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Comparative Advanced Oxidation Decolorization of the Triphenylmethane Dye with Dimethyl Dioxirane and Hydrogen Peroxide
2023
Vinotha, S. | Rose, A. Leema
Methyl Violet (MV), a triphenylmethane dye, has been subjected to comparative studies with hydrogen peroxide and dimethyl dioxirane under optimum situations. When employing hydrogen peroxide, the photolysis process becomes slower, but the dye solutions are entirely decolored and mineralized. The decolorization rate exhibits pseudo-first-order kinetics. The effect of pH, oxidant dosage, and methyl violet concentration on the degradation is also examined. Generated o-leucoaniline,1,3-diphenylurea,2-hydroxy benzoic acid, phenol, acetone, water, carbon dioxide, and carbon monoxide are identified and measured by GC-MS analysis. These substances remain in the dye solution along with dimethyl dioxirane, which is released faster during the last stages of degradation. The degradation rates of methyl violet reached 97.9% and 65.8% within 30 mins and 180 min of reaction time using dimethyl dioxirane and hydrogen peroxide.
Показать больше [+] Меньше [-]Biomimetic Synthesis of Nanoparticles: State-of-the-Art
2023
Abbasi, Tabassum | Abbasi, S. A. | Rajalakshmi, R. | Patnaik, Pratiksha | Abbasi, Tasneem
A state-of-the-art review of biomimetic nanoparticle synthesis is presented. The technique’s origin has been traced to the studies, started over 150 years ago, on the hyperaccumulation of certain metals by different species of plants. How the initial intracellular method of nanoparticle synthesis evolved into the now widely used extracellular route has been described. The review then covers the gist of all the studies reported on the biomimetic synthesis of nanoparticles of different metals using extracts of different botanical species (plants). The synthesis mechanism is discussed, and the factors influencing the nanoparticles’ extent, shapes, and sizes are identified.
Показать больше [+] Меньше [-]Strategic Monitoring of Groundwater Quality Around Olusosun Landfill in Lagos State for Pollution Reduction and Environmental Sustainability
2023
Oyebode, O.J. | Jimoh, F.O. | Ajibade, S.M. | Afolaluand, S.A. | Oyebode, F.A.
As urbanization and population increase in the megacity, there is a need for engineering intervention and strategic monitoring of groundwater around landfills for environmental sustainability, pollution reduction and public health. This study evaluated water’s physical and chemical parameters in wells and boreholes near the Olusosun landfill in Lagos State to determine how they impact groundwater quality. An Atomic Absorption Spectrometer (AAS) was used to evaluate groundwater samples obtained from five locations within the dump site. Some water parameters, such as dissolved oxygen (DO), iron (Fe), lead (Pb), manganese (Mn), and magnesium (Mg), had concentrations that were higher than the WHO, NESREA, and Nigerian Standard for Drinking Water Quality (NSDWQ) standard limits in some sampling sites, with mean concentrations of 0.33 mg.L-1, 0.04 mg.L-1, 0.74 mg.L-1, and 0.74 mg.L-1, respectively. A small amount of lead was identified in the groundwater of the study area. A major source of air and groundwater pollution, the Olusosun landfill has a detrimental impact on the health of those who live there. Solid waste, groundwater interactions, and contaminated migration into the nearby neighbourhood were studied. It was observed that the degradation of waste products in dump sites releases harmful leachate into the groundwater. Even though some heavy metal concentrations in the study area are still within WHO, NESREA, and NSDWQ standard limits, investigations and further monitoring should be conducted regularly to assess the concentrations of heavy metals in groundwater.
Показать больше [+] Меньше [-]Visitors Perceptions of the Climate Comfort at the Padang Coastal Tourism Area, Indonesia
2023
Sudiar, N. Y. | Gautama, M. I.
This study explains visitors’ perceptions of climate comfort in the Padang coastal tourism area, including Air Manis Beach, Padang Beach, Nirwana Beach, and Pasir Jambak Beach. Climate comfort index calculation using the Holiday Climate Index (HCI) and survey methods are used to take data. The survey is conducted to collect data on climate comfort perception and the role of weather on that comfort. There are 409 respondents in this study. Most visitors state that weather affects climate comfort during their trip (99%) and need weather information for outdoor tourism (98.5%). However, only 27.1% are looking for weather information before traveling outdoors. This coastal tourism area’s perceived level of climate comfort is comfortable (64%). The thermal sensation is neutral (66%). Meanwhile, the average score of the comfort index in Padang is neutral throughout the year. The temperature interval indicates the comfortable category is between 26ºC-28ºC.
Показать больше [+] Меньше [-]Denaturing Gradient Gel Electrophoresis (DGGE) Analysis Indicating Increased Microbial Diversity in Landfill Area Near Conserved Wetland
2023
Chakraborty, M. B. | Patgiri, S. R. | Rahman, A. S. | Dasgupta, A. | Pegu, G.
The ecological balance of an ecosystem has a relation to its biodiversity. Although it has been established that biodiversity and ecological stability are related, generalization about the exact nature of this relation remains elusive and more so in microbial diversity. A growing volume of studies has indicated that anthropogenic activities impact biodiversity, but it is difficult to generalize the impact of anthropogenic activities on microbial diversity. Landfilling by municipal solid waste is one such activity where microbes play a major role, and leachates are released from the landfill, altering the soil’s physical and chemical nature. Change in factors like carbon source, pH, and toxicity of the soil is most likely to affect the indigenous microflora of the soil. The present study was undertaken to compare the microbial diversity of soil receiving landfill leachate with that of the soil not receiving any landfill leachate to assess the impact of the landfilling activity on microbial diversity. The landfill site selected for the study was that of Kamrup Metro District of Assam, located at Boragaon, near the Ramsar wetland called Deeporbeel. By using the Denaturing Gradient Gel Electrophoresis (DGGE) method, it has been found that the microbial diversity of the soil receiving leachate was higher than that of the soil not receiving any leachate from the landfill.
Показать больше [+] Меньше [-]The Impact of High-Concentration Salt Solution on Morphological Changes in a Geosynthetic Clay Liner
2023
Nisha, N. P. | Jose, J. Prakash Arul
Microscopic examination was used to begin investigating the changes in geosynthetic clay liner (GCL) specimens that had been hydrated with two separate solutions: pure water and a 50 percent concentration NaCl solution. After already being hydrated with NaCl aqueous solution, the GCL samples were examined under an electron microscope. Even though the treated GCL samples’ surfaces mirrored those of the untreated GCL, a crystal deposit was found there. It was found that the bentonite particles in the GCL sample appeared more solid after being hydrated with distilled water as opposed to the NaCl solution using a scanning electron microscope (SEM). It seems that wetting the salt solution decreases the bentonite particles’ tendency to swell. Additionally, it was demonstrated by the energy-dispersive X-ray spectrometer (EDS) data that distilled water hydration had no impact on the distribution of the elements identified in the GCL samples. On the other hand, the presence of bound chlorine demonstrated that the bentonite particles had absorbed the NaCl solution. The hydrated GCL sample’s hydraulic conductivity showed some variation as well.
Показать больше [+] Меньше [-]Determination of the Dynamics of Thunderstorms Through the Dry Adiabatic Lapse Rate and Environmental Lapse Rate
2023
Hashim, Shiemaa A. | Kadhum, Jasim H. | Abbood, Zainab M. | Al-Taai, Osama T. | Nassif, Wedyan G.
This research aims to determine the types of thunderstorms formed in the thickness of the cloud (determine the Dry adiabatic lapse rate (DALR) and Environmental lapse rate (ELR)) in the case of precipitation during the day. Data were taken by Temperature, Dew point, Atmospheric Pressure, and Height from re-analysis by the (ECMWF) for the heights (0-18000) m, the levels of pressure (1000-100) mbar, low cloud cover data, and the characteristic days ((18, 24, 27) February, 28 April, and 25 November) of the year 2018 for Baghdad station were chosen to obtain the largest possible number of clouds and their diversity to use them in calculating the cloud cover and weather stability in terms of calculating the daily change, temperature, dew point in addition to calculating the low cloud cover with altitude and atmospheric instability. The Sigma Plot program was used in this research to determine the base of clouds and thunderstorms. The change in temperature, Dew point, clouds base, and altitude was determined, then the cloud thickness, types, and classification were calculated. The clouds found are strong thunderstorm clouds characterized by thickness and height, such as the clouds of Nimbostratus (Ns) and Cumulonimbus (Cb).
Показать больше [+] Меньше [-]Plant Growth Promoting Efficacy of Endophytic Fungi Isolated from the Terrestrial Plants of North India
2023
Patyal, Urvasha | Kumar, Vikas | Singh, Manoj | Singh, Kulbir
Enhanced crop health, which is crucial for sustainable agriculture, is facilitated by a unique endophyte or endophytic community that is frequently linked to a variety of crops. Plant growth-promoting (PGP) characteristics of endophytes can directly or indirectly boost crop growth. Endophytic fungi have been proven to create a high percentage of new compounds, making them a particularly potential source of physiologically active chemicals. In this study, we have isolated two endophytic isolates, i.e., Paecilomyces sp. (Isolate AT1) and Aspergillus flavus (Isolate AT3), from different host plants, namely Melaleuca citrine and Carica papaya. These endophytes have shown significant plant growth-promoting potential toward different assays such as IAA production, phosphate solubilization, amylase production, cellulose-degrading assay, and ammonia production. These endophytic fungi also exhibit visible antimicrobial action towards selected crop pathogenic fungi (Aspergillus sp. and Penicillium sp.). Additionally, these fungal strains are reported for the first time from these plants, as we have found no reports in the literature. The research aims to explore the growth-promoting efficacy of endophytic fungi to boost plant growth.
Показать больше [+] Меньше [-]Radiation Tolerant Life Forms and Methods Used to Remediate Radioactive Wastes from Soil
2023
Verma, Richa | Shrivastava, Anamika
The expanding nuclear industry has led to increasing radioactive waste in the environment. Exposure to these wastes causes considerable irreversible damage to the organisms, some of them being even lethal. Conventional methods like incineration, wet oxidation, and acid digestion have been used for radwaste treatment to control this. Apart from them, other organic methods like bioremediation are being widely applied by scientists. Many bacteria, fungi, algae, and plants are observed to possess remediating properties. Hence, these are now used on a large scale to treat the radioactive matter as quickly and effectively as possible. Techniques like bioaccumulation, enzymatic reduction, bioprecipitation, or phytoremediation methods such as phytoextraction and phytostabilization involving such organisms with remedial abilities have successfully removed the radioactive matter to an extent from the contaminated site. Further research is needed to increase the efficiency of the techniques and help remove radionuclides in an environment-friendly manner.
Показать больше [+] Меньше [-]Variance-Based Fusion of VCI and TCI for Efficient Classification of Agriculture Drought Using Landsat Data in the High Atlas (Morocco, North Africa)
2023
Ezzahra, Fathallah Fatima | Ahmed, Algouti | Abdellah, Algouti
Drought assessment using drought indices has been widely carried out for drought monitoring. Remote sensing-based indices use remotely sensed data to map drought conditions in a particular area or region. Therefore, the objective of the present study is to make a study on drought risk based on the calculation of an indicator from biophysical parameters extracted from NOAA/AVHRR satellite data, namely TCI and VCI, to obtain a better understanding of the differentiation between each index, and their application for drought monitoring in the High Atlas of Marrakech on the Chchaoua Morocco watershed during 1980-2020. Landsat oli7 and8 data were used to construct the indices. The result showed that each index proved to be a useful, fast, sufficient, and inexpensive tool for drought monitoring. However, each index has its differences. The TCI was found to be drought sensitive during the dry season or in months when high temperatures occurred. While VCI detected drought more sensitively in the rainy season as well (December-January-February to May) than TCI and VCI. Meanwhile, VCI, including the improved TCI, combined two indicators to better understand drought occurrence. These indices were calculated using GIS, QGis, ArcGis satellite imagery scenes, and Landsat. After a comparative study of these years, from 1984 to 2020, the evolution of the VCI and TCI was highlighted.
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