In Shanxi, a major energy province in China, environmental pollution caused by coal gangue accumulation is becoming an increasingly serious problem. In addition, crops are the first trophic level in the human food chain, and the security and production of crops are closely related to human well-being. The objective of this study was to estimate the phytotoxicities of agricultural soil samples contaminated by coal gangue accumulation using maize (Zea mays L.) as a model organism. Finally, a tolerant maize cultivar was screened for coal gangue stacking areas. Seven cultivars of maize seeds were treated with agricultural soil leachate around the coal gangue stacking area at various concentrations of 0, 1:27, 1:9, 1:3, and 1:1. The results revealed that the agricultural soil leachate treatment could inhibit seed germination and the growth of roots and shoots and that the soil leachate-induced phytotoxicities were cultivar-dependent. At the same exposure concentration, tolerant maize cultivar displayed lower toxicity symptoms than sensitive maize cultivar in terms of growth inhibition, oxidative damage, and DNA damage. Stronger activities of antioxidant enzymes were observed in the tolerant maize cultivar than in the sensitive maize cultivar, indicating that the difference between cultivars in antioxidant capacity is one reason for the difference in plant tolerance. Our study provides experimental evidence for the ecological risk assessment of soil and the selection of maize cultivars with high environmental pollutant tolerance for use in coal gangue stacking areas.

The purpose of this study was to evaluate the short-term irrigation effect with industrial poultry wastewater on young olive trees (Olea europaea L. cv. Chemlali). Industrial poultry wastewater can be considered as a bio-fertilizer due to its richness in nutritive elements (SO₄²⁻, HCO₃⁻, total nitrogen, and K⁺). The physicochemical analysis of wastewater showed a high concentration of TSS, COD, BOD, COT, NO₃⁻, and conductivity. Measurements indicated that poultry wastewater enhanced plant growth, leaves dry matter, and ashes in comparison with tap water, as well as poultry wastewater diluted with tap water; however, a decrease in total soluble sugars (glucose and fructose) was detected in leaves. The determination of fatty acid profile of young olive trees leaves irrigated with poultry wastewater showed richness on saturated fatty acids in comparison with mono- and poly-unsaturated ones. In addition, oleic acid (C₁₈:₁) presented the lowest content in leaves of trees irrigated with poultry wastewater irrigation. According to those results, poultry wastewater lends itself to being a hydric alternative and at the same time a source of nutrients that can help fill the water deficit in semi-arid countries and avoid costly waste disposal for slaughterhouses.

The present study aimed to explain the mechanisms involved in cell-mediated immunotoxicity of atrazine (ATR) in rabbits and to evaluate the ameliorative role of glycyrrhizic acid (GA) against such toxic effects. Forty rabbits were assigned into 4 equal groups: control, ATR, GA, and ATR + GA groups. ATR (2475 ppm) and GA (60 μg of GA/ml of water) were administrated via food and drinking water, respectively, for 60 consecutive days. The cell-mediated immunotoxicity of ATR was clarified by the induced thymus immunotoxicity through downregulation of interleukin (IL)-9 gene and interferon-γ (IFN-γ) gene expression, upregulation in caspase-3, and significant decrease in the total leukocytic and lymphocyte counts. Histopathological investigations demonstrated severe depletion of lymphoid follicles in the medulla of the thymus gland. On the other hand, co-administration of GA for group 4 improved most of the undesirable impacts of ATR. In conclusion, the alteration in IL-9/IFN-γ expression may involve ATR-induced thymocyte apoptosis which may explain the mechanisms of ATR-induced cell-mediated immunotoxicity with a possible amelioration influence of GA administration.

Cigarette butt (CB) is a crucial litter in urban communities because it may contain various toxicants. Due to serious limitations on incinerating or landfilling CB, recycling of this hazardous waste is essential. The objective of this study was to investigate the most important challenges in CB collection and recycling. To this end, a search was done on Scopus, PubMed, and Web of Science by defining a search protocol and identifying appropriate keywords. At the end of the screening process, 52 appropriate papers were selected. In this review, all methods for the CB recycling were considered. This review showed that nine categorizations of different products have been produced from the recycling of CBs, but three important challenges were identified for the recycling of this hazardous waste. It should be noted that finding solutions to these challenges may be helpful in better management of CB as a toxic litter.

Carbon neutral is among the possible ways of solving the problem of climate change. Many scholars have utilized different single indicators such as CO₂ and methane with different variables to mitigate the possible ways of solving the problem of global warming. The present study employs a specific country (UAE) approach to investigate the possible way of solving climate change. The author utilized 1980–2018 annual data of the UAE to investigate the possibility of carbon neutral in the UAE as to suggest ways of limiting climate change. Both linear and non-linear (squared) foreign direct investment (FDI) and GDP per capita were added to the study and considered as the variables of interest and other control variables (energy use and population). Among the findings of this study are inverted U-shaped relationship between economic growth (GDP per capita) and ecological footprint which confirms EKC for the UAE, positive relationship between energy use and ecological footprint, negative relationship between FDI and ecological footprint in all stages which established a flat pattern of relationship, and a positive relationship between the population and ecological footprint. Findings from causal analyses exposed a two-way direction or feedback (bidirectional) between economic growth (GDP) and urban population, and between energy use and urban population both in the short and long run. Also, a one-way transmission (unidirectional) is found transmitting from ecological footprint and FDI to population both in the short run and long run; from the ecological footprint, energy use, and FDI to economic growth; from the ecological footprint and FDI to energy use in the long run; and from ecological footprint to FDI and energy use in the short run. The policy focus should be towards the improvement on the urban population. FDI pattern suggests the pollution halo hypothesis which is a pointer towards its (FDI) crucial contribution to environmental performance. Hence, FDI should be encouraged through relaxing of some laws that are preventive in nature towards FDI so as to maintain this positive trend towards sustainable development. The analytical abstract demonstrates the interactions that exist among the employed variables in Granger causality analysis. The big arrows denote two-way transmission while the small arrows show one-way causal transmissions passing to the variables where they are pointing at.

In order to improve and establish the localized source profile of PM₂.₅ in Fuxin, the ashes under dust catcher were collected from four typical coal-fired power plants in Fuxin and twenty-eight components were measured. The source profile of PM₂.₅ in the soot of the four coal-fired power plants was established. SO₄²⁻ was the most abundant component in the PM₂.₅ of the soot of the four coal-fired power plants, followed by Ca²⁺ and organic carbon (OC). The content of element components in PM₂.₅ smoke ranges from 5.06 to 10.97%, the content of ionic components ranges from 36.53 to 48.59%, and the total carbon content ranges from 9.43 to 11.36%. The divergence coefficient of PM₂.₅ source profile in Fuxin coal burning smoke is mostly similar to that of Fushun, whereas the divergence coefficient of Colorado reaches 0.65, indicating that Fuxin coal burning power plant smoke has no similarity to Colorado. The order of the geological accumulation index of Ni, Cu, V, Mn, and Cr was Cr (4.58) > Mn (4.42) > V (4.38) > Cu (4.09) > Ni (4.06), showing a heavy pollution level. The health risk assessment model recommended by the USEPA was used to assess the health risk of heavy metals in soot of coal-fired power plants, and the non-carcinogenic risk values of As for children and adults were 45.7 and 4.90, respectively. The carcinogenic risk values of Cr for adults and children were the highest, with values of 3.66 × 10⁻⁵ and 2.06 × 10⁻⁵, respectively, followed by As.

Anaerobic digestion is a possibility for post-hydrothermal liquefaction wastewater (PHWW) treatment because this wastewater is rich in nutrients and organic compounds. However, the PHWW presents many toxic compounds. A strategy for the anaerobic treatment of toxic compounds is using biomass adhered to inert supports forming biofilms, which can offer more resistance to the microorganism and protection from such compounds. The continuous treatment of PHWW is the essential key to obtaining a sustainable hydrothermal liquefaction process. In this work, the use of immobilized biomass was evaluated for the anaerobic degradation of PHWW from Spirulina in batch assays and continuous treatment. Higher methane production potential and volatile fatty acid mass balance showed the advantages of using biomass immobilized in polyurethane foam. Continuous treatment in a horizontal-flow anaerobic immobilized biomass (HAIB) reactor reached chemical organic demand (COD) removal efficiencies of 67% and 58% for volumetric organic load rates of 0.8 and 1.6 g COD.L⁻¹.d⁻¹, respectively. After 200 days of continuous treatment, Anaerobaculum and Coprothermobacter, fermentative proteolytic genera of bacteria with potential for hydrogen production, were favored.

The tolerance of Mentha crispa L. (garden mint) cultivated in cadmium-contaminated oxisol for 120 days was analyzed using plant growth variables such as height, the number of leaves and shoots in different Cd exposure periods, as well as assessing the metal concentration absorbed and accumulated in the plant parts (root, stem, and leaves). The maximum adsorption capacity was estimated at 9220 mg kg⁻¹ and used as a reference to establish the different Cd concentrations to be applied in the soil. M. crispa showed tolerance and revealed a reduction of height, the number of leaves and shoots, root development, and secondary toxicity signs such as chlorosis and leaf wilting. Comparing to the stems and leaves, Cd was retained mainly in the roots. PERMANOVA showed that plant growth variables and Cd concentrations in the plant’s part were affected by the Cd exposure time. The canonical discriminant analysis demonstrated height as the most affected variable until 45 growing days, and different responses were observed after 75 days. However, the number of shoots was the variable most affected by higher Cd concentrations. The bioaccumulation and translocation factors for all treatments were lower than one, indicating that M. crispa can be considered as an excluder plant and applied for a phytostabilization strategy.

The study was conducted to explore the influence of geomorphic features scattered throughout the area on the occurrence and distribution of arsenic in shallow groundwater. GIS techniques were frequently used to identify the geomorphic features and to correlate with arsenic distribution patterns. The study shows that the occurrence of geomorphic features and their distribution have a vital role in the heterogeneous distribution pattern of arsenic in shallow groundwater. The frequency distribution of geomorphic features is found similar to the arsenic distribution pattern. The moderate to highly contaminated zones are mostly consolidated to the central and southeastern part of the study area. Arsenic contamination levels are varying in different fluvial plains of the study area following the trend of Older Deltaic Plain (ODP) > Older Flood Plain (OFP) > Active Flood Plain (AFP). It has also been observed that arsenic contamination along the different geomorphic features follows the trend of abandoned channels > back swamps > other water bodies > swamps > cut-off meanders > meander scars > ponds > oxbow lakes > channel bar > point bars >channel islands. The present study indicates that the geomorphic features play a significant role in the mobilization of arsenic in shallow groundwater by supplying accumulated organic matter.

Soil erosion and runoff of cultivated land will cause farmland to be degraded and the downstream to be contaminated, which has aroused extensive attention worldwide. The conventional soil loss prediction model revised universal soil loss equation (RUSLE) is capable of more significantly simulating and predicting the amount of soil loss, but this model often cannot achieve the satisfied prediction accuracy when the rainfall distribution of 1 year is significantly inconsistent with the annual distribution law. In this study, the 3-year field experiments were performed in Jilin, China. Besides, an improved revised universal soil loss equation (IRUSLE) was provided with a novel vegetation cover and management factor (C). It considered the interaction between rainfall distribution and normalized difference vegetation index (NDVI) by theoretical analysis and the genetic algorithm. It was reported that IRUSLE model can achieve more effective simulation result than RULSE model, as well as laying a theoretical basis for soil loss prediction.