This study investigates the spatiotemporal variability of major and trace elements, dissolved organic carbon (DOC), total dissolved solids (TDS), and suspended particulate matter (SPM) in surface waters of several hydrosystems of the Loire River watershed in France. In particular, this study aims to delineate the impact of the abovementioned water physicochemical parameters on natural iron and manganese physical speciation (homoaggregation/heteroaggregation) among fine colloidal and dissolved (< 10 nm), colloidal (10–450 nm) and particulate (> 450 nm) phases in Loire River watershed. Results show that the chemistry of the Loire River watershed is controlled by two end members: magmatic and metamorphic petrographic context on the upper part of the watershed; and sedimentary rocks for the middle and low part of the Loire. The percentage of particulate Fe and Mn increased downstream concurrent with the increase in SPM and major cations concentration, whereas the percentage of colloidal Fe and Mn decreased downstream. Transmission electron microscopy analyses of the colloidal and particulate fractions (from the non-filtered water sample) revealed that heteroaggregation of Fe and Mn rich natural nanoparticles and natural organic matter to the particulate phase is the dominant mechanism. The heteroaggregation controls the partitioning of Fe and Mn in the different fractions, potentially due to the increase in the ionic strength, and divalent cations concentration downstream, and SPM concentration. These findings imply that SPM concentration plays an important role in controlling the fate and behavior of Fe and Mn in various sized fractions. Graphical abstract Physical speciation by heteroaggregation of (Fe-Mn) compounds: high [SPM] → [Fe-Mn] particulate faction; low {SPM] → [Fe-Mn] colloid-dissolved fraction.

Air pollution has been suggested to affect semen quality, but the evidence is still contradictory. To assess whether any differences occur in conventional sperm parameters of men life-long resident in low, middle-low, middle, and high industrial density zones in the province of Messina. We retrospectively analyzed the conventional sperm parameters of patients to whom the sperm analysis was requested during their female partner counseling for infertility in an assisted reproductive technique (ART) center. A total of 184 men were enrolled. Total sperm count was higher in patients living in low and middle-low industrial density areas compared with that of men living in middle and high ones (123.5 ± 146.8 vs. 80.7 ± 92.7 mil/ejaculate, p < 0.05). No difference was found for sperm concentration (37.2 ± 49.7 vs. 30.5 ± 37.2 mil/mL), progressive motility (15.4 ± 19.8% vs. 14.2 ± 18.4%), total motility (62.3 ± 20.5 vs. 58.4 ± 19.9 mil/mL), and normal forms (2.7 ± 1.5 vs. 2.3 ± 3.0 mil/mL). These results add further evidence to findings from Sicilian population. Effective control of air pollution should be accomplished to prevent its negative impact on human reproductive health.

This study deals with further and systematic laboratory evaluation of the already known ammonium 12-molybdophosphate (AMP)-diffusive gradient in thin film (DGT) method, which is used for measuring total Cs concentration in environmental waters. This study confirms that the AMP-binding gel is not stable for pH > 6. In order to reveal a potential impact of AMP degradation on DGT application, time-series experiments were performed by deploying AMP-DGT samplers in Cs-doped moderately basic soft and hard water up to total AMP-binding gel degradation (60 and 175 h of deployment time, respectively). Linear accumulation of Cs by AMP-DGT samplers was observed up to 48 and 58 h in hard and soft waters, respectively. For this deployment time range, AMP-DGT measured over 77 ± 10 and 94 ± 16% of total Cs concentration in hard and soft water, respectively. The difference in DGT response was attributed to Ca²⁺ and Mg²⁺ competition reducing the uptake of AMP-DGT samplers in hard water. Shrinkage of agarose-polyacrylamide diffusive gel was experimentally observed only in hard water due to more intensive AMP-binding gel degradation in hard water. Even if the AMP-DGT response was not impacted in this study, it is recommended to use agarose hydrogel as standard diffusive gel. Based on the experience obtained from this detailed validation process, the authors propose a number of key requirements that need to be considered when developing DGT devices, with testing the performance over longer deployment times being critical. Graphical abstract ᅟ

The study focuses on the estimation of health risk from nitrate present in the drinking water and vegetables in Nagpur and Bhandara districts in the state of Maharashtra, India. Drinking water samples from 77 locations from the rural as well as urban areas and 22 varieties of vegetable were collected and analyzed for the presence of nitrate for a period of 1 year (two seasons). The daily intake of nitrate from these water and vegetable samples was then computed and compared with standard acceptable intake levels to assess the associated health risk. The mean nitrate concentration of 59 drinking water samples exceeded the Bureau of Indian Standards limit of 45 mg/L in drinking water. The rural and urban areas were found to have mean nitrate concentration in drinking water as 45.69 ± 2.08 and 22.53 ± 1.97 mg/L, respectively. The estimated daily intake of drinking water samples from 55 study sites had nitrate concentration far below the safety margin indicating serious health risk. The sanitation survey conducted in 12 households reported contaminated source with positive E. coli count in 20 samples as the major factor of health risk. The average nitrate concentration was maximum in beetroot (1349.38 mg/kg) followed by spinach (1288.75 mg/kg) and amaranthus (1007.64 mg/kg). Among the samples, four varieties of the vegetables exceeded the acceptable daily intake (ADI) with an assumption of 0.5 kg consumption of vegetables for an average of a 60-kg individual. Therefore, irrigation of these locally grown vegetables should be monitored periodically for nitrogen accumulation by the crop above the ADI limit. The application of nitrogenous fertilizers should also be minimized in the rural areas to help protect the nitrate contamination in groundwater sources.

Mechanochemical degradation (MCD) technology has shown its remarkable potential in the disposal of persistent organochlorines in a non-combustion manner. In the present study, endosulfan, as the newly listed persistent organic pollutants (POPs) in the Stockholm Convention, was investigated for its feasibility of mechanochemical destruction using high-energy ball milling. Using calcium oxide (CaO) as a co-milling reagent, the degradation efficiency of endosulfan was nearly 100% after ball milling for 60 min, while the dechlorination efficiency and the sulfate formation efficiency were delayed for endosulfan degradation. After ball milling for 120 min, the dechlorination efficiency and sulfate formation efficiency reached 87.55% and 26.28%, respectively. Based on the measurement results from various material characterization approaches, the main degradation pathway of endosulfan was proposed as sequential dechlorination followed by the destruction of hydrocarbon skeleton. The GC-MS analysis confirmed that complete desulfurization and dechlorination had been realized finally. This study provides an option for the way toward the efficient and rapid destruction of endosulfan as a new POPs using mechanochemical technology.

This study investigates the validity of the EKC (environmental Kuznets curve) hypothesis for the 50 US states and a Federal District (Washington, D.C.). To this aim, the common correlated effects (CCE) and the augmented mean group (AMG) estimation procedures are applied between 1980 and 2015. While the CCE estimation does not support EKC hypothesis, the AMG does. The empirical findings of the AMG estimation indicate that only 14 states verify the EKC hypothesis. Additionally, the expected negative impacts of fossil energy consumption on the environment (CO₂ emissions) are strongly detected in all states except Texas. However, the expected positive impacts of renewable energy consumption on the CO₂ emissions are detected only in 13 states. Furthermore, the expected negative impacts of the population are not detected in some mostly populated states like New York, Texas, and Ohio. The overall findings of this study may help the US state-level policy makers in two ways: first, to understand whether their economic growths are sustainable (eco-friendly); second, to see how their fossil and renewable energy consumptions affect their environments and to review their energy policies.

In recent decades, climate change and environmental pollution have been at the center of global environmental debates. Nowadays, researchers have turned their attention to the linkage between real output and environmental quality and test the environmental Kuznets curve. Majority of the studies focus on a single pollutant aspect and measure the deterioration of the environment through carbon emission (CO₂) only. In contrary, the current study uses a comprehensive proxy, ecological footprint, to measure the environmental quality of the sixteen Central and Eastern European Countries (CEECs). The aim of this paper is to discover the impact of financial development, economic growth, and energy consumption (renewable and non-renewable) on the environment. In addition, for the first time, the current study includes biocapacity and human capital in the growth–energy–environment nexus in the case of CEECs. In doing so, we used annual data of sixteen CEE countries in perspective of the One Belt One Road (OBOR) initiative and cover the period of 1991–2014. For reliable findings, this study focuses on second-generation econometric approaches to check stationarity, cross-sectional dependency, and co-integration among the model parameters. The long-run estimations of the “Dynamic Seemingly Unrelated-co-integration Regression” (DSUR) signify that the effect of economic growth on ecological footprint is not stable and validate N-shaped relationship for cubic functional form between per capita income and ecological footprint (environmental quality). Empirical evidence divulges that financial development and energy use significantly contribute to environmental degradation while renewable energy improves environmental quality by declining ecological footprint significantly. Moreover, the significant effects of biocapacity and human capital are positive and negative on the ecological footprint, respectively. In robustness check through the “Feasible Generalized Least Square” (FGLS) and “Generalized Method of Moment” (GMM) models, we found consistent result. Lastly, the “Dumitrescu-Hurlin (D-H) Panel Causality Test” demonstrates that two-way causal relationship exists between EF and GDP, EF and FD, EF and EU, EF and BC, and EF and HC, while one-way causality is running from RE to EF. This study puts the present scenario of CEE economies in front of the policymakers and suggests that they should consider the vital role of renewable energy and human capital to get sustainability.

Placer gold mining is important anthropogenic sources of dust and metals that can strongly influence the environmental quality of the surrounding ecosystem. However, scarce studies have focused on evaluating the influence of placer gold mining on historical metal deposition in the surrounding ecosystem in the northern Great Hinggan Mountains, which is located at northeast of China. To address this research gap, four peatland cores with different distances to a gold placer in the northern Great Hinggan Mountains were selected in this study. Based on the ²¹⁰Pb depth-age model, historical variations in the Pb isotope and deposition fluxes of Pb, Cu, and Zn were reconstructed. The results show that metal deposition in the northern Great Hinggan Mountains was mainly influenced by the placer gold mining around the 1900s when the gold placer started to produce gold, and placer gold mining more seriously influenced the western sites that were closer to the placer gold mining. With increasing global metal productions after 1930, the proportion of the metals from placer gold mining sources gradually decreased, and part of Pb were transported via the atmosphere from other regions (e.g., Europe, East Asia). With the implementation of environmentally friendly policies and the decreasing anthropogenic production of Pb, Cu, and Zn around the world, deposition fluxes of these metals in the northern Great Hinggan Mountain began to decrease after 2000.

Exposure to pesticides is a major factor in the cause of dysfunction in the nervous system and neurodevelopment disorders in children at critical periods of great vulnerability. The aim of this study was to review scientific evidence published on neurodevelopmental effects of prenatal and postnatal exposure to organophosphate pesticides (OPs) in different stages, including neonates, infants, toddlers, preschool children, and school-age children. Full-text articles published in PubMed, Scopus, and ISI databases between 1973 and 2019 were reviewed and the scientific evidence was evaluated. Results: Fifty studies were eligible for inclusion in this quantitative synthesis. Fifteen of these papers evaluated the effects on neonates and infants, 18 on the effects on toddlers and preschool children, and 24 the effects on school-age children. Considerable evidence suggests that prenatal exposure to OPs contributes to child neurodevelopment disorders in all stages, whereas data about the effects of postnatal exposure are limited. Therefore, the available evidence supports the theory that sensitive time-windows occur prenatally rather than postnatally. Although 45 out of the total 50 selected articles found an association between OP exposure and child neurodevelopment, some of the evidence is controversial. A standardized methodology is needed to enable the comparison of the results in several studies, and further research studies are needed to warrant firmer conclusions. A systematic review of this evidence should be performed continuously to update the state of knowledge regarding neurodevelopmental effects associated with OP exposure.

Attention-deficit hyperactivity disorder (ADHD) of children is one of the most common neurodevelopmental diseases; the etiology remains unclear. We reviewed and meta-analyzed case-control studies to assess the effects of blood lead levels in children on ADHD symptoms. Relevant studies were identified by searching electronic databases. A meta-analysis was performed using the fixed model of Review Manager 5.3 software. Seven relevant studies were identified. The case groups exhibited significant increases in ADHD symptoms [mean difference (MD), 0.59; 95% confidence interval (CI), 0.50–0.68; p < 0.0001]. Subgroup assessment showed that even children with blood lead levels <3 μg/dL exhibited significant increases in ADHD symptoms (MD, 0.47; 95% CI, 0.39–0.56; p < 0.0001). Subgroup assessment also showed that children aged 5–12 years exhibited more significant increases in ADHD symptoms (MD, 1.35; 95% CI, 0.28–2.41; p < 0.0001) than children aged >12 years. Our findings suggest that low blood lead levels may be associated with ADHD symptoms in children. However, caution is needed when interpreting the results because among-study heterogeneity was in play. Primary interventions should focus on children with low blood lead levels.