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Corrosion Behavior of Petroleum Pipeline Steel in the Sulfur Ion Enriched Solution with Quinoline Полный текст
2023
Shanjian Li, Guotao Cui, Panfeng Wu and Yang Feng
Localized corrosion is a serious, hazardous destroyer of steel petroleum pipelines meant for long-time use. However, previous studies on localized corrosion primarily focused on local corrosion morphology and corrosion rate of bulk metals because detecting the corrosion state of occlusive metals is difficult. Herein, we employ a simulating occluded battery unit to disclose the local corrosion behavior of the steel petroleum pipeline (N80 steel) in an occlusive S2–-enriched solution. After simulating localized corrosion in the S2–- containing corrosion solution using the occluded battery unit, the occlusive solution was acidified and the migration amount of S2– to the occluded area increased. Despite the increase of S2– concentration, the addition of quinoline corrosion inhibitor (0.8 wt%) still effectively impedes the corrosion of the occluded metal. Moderately raising the environmental temperature can stimulate the activity of the inhibitor and promote the inhibition effect. The quinoline corrosion inhibitor displays the maximum inhibition rate at an elevated temperature of 50°C. Meanwhile, a maximum over the temperature of 60°C-70°C will likely accelerate the failure of the inhibitor.
Показать больше [+] Меньше [-]Groundwater Quality Assessment in Korba Coalfield Region, India: An Integrated Approach of GIS and Heavy Metal Pollution Index (HPI) Model Полный текст
2023
Vijayendra Pratap Dheeraj, C. S. Singh, Nawal Kishore and Ashwani Kumar Sonkar
The goal of this study was to examine the water quality for drinking and domestic purposes in the Korba coalfield region of Chhattisgarh, India. The Korba Coalfield region has seen the collection of fifteen groundwater samples from different places. The content of eight metals was determined using ICP-MS instruments: aluminum (Al), barium (Ba), cadmium (Cd), iron (Fe), magnesium (Mn), lead (Pb), nickel (Ni), and zinc (Zn). Spatial distribution maps were produced using GIS software to make it simple to understand the groundwater’s quality. The groundwater samples were collected during the pre-monsoon season and the amount of Al, Ba, Cd, Fe, Mn, Pb, Ni, and Zn exceeded the ideal drinking water standards in a few sites. The elevated metal concentrations in the study region’s groundwater could be hazardous to the quality of water. The HPI value based on mean concentration was calculated to be 21.64, which is significantly lower than the reference pollutant index score of 100. The HPI calculation revealed that 73.33% of groundwater samples had low HPI values, 6.67% had medium HPI values, and the remaining 20% had high HPI values. The correlation between heavy metals and HPI was calculated; HPI is positively correlated with Fe (r > 0.9471), Pb (r > 0.9666), and Zn (r > 0.9634), indicating that these elements contribute significantly more to heavy metal concentration in the various samples examined than the other selected elements. The box plot seems to be a graphical representation of the outcomes of the different parameter concentrations which show the mean, maximum, and minimum metal values. The cluster analysis was performed and it was classified into two clusters. Cluster-1 comprises 14 members (93.33%) of the water samples examined and is distinguished by relatively low Ba (<700 μg.L-1), pH, TDS, Al, Fe, Cd, Mn, Pb, and Zn concentrations. Cluster-II is made up of 1 member (6.67%), which is primarily made up of groundwater samples (GW-10) taken in the KCF region, India. High values of HPI are found in the eastern portion of Chhattisgarh’s KCF region, reflecting the spatial distribution of metals. Heavy metal leaching from open-pit mining and transit routes was observed to have contaminated groundwater in the eastern section of the research region.
Показать больше [+] Меньше [-]Spatial Distribution of PM10 and NO2 in Ambient Air Quality in Cape Town CBD, South Africa Полный текст
2023
O. Ndletyana, B. S. Madonsela and T. Maphanga
Fixed air quality monitoring stations generally monitor the air quality in developing countries. However, this practice, in addition to being costly, inherently contains drawbacks associated with the inability to capture the spatial distribution of air pollutants. Against this limitation, it is necessary to employ flexible and dynamic monitoring techniques that are fundamental and influential in comprehending the spatial distribution of pollutants. Because of this, in recent times, the application of GIS as a monitoring technique has proved to be more efficient than using fixed monitoring stations. Therefore, to this end, the current study mapped the spatial distribution of PM10 and NO2 pollutants in Cape Town CBD using the GIS technique. Subsequently, the GIS monitoring technique revealed that both pollutants had high spatial distribution between 2017 and 2018, irrespective of the season. Furthermore, high exposure concentrations of PM10 were generally observed across the CBD in contrast to NO2 exposure levels, which were relatively low. To contextualize the findings, compared with other studies, the current research discovered that spatial distribution of air pollution is associated with meteorological conditions, such as wind speed and temperature, that traditional techniques of monitoring exposure can’t capture.
Показать больше [+] Меньше [-]Impacts of microplastics and heavy metals on the earthworm Eisenia fetida and on soil organic carbon, nitrogen, and phosphorus Полный текст
2023
Mai, Huong | Thien, Nguyen Danh | Dung, Nguyen Thuy | Valentin, Christian
Microplastics (MPs) are increasingly being studied because they have become ubiquitous in aquatic and terrestrial environments. However, little is known about the negative effects of co-contamination by polypropylene microplastic (PP MPs) and heavy metal mixtures on terrestrial environment and biota. This study assessed the adverse effects of co-exposure to PP MPs and heavy metal mixture (Cu2+, Cr6+, and Zn2+) on soil quality and the earthworm Eisenia fetida. Soil samples were collected in the Dong Cao catchment, near Hanoi, Vietnam, and analyzed for changes in extracellular enzyme activity and carbon, nitrogen, and phosphorus availability in the soil. We determined the survival rate of earthworms Eisenia fetida that had ingested MPs and two doses of heavy metals (the environmental level — 1 × — and its double — 2 ×). Earthworm ingestion rates were not significantly impacted by the exposure conditions, but the mortality rate for the 2 × exposure conditions was 100%. Metal-associated PP MPs stimulated the activities of β-glucosidase, β-N-acetyl glucosaminidase, and phosphatase enzymes in soil. Principle component analysis showed that these enzymes were positively correlated with Cu2+ and Cr6+ concentrations, but negatively correlated with microbial activity. Zn2+ showed no correlation with soil extracellular enzyme activity or soil microbial activity. Our results showed that co-exposure of earthworms to MPs and heavy metals had no impact on soil nitrogen and phosphorus but caused a decrease in total soil carbon content, with a possible associated risk of increased CO2 emissions.
Показать больше [+] Меньше [-]Potassium Solubilizing Bacteria (KSB) and Osmopriming Mediated Morphological Changes and Triggers in Yield of Green Gram (Vigna radiata L.) Under Water-Limiting Conditions Полный текст
2023
A. Kalangutkar and A. Siddique
A field-based experiment was conducted to know the relevance of potassium solubilizing bacteria (KSB), and Osmo-priming mediated morphological changes and yielded recovery in green gram (Vigna radiata L.) under water-limiting conditions. Hence, the experiment was carried out at the research farm of Lovely Professional University. The characters like plant height, number of leaves, leaf area plant-1, and LAI were considered to track the morphological changes, while the primary branches, nodules, pods plant-1, seeds pod-1, the average length of the pod, test weight, biological yield, grain yield, and harvest index (HI) were used to determine the recovery of yield as compared to control. Among the treatments, T8 was recorded as one of the best treatments for all the morphological parameters studied, i.e., plant height (51.80 cm), number of leaves (42 plant-1), leaf area (577.27 cm2.plant-1) and LAI (1.92) while most of the yield contributing characters were found better in T6 i.e. nodules (8.3 plant-1), seeds pod-1 (10) and length of the pod (7.65 cm) except for the primary branches and the number of pods plant-1 which was remain recorded maximum in T8 (6.0 and 22). The yield of green gram and its biological yield were recorded as highest in T6 and T2 (6.83 and 24.23 g.plant-1), while HI and test weight were also noted in T6 (32.0% and 5.90 g). This study has concluded that the KSB, combined with KNO3, showed a strong potential to modify the morphological structure while the yield of green gram was in KSB + Ca(NO3)2 under water scarcity.
Показать больше [+] Меньше [-]Intellectual Property Rights Regime in Green Technology: Way Forward to Sustainability Полный текст
2023
Z. A. Khan and Shireen Singh
Climate change crises and environmental imbalances have been a significant concern globally in recent times. The climatic changes give rise to various issues such as global warming, depletion of the ozone layer, deterioration of natural resources, soil erosion, deforestation, and more. Many international and national agreements and policies have been created to protect the environment, from the UNFCCC to the recent Paris Agreement, aiming to control rising environmental issues. However, developed and developing countries must achieve desirable results in combating climate change. Industrial and technological developments are critical reasons for environmental pollution and degradation. Progress is necessary for planned developing countries, but growth and expansions shall also consider ecological sustainability. Technology shall be novel in adapting to the changes, considering the effects it can produce on the environment. Green technology combines technology with the environment, also called environmental technology, clean technology, or sustainable technology. It is a combination of science and technology together to mitigate climatic changes and protect the environment. Green technology is the modern sustainable solution to pressing environmental concerns. India is one of the countries globally showing rapid green technology developments. The authors of this paper have tried to highlight the dire need to modify technological developments vis-a-vis environmental sustainability to protect the environment. The research paper delves into and understands the interface between clean technology’s importance and relevance for ecological sustainability and the role of patent law, particularly in dealing with issues of the environment. The paper shall also establish a harmonious relationship between patent law and its role in ensuring environmental sustainability.
Показать больше [+] Меньше [-]Heavy Metal Remediation from Water/Wastewater Using Bioadsorbents - A Review Полный текст
2023
Akhil Tewari, Dinesh S. Bhutada and Vinayak Wadgaonkar
This paper aims to emphasize heavy metals’ impact on water and its removal mechanism with a focus on adsorption. Furthermore, factors affecting bio adsorption, such as temperature, pH, RPM, and initial heavy metal concentration, have been studied for different heavy metals and bioadsorbents. A comparison of their adsorption capacities and efficiencies has been made. This review reviewed different bioadsorbents for their suitability in removing cadmium, lead, and copper ions from water and wastewater, typically by using adsorption as a methodology. A suitable summary compares various heavy metal removal techniques and their advantages and limitations. For adsorption, the characteristics of bioadsorbents and their activation steps have been consolidated. Furthermore, the effects of operational parameters and adsorption mechanisms have been discussed in the review. Apart from assessing the suitability of bioadsorbent, a novel bioadsorbent has been suggested for copper ions removal. The findings shall be significantly useful in applying bioadsorbent in water/wastewater treatment fields to reduce heavy metal pollution. Thorough and well-planned research in this field can facilitate the creation of sustainable and durable technology for wastewater treatment, addressing the increasing demand for safe and dependable water resources, focusing on making it cost-effective and recyclable.
Показать больше [+] Меньше [-]Heavy Metal Contamination Assessment in Sediments, Soils and Surface Waters in Agriculture-Based Rural Chhattisgarh, India, and Evaluation of Irrigation Water Quality Полный текст
2023
Manash Protim Baruah, Subhajit Das, Monjil Rajkonwar and Mahesh Thirumala
Regional geochemical mapping was carried out in Bilaspur and Korba Districts of Chhattisgarh, and stream sediments/slope wash, soil, and water samples were analyzed for concentration of heavy metals. The study contributes to understanding heavy metals contamination of sediments, soils, and water due to anthropogenic activity, mainly in agriculture-based rural areas. The study reveals that high geochemical anomalies observed for heavy metals like Ni, Cr, As, and Zn in sediments and soil samples are due to the extensive uses of phosphatic fertilizer and soil amendments in the form of poultry and swine manure. Water quality assessment of major streams in the study areas shows that the water is suitable for domestic and agricultural uses. Correlation analysis reveals that the chemical weathering of rock-forming minerals doesn’t control the surface water chemistry of the study area and is also an anthropogenic source of sodium in water. This study also shows the importance of the country’s geochemical mapping database, which will have much broader applications than conventional mineral exploration and geological mapping.
Показать больше [+] Меньше [-]Assessment of SO2 Emissions from Cement Industries Utilizing Limestone with High Pyritic Sulfur Content: Case Study of Cement Plants in the Jaintia Hills District, Meghalaya, India Полный текст
2023
Arnab Mandal, M. K. Choudhury, Nazimuddin and Prashant Gargava
In properly operated Cement Plants, SO2 emissions are mostly caused by pyritic sulfur (sulfides) in the used limestones, accounting for approximately 85% of the raw mill in the plant. However, the pyritic sulfur content in limestones of the Jaintia Hills district of Meghalaya and their influence on the SO2 Emission from cement industries of Meghalaya have not been studied so far. The current study is conducted to perform an in-depth investigation of pyritic sulfur content in limestone reserves used by Meghalaya Cement Industries to assess the SO2 emission in the cement industries using high pyritic sulfur limestones and review the existing technology for the recommendation of the most suitable technology to minimize the SO2 Emissions. Random testing of collected limestone samples from various locations of Captive Mining sites in Cement Industries is performed to assess average pyritic sulfur concentration along different mining benches. Pyritic Sulfur Content (wt.%) in collected limestones varies from 0.15% to 3.5%. Polynomial Regression Analysis shows that Avg.SO2 Emission(Y) from Klin Stack can be represented as a function of pyritic sulfur content (X) (wt.%) of used limestones in the process: Y = 273.7X2 + 21.46X + 422.76. Based on the pyritic sulfur content in limestones, it is observed that “the more the Pyritic Sulfur content is, Darker the Limestone Samples are.” Hence, A Colour Scale has been prepared to visualize higher pyritic sulfur content in limestones. For longer-term sustainability, installing a Flue-Gas Desulfurization (FGD) unit at the kiln stack outlet may be included in the manufacturing process of cement plants to reduce the SO2 Emissions from Stack.
Показать больше [+] Меньше [-]Fuzzy Indicators of the Forecast of Environmental Safety Taking into Account the Impact of Natural and Technosphere Factors Полный текст
2023
Alexey Gordienko, Eduard Tshovrebov, Boris Boravskiy and Filyuz Niyazgulov
The emergence and uncontrolled development of environmental hazards in the processes of life in the absence of appropriate response measures in many cases leads to the emergence of man-made emergencies with dangerous consequences for public health and the environment. It is proposed to evaluate the results of complex monitoring and forecasting of these dangerous processes in a new format of creating a fuzzy scale of indicators of the level of environmental safety of life support of territories based on the theory of fuzzy sets. The study aims to develop a fuzzy scale of indicators for predicting the state of environmental protection. Protection of the population and territories from environmental threats and possible man-made emergencies. Within the framework of the purpose of the study, a fuzzy scale of threshold levels of environmental safety of territories and economic objects has been developed based on the theory of fuzzy sets and the mathematical apparatus of soft computing. The practical significance of the developments is confirmed by the successful application of the proposed scale of indicators and indicators in assessing the environmental hazard of life support systems of settlements and industrial enterprises affecting the environment.
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