The ability of vetiver grass (Chrysopogon zizanioides L.) for the reduction of anions and cations especially inorganic nitrogen compounds from the influent and effluent of sewages was investigated. Vetiver grass was grown hydroponically in influent (IN) and four different effluent (EF) sewages including control, 125 (EF125), 250 (EF250), and 500 (EF500) mg L⁻¹ Ca(NO₃)₂. During 18 days, phosphate concentration gradually declined in both influent and all effluent treatments. Unlike effluent treatments, the amount of ammonium in influent was greater than the standard (39.52 mg L⁻¹) and decreased severely down to 4.85 mg L⁻¹ at the end of the experiment. After just 48 h, the concentration of nitrate in EF treatment reached 2.25 mg L⁻¹ that is lower than the standard. The decrease of nitrate to concentrations less than the standard was also observed at days 8, 11, and 18 in EF125, EF250, and EF500 treatments, respectively, and about 90% of nitrate had been removed from 500 mg L⁻¹ Ca(NO₃)₂ treatment. Other ions such as Cl⁻, Ca²⁺, and K⁺ decreased in influent and all effluent sewages due to phytoremediation process. Accordingly, phytoremediation by vetiver grass could decrease concentrations of nitrate, ammonium, phosphate, chloride, and calcium in influent and all effluent sewages. Increasing the concentration of nitrate resulted in the increase in its uptake rate. In addition, a positive correlation was shown between the uptake rate of nitrate by vetiver grass and the duration of cultivation of this plant in nitrate-containing medium.

Coal fly ash (FA) is a solid waste produced in coal combustion. This study focused on the removal of Cd²⁺ from wastewater by a newly synthesized adsorbent material, the low-temperature and sodium hydroxide–modified fly ash (SHM-FA). The SEM and BET analyses of SHM-FA demonstrated that the adsorbent was porous and had a huge specific surface area. The XRF, XRD, FTIR and TGA characterization showed that SHM-FA has an amorphous structure and the Si–O and Al–O in the fly ash dissolved into the solution, which improved the adsorption capacity of Cd. The results indicated that SHM-FA has desired adsorption performance. The adsorption performance was significantly affected by the dosage, starting pH, Cd²⁺ initial concentrations, and temperature, as well as adsorption time. In the optimal conditions, the removal efficiency and adsorption capacity of Cd²⁺ by SHM-FA were 95.76% and 31.79 mg g⁻¹, respectively. The experiment provided clearly explained adsorption kinetics and isotherms. And the results confirmed that the adsorption behavior was well described by the pseudo-second-order kinetic and Langmuir isotherm model, which means that the adsorption of Cd²⁺ was controlled by SHM-FA through surface reaction and external diffusion process. In addition, the recycling of SHM-FA for reuse after Cd²⁺ adsorption showed high removal efficiency up to six times of use. Therefore, it can be concluded that SHM-FA is a low-cost adsorbent for Cd²⁺ removal from wastewater.

Metal-organic frameworks, an emerging class of porous material, have developed rapidly in recent years. In order to clarify the application of metal-organic frameworks in the field of environmental science, 1386 articles over the last 20 years were obtained from Scopus and analysed by the bibliometric method. And the collaboration between countries, institutions and authors and the co-occurrence of keywords were also conducted using VOSviewer. The results indicated that this area of research has entered a fast-developing stage. The number of articles published has grown from 7 articles in 1999 to 378 articles in 2018. The most productive country was China with 626 articles published. The most productive institution was the Chinese Academy of Sciences, and the most productive author was Jhung SH from Kyungpook National University of South Korea. Although metal-organic frameworks have been widely used in adsorption and catalytic degradation of pollutants from the environment, the removal mechanism of pollutants by MOFs, the stability improvement and the cost reduction of metal-organic frameworks are still the main challenges for their practical applications.

Cardiovascular disease has always been the most serious public health problem in China. Although many studies have found that the risk of death caused by cardiovascular disease is related to air pollutants, the existing results are still inconsistent. The aim of this study was to investigate the effects of air pollutants on the risk of daily cardiovascular deaths in Hefei, China. Daily data on cardiovascular deaths, daily air pollutants, and meteorological factors from 2007 to 2016 were collected in this study. A time-series study design using a distributed lag nonlinear model was employed to evaluate the association between air pollutants and cardiovascular deaths. First, a single air pollutant model was established based on the minimum value of Akaike information criterion (AIC), and the single day lag effects and multi-day lag effects were discussed separately. Then, two-pollutant models were fitted. Subgroup analyses were conducted by gender (male and female), age (< 65 age and ≥ 65 age), and disease type (ischemic heart disease and cerebral vascular disease). There were 34,500 cases of cardiovascular deaths during the period 2007–2016, and the average concentrations of air pollutants (PM₁₀, SO₂, NO₂, PM₂.₅, CO, O₃) were 106.11, 20.34, 30.49, 72.59, 958.7, and 67.88 μg/m³, respectively. An increase of interquartile range (IQR) in PM₁₀, SO₂, NO₂, PM₂.₅, CO, and O₃ were associated with an increase of 4.34% (95%CI 1.54~7.23%) at lag 0–6, 5.79% (95%CI 2.43~9.27%) at lag 0–5, 4.47% (95%CI 1.64~7.37%) at lag 0–5, 3.14% (95%CI 0.03~6.36%) at lag 0–4, 3.11% (95%CI 0.21~6.10%) at lag 0–3, and 8.17% (95%CI 1.89~14.84%) at lag 0–5 in cardiovascular deaths, respectively. Females, older group (≥ 65 years) and deaths from cerebral vascular disease were more vulnerable to air pollution than males, younger individuals (< 65 years) and deaths from ischemic heart disease. Our results suggest that air pollution increased the risk of cardiovascular deaths in Hefei. These findings can provide evidence for effective air quality interventions in Hefei.

Arsenic (As) and mercury (Hg) are toxic elements that are often classified as heavy metals, much like cadmium (Cd) and lead (Pb) and others. In this study, we determined the As and Hg contents in rice samples obtained from commercially available rice in Beijing and the health risks associated with daily dietary exposure to As and Hg by the consumption of this rice. Furthermore, the pollution levels of the rice were evaluated based on the Nemerow index. For this purpose, we collected 353 rice samples from 16 municipal districts in Beijing and determined the As and Hg contents in these samples by microwave digestion and inductively coupled plasma mass spectrometry (ICP-MS). The results were as follows: (i) the average content of As in the collected rice samples was 154.91 μg/kg (95% confidence interval (CI) of 139.90–169.92 μg/kg), and the average content of Hg was 2.02 μg/kg (95% CI of 1.25–2.79 μg/kg), which did not exceed the limits established by China’s National Standard; (ii) the Nemerow index indicated that the As and Hg contents in these rice samples were safe; (iii) the dietary exposure to As and Hg by rice consumption was, respectively, 15.35 μg/day and 0.20 μg/day, which accounted for 12.91% and 3.35% of the total dietary exposure, respectively; (iv) the hazard quotients (HQs) of As and Hg by the dietary consumption of rice were, respectively, 0.77 and 0.03, and both the HQ and hazard index (HI is 0.8) were less than one. These results indicate that dietary exposure to As and Hg would have no detrimental effect on the health of the residents in the study area; however, the possible carcinogenesis by As in these residents warrants serious attention.

Determining alternative water sources to meet municipal water demands is important when availability is limited. The purpose of this study was to demonstrate a means for water planners to estimate the amount of combined sanitary wastewater and storm water that they might already be capturing through open air oxidation ponds. Increased understanding of the quantity of water that is already available could help water planners to better envision optimal water reuse scenarios. Using water and climate data on oxidation ponds in these three cities within the Texas Panhandle from 2010 to 2014, we evaluated water quantities which would be available for potential reuse. From the net monthly wastewater volumes values, the study also considered if per capita demand could have been met by reusing the wastewater. The study found wastewater volumes were lower in fall and winter months and much higher in spring and summer months. If a city considers reusing wastewater, blue water (groundwater) extraction could be reduced by as low as 45–50% in one city to as high as 100% in another. Water planners in similar environments and wastewater treatment systems may find this demonstration of potential reuse water quantity encouraging for better meeting their own water demands and enhancing water supply resiliency.

This paper investigates the interaction effects of income inequality and democracy on CO₂ emissions. The spatial panel model, which accounts for the spatial spillover effects across countries, is used. Using the panel data covering 41 Belt and Road initiative countries, the results indicate significant positive spatial spillovers effect to country-level CO₂ emission activity. The Kuznets Curve hypothesis, which assumes that reverse U relation presents between income and CO₂ emissions, is identified. Empirical results provide evidence that democracy levels promote the nonlinear nexus between income inequality and CO₂ emissions. High levels of inequality, ceteris paribus, in conjunction with poor democratic institutions are likely to result in higher pollution. The findings are robust to various robustness tests.

The developing world is facing pivotal challenges in recent times. Among these, global warming has ominous repercussions on every segment of society, thus tracing its underlying causes is imperative. This research attempts to investigate the impact of urbanization and energy consumption on carbon dioxide emissions (CO2) for a panel of 8 Asian countries (Bangladesh, China, India, Indonesia, Malaysia, Nepal, Pakistan, and Sri Lanka) over the period 1982 to 2017. The analyses are executed using panel co-integration and Granger causality techniques. The main findings of panel co-integration reveal a long-run relationship between urbanization, energy consumption, and CO₂ emissions. Furthermore, the results indicate a positive and significant impact of urbanization and energy consumption on CO₂ emissions, indicating that urban development and high energy consumptions are barriers to improve environmental quality in the long run. The results also highlight bi-directional causality between energy consumption and urbanization, while unidirectional causality exists between energy consumption and CO₂ emissions. Based on the obtained results, this study offers useful policy implications for plummeting carbon emissions.

Bioretention cell (BRC), bioretention cell with microbial fuel cell (BRC-MFC), and an enhanced combined BRC-MFC system with bimetallic zero-valent iron (BRC-MFC-BZVI) were implemented in current study to treat the domestic wastewater. Nitrogen removal characteristics of three systems were investigated by adjusting influent carbon/nitrogen ratio (C/N ratio of 2.54–19.36). Results revealed that the nitrification and denitrification performances were mainly influenced by organic matter and system combination, which further affected nitrogen removal. When the influent C/N ratio was between 2 to 3, compared with BRC system, in BRC-MFC and BRC-MFC-BZVI system, chemical oxygen demand (COD), total nitrogen (TN), and ammonical nitrogen (NH₄⁺-N) removal efficiencies were still reached to 83.04%, 61.06%, and 42.26% and 86.53%, 43.61%, and 50.99% respectively, which simultaneously achieved high-efficiency of organic matter and nitrogen removal. The efficient supply of electrons in the BRC-MFC and BRC-MFC-BZVI processes was the main reason to achieve profound denitrification removal under the condition of low C/N. Removal rates of nitrate (NO₃⁻−N) and nitrite (NO₂⁻−N) were relatively higher due to microbial-driven redox reactions caused by driving electrons to flow in the closed circuit of metal wire connection. Moreover, phylogenetic diversity of bacterial communities mainly induced the catalytic iron, which further enhanced biological nitrogen reduction. The maximum efficient removal of organic matter (OM), TN, and NH4 + −N were obtained in the BRC-MFC-BZVI system, which were 98.42% (C/N = 10.42), 55.61% (C/N = 4.16), and 61.13% (C/N = 4.16), respectively.

To evaluate the effects of air pollutants on hospitalizations of elderly people for congestive heart failure (CHF) in the city of São Paulo, stratified by sex, exploring lag structures, from 2000 to 2013. Ecological time series study using information on hospitalization of elderly patients for CHF (ICD-10th: I50) obtained from DATASUS for the city of São Paulo. Information on O₃, PM₁₀, NO₂, SO₂, CO, temperature and humidity was obtained from CETESB. Descriptive analyses, Pearson correlation, and generalized linear Poisson regression model were applied to estimate the effects of pollutants. The interquartile variations of O₃ (52.45 μg/m³), PM₁₀ (24.28 μg/m³), NO₂ (7.63 μg/m³), SO₂ (50.22 μg/m³), and CO (1.28 ppm) were associated with increased hospitalizations for CHF. Air pollutants continue to be a factor that contributes to the increase in the number of hospitalizations due to CHF.