiological Quality Index and Water Quality Index Полный текст
2021
Abba, El Hassan | Idrissi, Imam | Bennani, Younes | El Yaacoubi, Adnane | Cherroud, Sanae | Ainane, Tarik | Khaffou, Mhamed
Water resource management requires simple tools to enable managers to make decisions. This is the case for water quality indices that provide access to clear, synthetic and well-targeted information. In this study, we have chosen two indices based on two different approaches, the Microbiological Quality Index (MQI), which is determined from bacteriological analyses of water, and the Water Quality Index (WQI), which is based on physicochemical parameters. The Water Quality Index (WQI) shows a longitudinal upstream-downstream variation and ranges from is between five (5) (Null Faecal Contamination) at sampling point P1 and 3.4 (Moderate Fecal Contamination) at P2. The Water Quality Index (WQI) ranges from a low of 14.08 (excellent water quality) at the P1 level to a high of 93.05 at the P2 level (poor water quality) receiving wastewater discharges. The WQI results for P3 and P4, show that the water is of good quality (downstream of P2), which shows the degree of self-purification of the Oum Er Rabia River, regardless of the sampling period. Finally, the results of the MQI corroborate those obtained with the WQI for the water quality of the different sampling points.
Показать больше [+] Меньше [-]Promising Potential of Electro-Coagulation Process for Effective Treatment of Biotreated Palm Oil Mill Effluents Полный текст
2021
Tahreen, Amina | Jami, Mohammed Saedi | Ali, Fathilah | Yasin, Nik Mohd Farid Mat | Ngabura, Mohammed
The critical parameters namely initial pH, time and current density largely impact the process efficiency of electrocoagulation (EC). Few works have been done on observing the interaction of these critical parameters and the possible combined effect on the overall pollutant removal efficiency. Therefore, the knowledge of the combined effect of critical parameter interaction would enhance the optimization of EC parameters to attain maximum efficiency with limited resources. Using aluminium electrodes with interelectrode distance of 10 mm on synthetic wastewater, representing biotreated palm oil mill effluent (BPOME), with a set range of initial pH, current density, and time of 3-8, 40-160 mA/cm2 and 15 to 60 minutes, respectively, the effect of the three critical variables was investigated. The optimum Chemical Oxygen Demand (COD) removal of 71.5% was determined at pH 6, current density of 160 mA/cm2 (with current 1.75 A) at EC time of 15 minutes. The experiment was validated with real BPOME, resulting in the removal efficiency of 60.7 % COD, 99.91 % turbidity, 100 % total suspended solids (TSS) and 95.7 % colour. Removal of a large quantity of pollutants in a time span of 15 minutes with optimized parameters in EC is notable for a wastewater treatment alternative that requires no extensive use of chemicals. The interaction of parameters observed in this study indicated a synergistic contribution of initial pH and current density in removing maximum wastewater COD in 15 minutes of EC.
Показать больше [+] Меньше [-]Investigation of Suspended Particle Concentrations (PM10, PM2.5, TSP) in Tehran Subway Line one Stations in the Spring and Autumn Полный текст
2021
Mousavi Fard, Zahra Sadat | Asilian Mahabadi, Hassan | Khajehnasiri, Farahnaz
Today, indoor air pollution is a major concern. So far, many quantitative and qualitative studies have been conducted on particulate matter pollution in closed environments, but not much research has been done to measure air pollution in subway station. In this study, we have investigated the concentrations of PM10, PM2.5 and TSP particles in 12 underground stations on the oldest and main Tehran metro line, in two seasons, autumn and spring. For sampling suspended particles, we have used a portable direct reading device for monitoring suspended-particles (HAZDUST EPMA5000). We also used Pair T- test to compare the particle concentrations in different modes of the ventilation system (on, off, and inlet air) and Three-way variance analyze. According to the results, the mean concentrations of PM2.5-PM10 - TSP values in line-1 on the station platforms are significantly higher in spring than in autumn, off state of the ventilation system than on state of the ventilation system (P <0.001). Also, the concentration of particles measured in the air of subway stations is higher in the off state of ventilation systems, compared to Inlet air to stations (P<0.001). There is a correlation between concentration of particles measured in different sampling season, condition of the ventilation mode (on, off, inlet air) (P<0.001). Improving the efficiency of ventilation systems (equipped with a suitable filter) and fan in stations is suggested as one of the factors to reduce the concentration of particles, especially in spring.
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