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Diversity and Degradative Potency of Extant Autochthonous Crude Oil-Metabolizing Species in a Chronically Polluted River
2023
Osadebe, Anwuli | Ogugbue, Chimezie | Okpokwasili, Gideon
Persistent pollution of surface waters by hydrocarbon compounds is one of the foremost threats to limited global freshwater resources. This study analyzed the abundance, diversity and degradative capacities of hydrocarbon-utilizing bacteria in chronically polluted Kono River in the Nigerian Niger Delta in order to establish the bacterial drivers of ecological regeneration of the river after an oil spill. The study further aimed to develop a specialized bacterial consortium for application in bioremediation interventions. Bacillus, Pseudomonas and Enterobacter spp. were predominant out of the 82 isolates obtained. Klebsiella pneumoniae and two species of Enterobacter cloacae were identified as the most efficient hydrocarbon utilizers. The isolates were also confirmed as biosurfactant producers and possessed the alkB1 and nahAc genes for degradation of aliphatics and aromatics. E. cloacae-K11, K. pneumoniae-K05, E. cloacae-K12 and their consortium were able to degrade the total petroleum hydrocarbons and polycyclic aromatic hydrocarbons in batch systems by 59.37% – 96.06% and 68.40% – 92.46% respectively. K. pneumoniae-K05 showed the greatest petroleum degradation capacity of the three isolates but hydrocarbon degradation was most efficient with the bacterial consortium. The results obtained showed no significant differences at p≤0.05 between the degradation capacities of K. pneumoniae-K05 and the consortium for PAHs but a significant difference (p≤0.05) was seen with TPH degradation. A viable hydrocarbon degrading bacterial consortium was developed at the end of the study and it was concluded that the polluted river water displayed inherent potential for effective natural attenuation.
Показать больше [+] Меньше [-]Prediction of Air Pollutants Concentration Emitted from Kirkuk Cement Plant Based on Deep Learning and Gaussian Equation Outputs
2023
Ajaj, Qayssar | Mohd Shafri, Helmi Zulhaidi | Ramli, Mohammad | Wayayok, Aimrun
Researchers are interested in developing techniques to monitor, manage and predict the risks of gases and particles emitted from cement factories, which have a direct and negative impact on human health. Deep learning (DL) is a critical component of data mining, which further involves statistics and prediction. In this study, we developed a deep learning prediction model called the Deep Pollutant Prediction Model (DPPM). The data used for DPPM are separated into two types: observed data from a pollution monitoring station of the Institute of Mental Health in Ahmedabad City, India coded as (GJ001), to validate the model and simulated data generated using the Gaussian Plume Model for the hypothetical receptor (Laylan District, Kirkuk, Iraq) to predict the pollution that emitted from Kirkuk Cement Plant 5 km apart from the study area. The findings indicated that the DPPM has high efficiency in both Allahabad and Laylan stations, with more closed results for the data in the Laylan station, which is based on the Gaussian equation simulated data. Since the highest loss function value in the Laylan is 0.0221 of the CaO parameter, while it is 4.466 of the AQI parameter for the Allahabad Station, and the smallest loss function value in the Laylan is equal to 0.0041of both Fe2O3 and MgO parameters, it corresponds to 0.038 of Xylene for the Allahabad station. The results of the study proved that data continuity and non-volatility produce excellent outcomes for DPPM.
Показать больше [+] Меньше [-]Investigating the Influence of Urban River Valleys on Meteorological Parameters at the Local Scale as a Factor for urban sustainability - Case study: Farahzad River Valley
2023
Allahyari, Hadis | Salehi, Esmael | Zebardast, Lobat | Jafari, Hamidreza
Four regions of the Farahzad River Valley with different topography were selected to fully survey it and study the effects of morphology on local climate. then one of the hot days of the month of June 2021 (June 6th) was selected because the wind speeds increase in spring. According to the comparison of the simulation results with the existing site plans, the temperature in area 3 was the highest, 39.60 degrees, and the wind speed was 3.57 m/s. On the other hand, the study and analysis of the maps showed that the temperature of the roads in regions 3 and 4 were higher than the other two regions with a temperature range of 37.69-38.40, so the presence of impervious asphalt surfaces on the roads is very effective in increasing the air temperature in these areas. Comparisons also showed that tall buildings and vegetation create shaded areas and increase wind speed. Based on this, two scenarios were designed. In the first scenario, doubling the height of buildings increased wind speed in Region 3 by 3.42 m/s and decreased temperatures by 1.59 degrees. In the second scenario, when tall trees were planted at certain distances around the streets, the temperature in Region 3 decreased by 1.68 degrees and the wind speed increased by 1.68 m/s. The results show that the differences in the topography of urban valleys cause ventilation of the environment and that the effect of this feature in other environments is more effective through planting than through buildings.
Показать больше [+] Меньше [-]Natural Extraction of Dyes from Saffron ‘Crocus sativus L’ Flower Waste, Cotton Dyeing, and Antioxidant Effectiveness
2023
Lachguer, Khadija | Boudadi, Imane | Fayzi, Lahbib | El Merzougui, Soumaya | El Bouchti, Mehdi | Cherkaoui, Omar | Serghini, Mohammed Amine
The production of saffron, the spice obtained from the dried stigmas of Crocus sativus L. (Iridaceae family) flowers, generates, after pruning, considerable quantities of waste containing natural dyes. Saffron flower waste could be a source of extraction of natural dyes with antioxidant activity. In this study, we investigate the possibility of using saffron flower waste for dyeing cotton and evaluating the antioxidant effect of this dye by the DPPH free radical, reducing power and β-carotene bleaching assay. The dye has been evaluated for the composition of the color by the UV-visible spectrum and tested for the dyeing of cotton. The results indicate the presence of polyphenols and flavonoids. The dyeing conditions have been optimized at 6% dye concentration, dye bath pH of 3, dyeing temperature at 98 °C and dyeing time of 60 min. 2% dye concentration with 5 to 10% mordant concentration remains sufficient for dyeing with pre-mordanting. The exhaustion of the bath after dyeing has been improved by a rate of 20% in the case of addition of mordants which have produced a shade of green color. The dye contributes to the significant antioxidant activities with more DPPH scavenging capacity, FRAP reducing power, and β-carotene bleaching inhibition. Cotton fabrics dyed with bio-dyes obtained from saffron flower waste show good color fastness properties and could be a potential source of natural antioxidant agent. It presents an important eco-friendly alternative to synthetic dyes for large-scale application in textile and food industries.
Показать больше [+] Меньше [-]Characterization of Groundwater and Distribution of Fluoride in the Eastern Region of the Algerian Northern Sahara (Ouargla)
2023
Abdellaoui, Aicha | Baouia, Kais | Saggai, Sofiane
In the eastern region of the Algerian Northern Sahara, the groundwater is the only resource for drinking water supply and irrigation. This study aimed to assess the physical-chemical quality of groundwater with exposition of the fluoride distribution in the eastern region of Algeria taking as case study Ouargla area. The sampling campaign was carried out in such a way to cover the exploited aquifers (Miopliocene and Senonian). Water temperature, pH, conductivity, hardness, alkalinity, principal ions (Sodium, Potassium Calcium, Magnesium, Bicarbonates, Nitrates, Sulfates, and Chlorides) and the fluoride content in the groundwater were measured and determined. Examination and validation of obtained results were by the use ionic balance method and the hydrochemical analysis by Piper, Stabler and Richards diagrams. The obtained results of our study show that the groundwater of the Ouargla area presents a chlorinated sodium and potassium facies. Moreover, the groundwater quality in the study area is of poor quality; it is hard and characterized by very high mineralization, The Richards' diagram indicates that the groundwater of the study area are unsuitable for irrigation. The spatial distribution of fluoride ions in groundwater of the terminal complex shows that fluoride levels in Ouargla exceed the World Health Organization standard.
Показать больше [+] Меньше [-]Analysis of the Effect of Green Packaging on Attracting and Retaining Environmentally Friendly Customers with the Mediating role of Green Brand Image
2023
Seifollahi, Naser
Increasing the level of environmental knowledge of consumers and their level of concern towards the environment and green brands are among the important factors that have been considered in the discussion of consumer behavior in recent years. Marketing managers also try to attract customers' attention to their green products and brands in order to succeed in selling and marketing their products. Therefore, the present study was conducted with the aim of investigating the effect of green packaging on attracting and retaining environmentally friendly customers with the mediating role of green brand image. In terms of the purpose of the research, the type of applied research, the method of collecting descriptive data is of the correlation type. The statistical population of this research is the students of University of Mohaghegh Ardabili, 373 of them were selected as a sample by referring to Morgan's table and using the available sampling method. The required data were collected using a questionnaire and analyzed based on the structural equation modeling method and using SPSS and Smart PLS software. The results of the research showed that green packaging has a positive and significant effect on attracting and retaining environmentally friendly customers as well as the image of the green brand. On the other hand, the image of the green brand has a positive and significant effect on attracting and retaining environmentally friendly customers. Finally, green brand image acts as a mediating factor in the relationship between green packaging and attracting and retaining environmentally friendly customers.
Показать больше [+] Меньше [-]Current Eco-friendly and Sustainable Methods for Heavy Metals Remediation of Contaminated Soil and Water: Special Emphasis on Use of Genetic Engineering and Nanotechnology
2023
Yadav, Meena | Sharma, Poonam
Anthropogenic activities have polluted soil and aquatic ecosystems by introducing harmful heavy metals (HMs) such as cadmium, copper, mercury, lead, manganese, nickel, zinc, and others. These HMs lead to serious health conditions in humans like cancer, skin lesions, birth defects, liver and kidney damage, and mental retardation leading to other disabilities. Conventional methods of HM remediation of contaminated soil and water include physical, chemical, biological, and integrated methods. The use of physical and chemical methods, in isolation, has been reduced in practice, owing to their negative impacts, however, work on suitable integrated approaches, and the use of organisms for HM remediation has been in steady progress since past few decades. These approaches have proved to be eco-friendly, cost-effective, and show reduced negative impacts on the environment and biota. However, there is consistent increase in anthropogenic contribution to this problem, so, to keep pace with it, more recently work is in advancement on exploiting the biological system to increase the efficiency of bioremediation, using the latest technologies such as genetic engineering and nanotechnology. This paper provides an overview of the current methods deployed to address this problem, developments made in this field in past few decades, and evokes a research thrust that might lead to novel remediation approaches in the future.
Показать больше [+] Меньше [-]Characterization and Evaluation of the Nickel-Removal Capacity of Kluyvera cryocrescens M7 Isolated from Industrial Wastes
2023
Bisht, Heena | Kumar, Narayan
Heavy metal contamination poses grave risks to all kinds of life. The fastest growing automotive, electroplating, and battery industries release the most common heavy metal, Nickel, into the environment, which has lethal impacts on human health. Our research aims to find Ni-resistant bacteria in the metal-contaminated soil that have a great potential for removing Ni from the environment. Attempts have been made to extract and characterize Ni-resistant bacteria from automobile and electroplating industry waste-contaminated soil using serial dilution, streak plating, and various morphological, biochemical, and genetic techniques. The maximum tolerable concentration of Ni and other heavy elements, such as cadmium, lead, and aluminium for the selected isolate, was investigated using the UV-Vis spectrophotometric method. Additionally, the bacterial strain's ability to remove Ni was assessed using an atomic absorption spectrophotometer. The current research reveals a novel strain of Kluyvera cryocrescens that could withstand Ni, Cd, Pb, Al, and combinations of these heavy metals. The maximum tolerance concentration of K. cryocrescens M7 for Ni, Cd, Pb, and Al was found to be 150 ppm, 200 ppm, 1000 ppm, and 150 ppm, respectively. Additionally, it was also observed that the bacterial strain could remove Ni by 29.57%, 35.36%, 48.41%, 46.91%, and 44.88% after 12, 24, 48, 72, and 96 hours, respectively. The strain has also exhibited resistance to vancomycin, ampicillin, carbenicillin, and streptomycin. This research discovered a novel bacterial strain, K. cryocrescens M7 that may be beneficial for removing heavy metals, particularly Ni, from metal-contaminated soil.
Показать больше [+] Меньше [-]Assessing the Natural and Anthropogenic Radionuclide Activities in Fish from Arctic Rivers (Northwestern Russia)
2023
Puchkov, Andrey | Druzhinina, Anna | Yakovlev, Evgeny | Druzhinin, Sergey
This scientific article presents the results of studies on the distribution of natural and artificial radionuclides in fish living in the rivers of the northwestern sector of the Arctic zone of the Russian Federation. Fish sampling (about 76 kg in total) was carried out in the White Sea, in the Northern Dvina and Mezen Rivers, and in the Sukhoe Sea Bay of the Arkhangelsk Region, as well as in the rivers of the Nenets Autonomous District: Pesha, Oma, Vizhas, Nes, and Pechora. The results showed the presence of artificial radionuclides Cs-137 and Sr-90 in fish only in the Nes River of the Nenets Autonomous District. The levels of radionuclides in whole bodies perch and pike in the Nes River range from 3.73 to 14.0 Bq/kg wet weight for Cs-137 and less than 3.72 to 23.1 Bq/kg wet weight for Sr-90. In addition to Cs-137 and Sr-90, the presence of the radionuclide K-40, which is the main dose-forming radionuclide, was noted in the fish of all the studied rivers and seas. K-40 activity was in the reached values 138 Bq/kg for whole fish bodies. The only assumption that can explain the presence of artificial radionuclides in the fish of the Nes River is a possible radioactive trace formed as a result of global nuclear tests, including in the Novaya Zemlya archipelago. At the same time, it is noted that the current levels of technogenic radioactivity in fish from the Nes River do not pose a radiological hazard to the local population.
Показать больше [+] Меньше [-]Trichoderma tomentosum Ts141 as a Potential Candidate for Bioremediation of Cadmium, Lead, and Nickel Ions
2023
Hosseinzadeh, Samira | Aliloo, Ali Asghar | Shahabivand, Saleh | Ghaderi, Mohammad
Fungi are successful microorganisms in the bioremediation of environmental pollution. So, this study aimed to determine the potential of Trichoderma tomentosum to remediate cadmium, lead, and nickel contaminations from potato dextrose agar (PDA) and potato dextrose broth (PDB) media. Growth rates, toxicity tolerance sporulation, bio-sorption capacity, and bio-sorption efficiency of the fungus were evaluated under different concentrations of CdCl2, Pb(NO3)2, and NiCl2. The findings demonstrated that the growth rate of the fungus differed depending on concentration, metal type, and medium. More metals in PDA medium induced more inhibition on fungus growth rates; however, the rate was independent from the heavy metals concentrations in PDB medium. Cadmium was the most toxic metal tested against T. tomentosum, with a 72h LC50 of 37 ppm. It was about 3.16 and 4.24 times as toxic as nickel and lead, respectively. In the control condition, sporulation of the fungus began at 72 hours, but under the heavy metals, it began at 168, 168, and 192 hours, respectively, for Pb, Ni, and Cd. Both the bio-sorption capacity and efficacy of the fungus were significantly enhanced by an increase in metal content and the highest values were obtained at 200 ppm of the salts. The heavy metals total bio-sorption capacity order was Ni < Cd < Pb in the aqueous medium. The conclusion was that T. tomentosum has a greater potential for the biosorption of heavy metals; hence, the fungus may be employed for the bioremediation of heavy metals from polluted sites, particularly wastewater and industrial influents.
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