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Cold plasma Technology for Removal of Endotoxin from Dialysis Water
2023
Fakhri Jasim, Shaimaa | Raad Humudat, Yasamen | Awad Kadhim, Suadad
Cold plasma has emerged as a powerful energy-efficient and environmentally friendly advanced oxidation technique in recent decades as a non-thermal approach in a wide range of applications. It is a form of plasma that is created at low temperatures and can be used for various applications, including water treatment This study aims to determine the influence of Cold plasma treatment on endotoxin reduction in dialysis water. A lab-scale unit was built to implement the experiments and synthetic water (feed solution) was prepared with a known level of endotoxin (0.48 EU/mL). The test for Limulus amebocyte lysate was used to assess concentrations of endotoxin in treated water. The experimental results showed reduce of endotoxins in the cold plasma treatment. This type of treatment reduced the concentration of endotoxin to 0.17 ± 0.09 EU/ml. The results of the study indicated that this could be an innovation in cold plasma jet fields, with numerous applications in dialysis fluid preparation.
Показать больше [+] Меньше [-]Investigating the Impact of Virtual Education on Air Pollution Indicators in Tehran during the COVID-19 Outbreak
2023
Omidifar, Reza | Mazari, Ebrahim | Ostadalidehaghi, Rezvan
This research aims to investigate the effect of virtual education during the COVID-19 outbreak on air pollution indicators in Tehran. The study uses quantitative methods, including One-Way ANOVA, to analyze the air pollution indicators before and during the COVID-19 pandemic. Data on air pollution indicators in Tehran from 2018, 2019, and 2020 were collected from Tehran Air Control Company and compared using statistical tests. The year 2019 represents virtual education, while 2018 and 2020 represent face-to-face education. The examined indicators include particulate matters with a diameter less or equal than 2.5μ (PM2.5), SO2, NOX (i.e., NO2 and NO), O3, and CO. The results of variance analysis show significant differences in the PM2.5and NOX indices between virtual and face-to-face training days. Follow-up tests by Toki and Scheffé indicate that in 2019, when education was fully virtual, the levels of these pollutants were lower compared to 2018 and 2020. However, there were no significant differences in the SO2, O3, and CO indices during the days of virtual education compared to the years before and after. This suggests that virtual education during the COVID-19 outbreak contributed to pollution reduction by reducing traffic to educational organizations and its indirect effects.
Показать больше [+] Меньше [-]Geotechnical Investigation of Tailings Disposal Site for Tailings Storage of zinc Processing Factory
2022
Shirdam, Ravanbakhsh
The present study aims at determining the geotechnical properties of the tailings and the natural bed at Iran Mineral Processing Company, Sites 1 and 5. It qualitatively studies the subsurface layers of the company’s tailings storage site. After drilling different boreholes and conducting in-situ tests, it has made laboratory analyses in the form of field exploration to determine the geotechnical parameters of the extracted samples. Results from the analyses show the permeability coefficient of the subsurface layer of Site No. 1 and 5 to be very small, in the range of 10-7 cm/sec. Considering the conformity of permeability coefficient, percentage of fine grains (98% to 99%), plasticity index (28.5-29.5), and clay content of different layers of Sites 1 and 5 (68%-80%), based on the compacted clay liner criteria, it can be concluded that by nature, the subsurface layers of the mentioned sites are sealed with no need for any compacted clay liner. The tailings for storage Site 5 are fine-grained (80-88<75mm), basically in ML range according to USCS system, with a permeability coefficient of about 10-6 cm/sec. Therefore, the tailings themselves act as a relatively primary sealing layer against the infiltration of hazardous leachates into the natural bed. The method, used in the process of site selection of tailings storage facilities (TSF), can cut the construction time as well as the expenditures, thus reducing the production costs in the long run.
Показать больше [+] Меньше [-]Determination of Dioxins and Polychlorinated Biphenyls Levels in Milk Samples from Capital and North of Iran
2022
Azarchehry, Seyede Pegah | Ataie, Farangis | Hosseinkhani, Saman
High levels of dioxins and dioxin-like compounds in the food and their adverse effects on human health are of increasing concern. Since milk is one of the most essential human nutritional resources, the present study aims at determining dioxins and PCBs in raw milk samples from four farms in North of Iran and raw and pasteurized samples from three farms and five dairy factories in Vicinity of Tehran (capital of Iran). Total toxic equivalence (TEQ) of dioxin and PCBs have been determined, using the DR-CALUX® bioassay. Results reveal that all samples are contaminated with dioxins and PCBs, comparatively. The total dioxins and PCBs levels in raw milk samples from the north range from 4.08 to 0.97 pg/gfat and for the raw samples and pasteurized samples from Tehran Province from 1.89 to 0.63 pg/gfat and 0.1 to 0.03 pg/gfat, respectively. The mean concentration of dioxins/PCBs is higher in samples from the north of Iran. This may be because of the common method of removing domestic and agricultural disposal in this area.
Показать больше [+] Меньше [-]Presence of Microplastics in Freshwater Ecosystems: An Unheeded Emerging Concern – A Global Review
2022
Mukhopadhyay, Patralika | Arkkakadavil Valsalan, Shibu
Plastic production has inevitably increased in the past few decades and is one of the diverse material used in today’s world. With this increasing production and wider use, the aquatic ecosystems have become the trash barrel for all kinds of plastic resulting in it becoming a looming spectre to the habitat and functions of both inland and offshore ecosystems. Plastic pollution is considered as an emerging global environmental concern which could significantly affect the biological diversity and may have potential to cause inimical effects on human health. These plastics have shown to gradually degrade into micro fragments and are reported to cause toxic effects on the aquatic organisms. In comparison to the studies on presence of microplastic in marine ecosystems, the studies on the presence of it in freshwater ecosystems have received relatively lesser attention although some studies have shown that the contamination is as grievous as that of in marine environment. This review article focuses on the literature available on the reports of microplastic occurrence, its distribution in freshwater ecosystems across the world and its insidious effects which are of emerging concern. The effect of such microplastic ingestion in both aquatic organisms and the potential health hazards due to such plastic consumption in humans have also been examined. The paper also discusses the existing knowledge gaps so that future research directions can be taken accordingly and the findings in this paper would significantly help all the countries across the world to understand the present plastic pollution scenario and work towards the mitigation of the same.
Показать больше [+] Меньше [-]Radiological Hazards Associated with 238U, 232Th, and 40K in some selected Packaged Drinking Water in Ilorin and Ogbomoso, Nigeria
2022
Ajibola, Taiye Benjamine | Orosun, Muyiwa Michael | Ehinlafa, Olusegun Emmanuel | Sharafudeen, Fatimah Anike | Salawu, Banji Naheem | Ige, Simon Olatunji | Akoshile, Clement O.
In order to ensure radiation monitoring and protection, investigation and assessment of radiological risks that may be associated with the consumption of packaged table waters commonly consumed in Ogbomoso and Ilorin metropolis, Nigeria, was carried out. The measurements were carried out using a ‘3 x 3’ inch lead-shielded NaI (Tl) detector coupled through coaxial cable to a multichannel analyser. The measured activity concentrations of the natural radionuclides in the packaged drinking water sample are mostly within the recommended limits. The estimated mean Annual Effective Dose was found to be within the acceptable limits of 1 mSv/y for the general populace except for the infants which is slightly higher for some of the samples. The estimated Excess Lifetime Cancer Risk were found to be lower than the world average value of 0.2 x 10-3 in only two of the selected packaged drinking water. This implies the possibility of developing cancer over a lifetime considering seventy years as the average life span is considerably high.
Показать больше [+] Меньше [-]Biosorption of Chromium by Fungal Strains Isolated from Industrial Effluent Contaminated Area
2022
Narolkar, Swati | Mishra, Arvnabh
The ability of fungi to act as bio-sorbent had been extensively evaluated and has shown excellent metal sequestering ability for heavy metals such as cadmium, copper, zinc, lead, iron, nickel, radium, thorium, and uranium from aqueous solution. In the present study, tolerance, removal efficiency and adsorption capacity of hexavalent chromium using isolated fungal strains were analysed. Total nine fungal isolates were obtained from organic pollutants and metals contaminated Gujarat Industrial Development Cooperation sites. Filamentous fungi isolated belonged to Aspergillus spp., Rhizopus spp., Trichoderma spp., and Penicillium spp. Chromium sorption experiments using isolated fungal strains were carried out to check adsorption capacity and adsorption intensity. At higher chromium concentration, removal efficiency and adsorption capacity were observed in the order of Aspergills candidus > Aspergillus ochraceus > Aspergillus flavus > Rhizopus spp. > Trichoderma spp. A. candidus showed higher adsorption capacity, 5.49mg/g with 98.75% chromium removal efficiency at 150ppm of hexavalent chromium. The observed RL value for Langmuir isotherm for all the three concentrations was less than 1, depicting favourable sorption and in Freundlich isotherm, the value of 1/n exceeds more than 1 showing co-operative or similar type of adsorption.
Показать больше [+] Меньше [-]Atmospheric Aerosol Loading and Properties over India: A review
2022
Mor, Vikram | Dhankhar, Rajesh
Atmospheric aerosols are very crucial from air pollution and health perspective as well as for regional and global climate. This paper attempts to summarize the aerosol loading and their properties such as Aerosol Optical Depth (AOD), Single Scattering Albedo (SSA), Angstrom exponent, and Radiative forcing, over India. All the above mentioned parameters have shown significant variability with change in the site and season. From various studies it was observed that AOD is relatively higher over Northern part of India as compared to Southern and Eastern part. Generally, lower values of SSA were observed over all sites during winter and post-monsoon seasons which indicates the dominance of absorbing type aerosol during these seasons. Also the ARF within atmosphere showed comparatively higher values during November-December and lower value during August and September all over the India. The current state of knowledge about aerosol sources, interactions and their effects on environment is limited because of its complexity. Therefore, more focused research in needed to understand the aerosol’s role in climatic phenomenon.
Показать больше [+] Меньше [-]A Preliminary Study on Mercury Contamination in Artisanal and Small-Scale Gold Mining Area in Mandalay Region, Myanmar by using Plant Samples
2022
Kuang, Xiaoxu | Kyaw, Win Thiri | Soe, Pyae Sone | Thandar, Aye Myat | Khin, Hnin Ei | Zaw, Nan Myat Pyae | Sakakibara, Masayuki
A large anthropogenic source of mercury pollution is mercury-dependent artisanal and small-scale gold mining (ASGM). Thabeikkyin Township is a small-scale gold mining township located in Pyin Oo Lwin District in the Mandalay Region, Myanmar. The villages of Thabeikkyin Township engage in gold ore crushing, screening, refining, and other mining activities for a living. Miners in this area commonly use mercury for gold recovery by heating amalgam at their homes, gold shops, on the street, and near the riverbank. The evaporated mercury is released into the atmosphere during the heating process and then transported and deposited in the surrounding environments, resulting in the mercury pollution of air, water, soil, etc. To assess atmospheric mercury pollution, a preliminary study on the environmental mercury contamination from ASGM was conducted in Thabeikkyin Township. High mercury concentrations were observed in plant samples collected near the refining sites, ranging 0.33–6.51 ug/g, compared with 0.02 ug/g in Wet Thay Village, where no mercury use was reported. Correlation coefficients between Hg and other heavy metals showed that no heavy metal concentration significantly correlated with that of Hg. The results indicated that the atmospheric environment in the ASGM area of Thabeikkyin Township was contaminated with mercury originating from ASGM, which could very likely deteriorate the health of surrounding residents.
Показать больше [+] Меньше [-]Environmental Performance of Alternative Schiff Bases Synthesis Routes: A Proposal for CO2 Storages
2022
Yaseen, Anahed A. | Yousif, Emad | Al‐Tikrity, Emaad T. B. | Kadhom, Mohammed | Yusop, Muhammad R. | Ahmed, Dina S.
The increased consumption of fossil fuels provokes high levels of carbon dioxide (CO2) emissions, which give rise to serious environmental issues. Accordingly, designing and utilizing new classes of materials, such as Schiff bases, to capture CO2 gained significant attention from researchers worldwide. In the present work, two Schiff bases were synthesized and examined as storage materials for carbon dioxide gas. The prepared compounds were obtained by reacting trimethoprim with two aldehydes severally (benzaldehyde and parabromobenzaldehyde) in boiling methanol. The surface morphology of the compounds was investigated via field emission scanning electron microscopy (FESEM). The Brunauer-Emmett-Teller (BET) test showed that Schiff bases 1 and 2 have surface areas of 17.993 and 2.732 m2/g, pore volumes of 0.008 and 0.005 cm3/g, and pore diameters of 17.02 and 74.89 nm, respectively. Reasonable uptake values of CO2 (31.36 cm3/g, 6.2 wt%) and (25.30 cm3/g, 5.0 wt%) were achieved by the prepared Schiff bases 1 and 2, respectively, at 313 K temperature and 40 bars pressure.
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