Microplastics have become an inevitable component of our environment. Worldwide, free public fountains are common and one of the best sources of drinking water which are being installed with one of the viewpoints of reducing single-use plastics bottle consumption. However, the state of knowledge on how microplastics might be affecting in those free public drinking fountains is unknown. In this study, free drinking water fountains from 42 metro stations in Mexico City were being looked into for the occurrence of microplastics and investigated their shape type, size, abundance, distribution, polymer composition and surface morphology. Microplastics were detected in all the samples analyzed. The results revealed the significant abundance of microplastics ranging from 5 ± 2 to 91 ± 14 L⁻¹ in drinking water with an overall average of 18 ± 7 microplastics L⁻¹. Transparent fibers (69%) were predominant in the identified microplastics followed by blue (24%) and red colored (7%) fibers. The most frequent microplastics dimensions ranged between 0.1 and 1 mm which is approximately 75% of the total microplastics. Micro-Raman spectroscopy analysis indicated that microplastics contained in drinking water were mainly polyesters (poly (trimethylene terephthalate)) and epoxy resin suggesting the possible contribution of wastewater discharges for microplastics contamination. Thus, this study findings show that free public drinking water fountains are potential microplastics hotspot for human consumption and provide useful references for mitigation measures.

Particulate matter (PM) pollution is an urgent urban environmental problem. However, plants can mitigate this pollution by filtering the air. Combining the PM capture capacity with the air pollution tolerance could be better evaluate the suitability of greenbelt plants. We selected nine dominant roadside plants growing at two sites in Beijing, and compared their PM capture capacity, morphological characteristics, biochemical characteristics, and air pollution tolerance index (APTI). Sophora japonica had the highest PM capture capacity (362.98 μg cm⁻²), and its wax layers could trap large amounts of PM₂.₅; this high efficiency is important for successful phytoremediation. Sophora japonica. Sabina chinensis, Ulmus pumila, and Euonymus japonicus also showed relatively high PM capture capacity. This is due to their complex cuticular wax layers, short petioles, rough surfaces, high stomata density, and dense canopy structures which reduce the possibility of resuspension of captured PM. Amount of PM captured per unit leaf area had a significant positive effect on the degree of membrane lipid peroxidation, indicating that species with high PM capture capacity suffered higher oxidative stresses. Air pollution showed the strongest negative effect size on chlorophyll contents of E. japonicas. While, S. japonica, S. chinensis, and U. pumila could prevent chlorophyll content decline under severe oxidative stress. Sophora japonica also had the highest APTI at both sites, indicating this species had the greatest tolerance to air pollution. Our findings suggest that S. japonica would be the most suitable species for greenbelt construction in Beijing, followed by S. chinensis, E. japonicus, and U. pumila.

Electrohypersensitive people attribute various symptoms to exposure of radiofrequency electromagnetic fields (RF-EMF); sleep disturbance is the most frequently cited. However, laboratory experiments have yielded conflicting results regarding sleep alterations. Our hypothesis was that exposure to RF-EMF alone would lead to slight or non-significant effects but that co-exposure to RF-EMFs and other environmental constraints (such as noise) would lead to significant effects.3-week-old male Wistar rats (4 groups, n = 12 per group) were exposed for 5 weeks to continuous RF-EMF (900 MHz, 1.8 V/m, SAR = 30 mW/kg) in the presence or absence of high-level noise (87.5 dB, 50–20000 Hz) during the rest period. After 5 weeks of exposure, sleep (24 h recording), food and water intakes, and body weight were recorded with or without RF-EMF and/or noise. At the end of this recording period, sleep was scored during the 1 h resttime in the absence of noise and of RF-EMF exposure.Exposure to RF-EMF and/or noise was associated with body weight gain, with hyperphagia in the noise-only and RF-EMF + noise groups and hypophagia in the RF-EMF-only group. Sleep parameters recording over 24 h highlighted a higher frequency of active wakefulness in the RF-EMF-only group and a lower non-rapid eye movement/rapid eye movement sleep ratio during the active period in the noise-only group. There were no differences in sleep duration in either group. During the 1-h, constraint-free sleep recording, sleep rebound was observed in the noise-only group but not in the RF-EMF-only and RF-EMF + noise groups.Our study showed effects of RF-EMF, regardless of whether or not the animals were also exposed to noise. However, the RF-EMF + noise group presented no exacerbation of those effects. Our results did not support the hypothesis whereby the effects of RF-EMF on physiological functions studied are only visible in animals exposed to both noise and RF-EMF.

In this study, samples of soil and particulate matter obtained from the highly industrialized region of Ostrava, Czech Republic, are used for the toxicity evaluation of the selected metal(loid)s (Cd, Cr, Cu, Ni, Pb, Zn, As). We investigated the samples from sites supposedly affected the most by the local pollution sources using mineralogical techniques (XRD, SEM/EDS) to understand the solid speciation of the contaminants as the crucial factor affecting their release. Although the bulk composition was defined by common silicates and oxides that are rather resistant to leaching, the presence of tiny Ni, Pb, and/or Zn sulfate-like droplets indicated a potential increase of the solubility of these metals. In vitro tests simulating gastric and lung fluids were used to assess the exposure risk for humans, as well as metal(loid) bioaccessibility. Based on the results, the potential risk for the observed age group (3-year-old children) could be recognized, particularly in the cases of As, Pb and Cd for both oral and inhalation exposure. Arsenic exhibits high bioaccessibility (7.13–79.7%, with the median values of 10.6 and 15.6 for SGL and SLF, respectively), high daily intake (1.4- to 8.5-fold higher than the tolerable daily intake) and high concentrations in atmospheric PM₁₀ (2.5 times the tolerable concentration in air). In contrast, Ni exceeded tolerable concentrations in the atmosphere up to 20-fold, but its bioaccessibility remained relatively low (0.1–22%), and Ni did not pose a major threat to human health. Cadmium, Pb and As originating from industrial activities and domestic heating have been suggested to be the most important pollutants (tolerable daily intake was exceeded by up to 74-, 34- and 8-fold for Cd, Pb and As, respectively).

Herein, a new peroxymonosulfate (PMS) activation system was established using a biochar (BC)-supported Co₃O₄ composite (Co₃O₄-BC) as a catalyst to enhance chloramphenicols degradation. The effects of the amount of Co₃O₄ load on the BC, Co₃O₄-BC amount, PMS dose and solution pH on the degradation of chloramphenicol (CAP) were investigated. The results showed that the BC support could well disperse Co₃O₄ particles. The degradation of CAP (30 mg/L) was enhanced in the Co₃O₄-BC/PMS system with the apparent degradation rate constant increased to 5.1, 19.4 and 7.2 times of that in the Co₃O₄/PMS, BC/PMS and PMS-alone control systems, respectively. Nearly complete removal of CAP was achieved in the Co₃O₄-BC/PMS system under the optimum conditions of 10 wt% Co₃O₄ loading on BC, 0.2 g/L Co₃O₄-BC, 10 mM PMS and pH 7 within 10 min. The Co₃O₄/BC composites had a synergistic effect on the catalytic activity possibly because the conducting BC promoted electron transfer between the Co species and HSO₅⁻ and thus accelerated the Co³⁺/Co²⁺redox cycle. Additionally, over 85.0 ± 1.5% of CAP was still removed in the 10th run. Although both SO₄⁻ and OH were identified as the main active species, SO₄⁻ played a dominant role in CAP degradation. In addition, two other chloramphenicols, i.e., florfenicol (FF) and thiamphenicol (TAP), were also effectively degraded with percentages of 86.4 ± 1.3% and 71.8 ± 1.0%, respectively. This study provides a promising catalyst Co₃O₄-BC to activate PMS for efficient and persistent antibiotics degradation.

The current air pollution by SO₂ due to anthropogenic pressure in Poland was assessed based on sulfur concentrations in pine needles (Pinus sylvestris L.). On 308 monitoring sample plots located in pine stands distributed across Poland, measurements were conducted in mineral soil layers (0–10 cm, 10–40 cm, 40–100 cm) and in the soil organic layer (+5–0 cm). Samples of Scots pine foliage (current-year needles) were then collected, and the sulfur concentration in these needles was determined. Based on these data, a map of the spatial variability of sulfur concentrations in pine needles was drawn. The mean sulfur concentration in the pine needles was 854.8 mg kg⁻¹ in dry mass. Higher SO₂ emissions were noted in regions influenced by industry, such as the Upper Silesia and regions under strong urban pressure. Sulfur concentrations in Scots pine needles were related to the stands' degrees of defoliation. A comparison of the current sulfur concentrations in pine needles from biomonitoring in 2015–2016 with those from previous biomonitoring (in 1983–1985, by Dmuchowski and Bytnerowicz (1995) showed that air quality has improved and SO₂ emissions have decreased.

Antimonite [Sb(III)] and antimonate [Sb(V)] are known to have different toxicity to plants, but the corresponding mechanisms are not fully understood. This study was conducted to investigate reactive oxygen species (ROS), antioxidant systems, and levels of certain essential elements in response to exposure to Sb(III) and Sb(V). Results showed that exposure to Sb(V) caused oxidative stress in a rice plant (Yangdao No.6). Sb(III) was shown to be more toxic than Sb(V) as judged from a lower shoot biomass, a higher loss of essential elements, and higher production of superoxide anion free radicals (O₂⁻). The toxicity of Sb(III) might partially be due to the disturbance of the O₂ˉ dismutation reaction, which resulted in root cell membrane damage under exposure to 20 mg L⁻¹ Sb(III). Sb(V) stimulated the shoot fresh weight and the shoot uptake of many essential elements. Moreover, Sb(V) and Sb(III) both stimulated the accumulation of calcium in the shoots and roots, and calcium was found to significantly correlate with the concentrations of many essential elements and with some parameters correlated to antioxidant systems, suggesting a Ca-induced regulatory mechanism. The activity of glutathione peroxidase was significantly enhanced by Sb(V) and Sb(III), suggesting a role in scavenging hydrogen peroxide. Catalase was activated by exposure to 20 mg L⁻¹ Sb(III) in the roots and by exposure to 20 mg L⁻¹ Sb(V) both in the shoots and roots. However, peroxidase was activated by exposure to 5 mg L⁻¹ Sb(III) in the shoots and by exposure to 5 mg L⁻¹ Sb(V) in the roots. This study, for the first time, showed the differences between Sb(V) and Sb(III) toxicity when looking at the antioxidant response and essential element uptake.

Controversial glyphosate-based herbicides (GBHs) are the most frequently used herbicides globally. GBH residues in the wild, in animal and human food may expose non-target organisms to health risks, yet the developmental and cumulative effects of GBHs on physiology and reproduction remain poorly understood. We present the first long-term study on the effects of subtoxic GBH exposure (160 mg/kg) on multiple key physiological biomarkers (cellular oxidative status and neurotransmitters), gut microbiome, reproductive hormones, and reproduction in an avian model. We experimentally exposed in Japanese quail females and males (Coturnix japonica) to GBHs and respective controls from the age of 10 days–52 weeks. GBH exposure decreased hepatic activity of an intracellular antioxidant enzyme (catalase), independent of sex, but did not influence other intracellular oxidative stress biomarkers or neurotransmitter enzyme (acetylcholinesterase). GBH exposure altered overall gut microbiome composition, especially at a younger age and in females, and suppressed potentially beneficial microbes at an early age. Many of the microbial groups increased in frequency from 12 to 28 weeks under GBH exposure. GBH exposure decreased male testosterone levels both at sexual maturity and at 52 weeks of exposure, but did not clearly influence reproduction in either sex (maturation, testis size or egg production). Future studies are needed to characterize the effects on reproductive physiology in more detail. Our results suggest that cumulative GBH exposure may influence health and reproduction-related traits, which is important in predicting their effects on wild populations and global poultry industry.

The new-generation geostationary satellites feature higher radiometric, spectral, and spatial resolutions, thereby making richer data available for the improvement of PM₂.₅ predictions. Various aerosol optical depth (AOD) data assimilation methods have been developed, but the accurate representation of the AOD-PM₂.₅ relationship remains challenging. Empirical statistical methods are effective in retrieving ground-level PM₂.₅, but few have been evaluated in terms of whether and to what extent they can help improve PM₂.₅ predictions. Therefore, an empirical and statistics-based scheme was developed for optimizing the estimation of the initial conditions (ICs) of aerosol in WRF-Chem (Weather Research and Forecasting/Chemistry) and for improving the PM₂.₅ predictions by integrating Himawari-8 data and ground observations. The proposed method was evaluated via two one-year experiments that were conducted in parallel over eastern China. The contribution of the satellite data to the model performance was evaluated via a 2-week control experiment. The results demonstrate that the proposed method improved the PM₂.₅ predictions throughout the year and mitigated the underestimation during pollution episodes. Spatially, the performance was highly correlated with the amount of valid data.

In this study, size-fractionated particulate matters (PM) down to ultrafine (PM₀.₁) particles were collected using a cascade air sampler with a PM₀.₁ stage, in Hat Yai city, Songkhla province, southern Thailand during the year 2018. The particle-bound carbonaceous aerosols (CA) as elemental carbon (EC) and organic carbon (OC) were quantified with the thermal/optical reflectance method following the IMPROVE_TOR protocol. The concentrations of different temperature carbon fractions (OC1-OC4, EC1-EC3 and PyO) in the size-fractionated PM were evaluated to discern OC and EC correlations as well as those between char-EC and soot-EC. The results showed that biomass burning, motor vehicle, and secondary organic aerosols (SOC) all contributed to the size-fractionated PM. The OC/EC ratios ranged from 2.90 to 4.30 over the year, with the ratios of PM₂.₅₋₁₀ being the highest, except during the open biomass burning period. The concentration of CA was found to increase during the pre-monsoon season and had its peak value in the PM₀.₅₋₁.₀ fraction. The long-range transport of PMs from Indonesia, southwest of Thailand toward southern Thailand became more obvious during the pre-monsoon season. Transported plumes from biomass burning in Indonesia may increase the concentration of OC and EC both in the fine (PM₀.₅₋₁.₀ and PM₁.₀₋₂.₅) and coarse (PM₂.₅₋₁₀ and PM>₁₀) fractions. The OC fraction in PM₀.₁ was also shown to be significantly affected by the transported plumes during the pre-monsoon season. Good OC and EC correlations (R² = 0.824–0.915) in the fine particle fractions indicated that they had common sources such as fossil fuel combustion. However, the lower and moderate correlations (R² = 0.093–0.678) among the coarser particles suggesting that they have a more complex pattern of emission sources during the dry and monsoon seasons. This indicates the importance of focusing emission control strategies on different PM particle sizes in southern Thailand.