Wet deposition fluxes of organochlorine pesticides (OCPs) were determined for rain samples collected in a coastal area of Turkey. Seventeen precipitation samples were collected over a 1-year period from 2008 to 2009. Rainwater was accumulated at the beginning of rain events using real time monitoring. Atmospheric concentrations were also measured in parallel with deposition samples. Both atmospheric concentrations and deposition fluxes were determined as particle and gas phases. The particle phase and dissolved phase deposition fluxes were 794.26 ± 756.70 ngm⁻² day⁻¹ and 800.77 ± 672.63 ngm⁻² day⁻¹, respectively. The washout ratios for OCP compounds were calculated separately for the particle and dissolved phases using the atmospheric concentrations and rain concentrations. The minimum washout ratio for the particle phase was 2339.47 for Endrin aldehyde, whereas the maximum washout ratio was 497593.34 for Methoxychlor. The maximum washout ratio for the dissolved phase was 247523.89 for Endosulfan beta, whereas the minimum washout ratio was 10169.69 for p,p′-DDT. The dry deposition velocities ranged from 0.01 to 1.67 cms⁻¹. The partitioning of wet deposition between the particle and dissolved phases was 50 % in terms of total OCP deposition.

Oil fly and boiler ash samples were collected from the four major Egyptian power plants in order to determine their natural radioactivity. Secular equilibrium between ²³⁸U and ²³²Th and their decay products is significantly disturbed in oil ash samples. The ²²⁶Ra/²³⁸U ratios were between 440 and 1993 with an average value of 801, indicating that the concentrations of daughters ²²⁶Ra were very high compared to the parent ²³⁸U in the oil ash samples. While, the average ratios for ²¹⁰Pb/²²⁶Ra in most samples were 1.19 ± 0.05, indicating a secular equilibrium in the ²²⁶Ra–²¹⁰Pb sub series. The natural radioactivity due to ²³⁸U and ²³²Th was found to be negligible. While the activity concentrations of ²²⁶Ra ranged from 3205 to 12,320 Bq kg⁻¹ with an average value of 9284 Bq kg⁻¹, ²¹⁰Pb ranged from 5960 to 13,930 Bq kg⁻¹ with an average value of 11,513 Bq kg⁻¹. The results are compared with the reported data from other countries. The average value of radium equivalent activity was 9308 ± 2729 Bq kg⁻¹, while the external and internal hazard indexes were found to be 25 ± 7 and 50 ± 15, respectively. All the studied radiological parameters were higher than the recommended limit by the IAEA in all ash samples.

To examine the differences in root morphological responses of soybean cultivars with different cadmium (Cd) tolerance and accumulation to Cd stress, the biomass, Cd concentration, and root morphological features of five soybean cultivars were determined under 0, 9, 23, 45, and 90 μM Cd stress via hydroponic experiments. Significantly genotypic differences in Cd tolerance and Cd concentration were observed between five soybean cultivars at four Cd levels. For Cd tolerance, HX3 showed a strong Cd tolerance with tolerance indexes of shoot biomass at 92.49, 76.44, 60.21, and 46.45 % after 18 days at four Cd levels, and others had similar weak tolerance at young seedling. For Cd accumulation, Cd concentration in roots showed far higher than that in shoots. The different accumulation features in roots and shoots among five cultivars were found at four Cd levels. Comparing with the control, the total root length (RL), root surface area (SA), and root volume (RV) of all cultivars were decreased significantly at four Cd levels. Tolerant cultivar HX3 had the largest root system and sensitive cultivar BX10 had the smallest root system at young seedling stage. Correlation analysis indicated that RL, SA, and RV were positively correlated with root biomass and shoot biomass under 9 and 23 μM Cd treatments, but root average diameter (RD) was negatively correlated with shoot biomass and root biomass only under 9 μM Cd treatments, while RL and SA were negatively correlated with root Cd concentration under 23 and 45 μM Cd treatments. The results suggested that root morphological traits were closely related to Cd tolerance at young seedlings under Cd treatments.

Wastewater treatment plant (WWTP) is considered to be an important medium for the transport and transformation of organic pollutants. This study attempted to comprehensively investigate polybrominated diphenyl ethers (PBDEs) and novel brominated flame retardants (NBFRs) in a WWTP in Harbin, one of the main “Old Industrial Base” in China. The mean concentrations of the total PBDEs in the influent, effluent, and sludge were 152 ng/L, 16.2 ng/L, and 503 g/g dw, respectively, which were at the low end of the global range. BDE-209 was the most abundant congener, with contributions to the total PBDE ranging from 90.5 to 98.5 %. The level of the total NBFRs ranged from 24.5 to 107 ng/L, 0.95 to 20.3 ng/L, and 305 to 1202 ng/g dw in the influent, effluent, and sludge, respectively. For NBFRs, DBDPE was the most abundant congener (38.8–50.5 %), followed by BEHTBP (11.0–35.0 %). The ratio for DBDPE/BDE-209 (0.62 ± 0.42) was found less than 1 in sludge, which indicated that Deca-BDE is still the major BFR product in this city. Source identification suggested that indoor dust should be an important source of BFRs in the WWTP. Approximately 20.8 and 7.79 kg of PBDEs and NBFRs on annual basis were removed with the sludge. Biodegradation could play an important role on the fate of BFRs in the WWTP, which is required for future research.

During the past decades, land use change has taken place around the Loess Plateau at unprecedented rates. Due to the impact of existing land use policy, great changes have taken place in the land use types in this ecologically vulnerable area. Taking eight counties in Yan’an, Shaanxi province, China, as the study area, this study analyzed the long-term (from 1997 to 2011) changes in land use and ecological vulnerability. Based on thematic mapper (TM) images of Yan’an in 1997, 2004, and 2011, the dynamic changes in land use are analyzed with the application software for remote sensing (RS) and geographic information system (GIS) since the implementation of the policy of returning farmland to forest. Combined with the land use data, the local socio-economic data, and natural resources condition, ecological vulnerability is evaluated using the spatial principal component analysis (SPCA) model in Yan’an region. Using the natural breaks classification (NBC), the evaluation results are divided into five categories: potential, slight, light, medium, and heavy. The results show that although the regional land use types changed markedly, the ecological vulnerability in the study shows greater than average optimism, and the ecological vulnerability index of the southern four counties is lower than that of the northern four counties. In 1997–2011, the eco-environmental quality gradually improved in most areas. However, it gradually deteriorated in some regions.

γ-Ferric oxide nanoparticles are synthesized through modern and facile ayurvedic route followed by normal and special purification steps, which are both cost-effective and eco-friendly. These synthesized γ-ferric oxide nanoparticles were applied on Solanum lycopersicum to search the effect on chlorophyll content. This process involves multiple filtration and calcination steps. The synthesized samples were analyzed by X-ray diffraction (XRD), UV-visible (UV-vis) spectroscopy, transmission electron microscopy (TEM), vibrating sample magnetometry (VSM), and particle size analysis (PSA) to identify the purification step’s influence on the structural, optical, morphological, magnetic, and particle size properties of ferric oxide nanoparticles (γ-phase). X-ray diffraction has revealed that ferric oxide nanoparticles have rhombohedral structure of α-phase (hematite) in initial purification process later transformed into cubic structure γ-phase (maghemite). UV-vis spectroscopy analysis has clearly shown that by repetitive purification steps, λₘₐₓ has increased from 230 to 340 nm. TEM result has an intercorrelation with XRD results. γ-Ferric oxide nanoparticles were tested on Solanum lycopersicum (tomato seeds). The changes in the contents of chlorophyll a, chlorophyll b, and total carotene were studied using spectral measurements at two different dosages—0.5 and 2 M. As a result, at 0.5-M concentration, magnetic nanoparticles exhibit fruitful results by increasing the crop yield and being more resistant to chlorosis.

The solar flat plate collector operating under different convective modes has low efficiency for energy conversion. The energy absorbed by the working fluid in the collector system and its heat transfer characteristics vary with solar insolation and mass flow rate. The performance of the system is improved by reducing the losses from the collector. Various passive methods have been devised to aid energy absorption by the working fluid. Also, working fluids are modified using nanoparticles to improve the thermal properties of the fluid. In the present work, simulation and experimental studies are undertaken for pipe flow at constant heat flux boundary condition in the mixed convection mode. The working fluid at low Reynolds number in the mixed laminar flow range is undertaken with water in thermosyphon mode for different inclination angles of the tube. Local and average coefficients are determined experimentally and compared with theoretical values for water-based Al₂O₃ nanofluids. The results show an enhancement in heat transfer in the experimental range with Rayleigh number at higher inclinations of the collector tube for water and nanofluids.

Aerosol composition and properties variation under the advection of different air masses were investigated, as case studies, by contemporary measurements over the atmospheric column and at the ground in a semi-rural site in South Italy. The absence of local strong sources in this area allowed to characterize background aerosol and to compare particle mixing effects under various atmospheric circulation conditions. Aerosol optical depth (AOD) and Ǻngström parameters from radiometric measurements allowed the detection and identification of polluted, dust, and volcanic atmospheric conditions. AODs were the input for a suitable model to evaluate the columnar aerosol composition, according to six main tmospheric components (water-soluble, soot, sea salt accumulation, sea salt coarse, mineral dus,t and biological). Scanning electron microscope (SEM) analysis of particulate sampled with a 13-stage impactor at the ground showed not only fingerprints typical of the different air masses but also the effects of transport and aging on atmospheric particles, suggesting processes that changed their chemical and optical properties. Background columnar aerosol was characterized by 72 % of water-soluble and soot, in agreement with ground-based findings that highlighted 60 % of contribution from anthropogenic carbonate particles and soot. In general, a good agreement between ground-based and columnar results was observed. Under the advection of trans-boundary air masses, water-soluble and soot were always present in columnar aerosol, whereas, in variable percentages, sea salt and mineral particles characterized both dust and volcanic conditions. At the ground, sulfates characterized the amorphous matrix produced in finer stages by the evaporation of solutions of organic and inorganic aerosols. Sulfates were also one of the key players involved in heterogeneous chemical reactions, producing complex secondary aerosol, as such clay-sulfate internally mixed particle externally mixed with soot chains.

Mercury contents in soil and olive tree leaves have been studied in 69 plots around three different source areas of this element in Spain: Almadén (Ciudad Real), Flix (Tarragona) and Jódar (Jaén). Almadén was the world’s largest cinnabar (HgS) mining district and was active until 2003, Flix is the oldest Spanish chlor-alkali plant (CAP) and has been active from 1898 to the present day and Jódar is a decommissioned CAP that was active for 14 years (1977–1991). Total mercury contents have been measured by high-frequency modulation atomic absorption spectrometry with Zeeman effect (ZAAS-HFM) in the soils and olive tree leaves from the three studied areas. The average soil contents range from 182 μg kg⁻¹ in Flix to 23,488 μg kg⁻¹ in Almadén, while the average leaf content ranges from 161 μg kg⁻¹ in Jódar to 1213 μg kg⁻¹ in Almadén. Despite the wide range of data, a relationship between soil–leaf contents has been identified: in Almadén and Jódar, multiplicative (bilogarithmic) models show significant correlations (R = 0.769 and R = 0.484, respectively). Significant correlations were not identified between soil and leaf contents in Flix. The continuous activity of the Flix CAP, which remains open today, can explain the different uptake patterns for mercury, which is mainly atmospheric in origin, in comparison to the other two sites, where activity ceased more than 10 years ago and only soil uptake patterns based on the Michaelis–Menten enzymatic model curve are observed.

The composition, seasonal variation, and potential sources of sulfate (S) and nitrogen (N) deposition in precipitation in the southwest of China from 2003 to 2013 were investigated. The results showed that the concentration of SO₄²⁻, NO₃⁻, and NH₄⁺ in rainwater were 10.57–1360, 7.16–523.71, and 7.54-1020 μeq l⁻¹, with an annual volume-weighted mean (VWM) concentration of 103.99, 46.73, and 97.30 μeq l⁻¹, respectively. The annual wet deposition of SO₄²⁻, NO₃⁻, and NH₄⁺ was 21.66, 8.16, and 17.49 kg S (N) ha⁻¹, respectively. The temporal variations of the ions showed that the abrupt decreasing breakpoints were in 2008 for SO₄²⁻ and in 2009 for NO₃⁻ and NH₄⁺, and increasing trends were observed after 2010 for the three ions. These trends reflected the effect of economy recession and the policy of controlling SO₂ and NOₓ emissions. The acid rain type of precipitation was shifted from sulfur to a mixed one. The ions of SO₄²⁻, NO₃⁻, and NH₄⁺ presented high values in winter and spring and low values in autumn and summer. A highly positive linear correlation between SO₄²⁻ and NO₃⁻ (R ² = 0.71), SO₄²⁻ and NH₄⁺ (R ² = 0.74), and NO₃⁻ and NH₄⁺ (R ² = 0.84) existed while a strong negative correlation was found between the three main ionic concentrations and precipitation. The SO₄²⁻ was mainly from fossil fuel combustion (60.53 %), aged sea salt (19.03 %), agriculture (11.38 %), crust (6.66 %), and biomass burning (2.40 %); the NO₃⁻ was mainly from fossil fuel combustion (75.41 %), biomass burning (9.67 %), aged sea salt (7.97 %), and agriculture (6.96 %); and the NH₄⁺ was mainly from agriculture (86.38 %), fossil fuel combustion (10.52 %), and aged sea salt (3.09 %).