Analyses of sediment core samples are primary sources of historical pollution trends in aquatic systems. Determining organic compounds, such as POPs, in the dated sediments enables the estimation of their temporal concentration changes and the identification of the contaminant origin in local regions. Wars, large-scale fires, economical transitions, and bans on certain chemicals are reflected in the sediment organic compound concentrations. The high POP concentrations in surficial sediments suggest that these chemicals, even after being banned, remain in the environment. Furthermore, vertical profiles can help in understanding the sedimentation process and in estimating effective countermeasures against pollution. Moreover, studies published during the period 1991–2013 on PAHs, PCBs, OCPs, dioxins and dioxin-like compound concentrations in sediment core samples are reviewed.

Measuring loads of bioavailable metals is important for environmental assessment near mines and other industrial sources. In this study, a setup of monitoring buoys was tested to assess loads of bioavailable metals near a former Pb–Zn mine in West Greenland using transplanted seaweed, mussels and sea snails. In addition, passive DGT samplers were installed. After a 9-day deployment period, concentrations of especially Pb, Zn and Fe in the species were all markedly elevated at the monitoring sites closest to the mine. Lead concentrations in all three species and the DGT-Pb results showed a significant linear correlation. Zinc and Fe concentrations were less correlated indicating that the mechanisms for Zn and Fe accumulation in the three species are more complex. The results show that there is still a significant load of metals from the mine and that such buoys can be an adequate method to assess present loads of bioavailable metals.

A multispecies bloom caused by the centric diatoms, viz. Coscinodiscus radiatus, Chaetoceros lorenzianus and the pennate diatom Thalassiothrix frauenfeldii was investigated in the context of its impact on phytoplankton and microzooplankton (the loricate ciliate tintinnids) in the coastal regions of Sagar Island, the western part of Sundarban mangrove wetland, India. Both number (15–18 species) and cell densities (12.3×103cellsl−1 to 11.4×105cellsl−1) of phytoplankton species increased during peak bloom phase, exhibiting moderately high species diversity (H′=2.86), richness (R′=6.38) and evenness (E′=0.80). The diatom bloom, which existed for a week, had a negative impact on the tintinnid community in terms of drastic changes in species diversity index (1.09–0.004) and population density (582.5×103 to 50×103indm−3). The bloom is suggested to have been driven by the aquaculture activities and river effluents resulting high nutrient concentrations in this region. An attempt has been made to correlate the satellite remote sensing-derived information to the bloom conditions. MODIS-Aqua derived chlorophyll maps have been interpreted.

The characteristics and sources of organic matter in water of the Lake Shihwa, which receives inputs from rural, urban, and industrial areas, were evaluated by examining the biodegradable organic carbon concentration, fluorescence spectra, and carbon and nitrogen isotope ratios, especially during rainy season and dry season. The organic matter transported from rural areas was of refractory nature, while that of industrial origin decomposed rapidly. As compared to the dry season, the organic matter in the rainy season was characterized by a reduced labile fraction. During the dry season, the autochthonous organic matter dominated in the lake, however, the contributions of allochthonous organic sources by industrial and rural areas significantly increased at rainy season. This investigation revealed that the transport of organic matter of anthropogenic origin to the Lake Shihwa was mainly influenced by heavy rainfall. Moreover, each anthropogenic source could differently influence the occurrence of organic matter in water of the Lake Shihwa.

The partitioning and bioaccumulation of polycyclic aromatic hydrocarbons (PAHs) in water, suspended particulate matter (SPM), and fish samples from the Dongjiang River (DR), Pearl River (PR), and the Pearl River Estuary (PRE) were examined. Although PAHs are much lower in PRE than in DR or PR, PAHs in some fish species are significantly higher in PRE than in DR or PR. Aqueous or particulate PAHs respectively show significant correlations with dissolved organic carbon, particulate organic matter, and chlorophyll a, suggesting that biological pumping effect regulates their distribution. The in situ partitioning coefficients (logKoc) for PAHs are one order magnitude higher than the empirical logKoc–logKow correlation. The bioconcentration factor (BCF) is slightly higher for the marine fish than for the freshwater fish. The above phenomena indicate that BCF may vary due to the diversity of fish species, feeding habits, and metabolism of PAHs in fish.

Ambient measurements of elemental species concentrations were made using an online elemental monitor at an air pollution monitoring station in Gwangju, Korea to evaluate the performance of the monitor for near–real time PM2.5 elemental monitoring and identify possible sources of the observed elements. This study also demonstrates the utility of integrating hourly elemental data with the meteorological data to better understand the sources of elements. Good agreement between the online and filter–based measurements was obtained for the elements studied, with an R2 of 0.73–0.97 and regression slopes of 0.84–2.37, suggesting the potential use of the online monitor to observe temporal variations in anthropogenic aerosol particles. Atmospheric element concentration levels studied were 2–20 times greater than their background levels when pollution plumes coming from industrial areas had impacted the site. Examination of the elements data revealed several short spikes of elements that are associated with local industrial emissions and road dusts. For the haze episodes observed over the study period, the element K was significantly influenced by biomass burning emissions with some impacts from soil dusts and industrial activities. Based on the wind direction and wind speed data, As/Se, Se/SO42−, and correlations among Se, As, Pb, SO2, and SO42−, it is suggested that the observed As and Se were significantly impacted by local anthropogenic sources and long–range transport of aerosols, rather than local coal combustion or coke emissions. Conditional probability functions were applied to identify likely local emission source locations of the elements observed at the site, indicating that the elements contributions were from the southwest and northeast directions, where two industrial areas and an express highway are located. Results from principal component analysis indicate that the observed concentrations of the element species were likely attributed to road dust/local industrial emissions, oil combustion, and metal processing.

Composition and abundance of persistent buoyant litter (plastics, polystyrene and manufactured wood) were investigated at riversides and on adjacent coastal beaches of four rivers flowing into the SE Pacific Ocean. Persistent buoyant litter made up the main share of litter at riversides (36–82%) and on coastal beaches near the river mouths (67–86%). The characteristic litter composition of each river is attributable to human influences along its course. Riverine litter items were deposited to both sides of the river mouths on coastal beaches, and their abundance generally declined with distance from the river mouth. However, maximum litter accumulations were often found on beaches north of the river mouth, suggesting a long-term influence of the prevailing equatorward low-level jet along the Chilean coast. The results confirm that riverine transport has an important impact on litter abundances on coastal beaches.

The bioaccumulation of persistent organic pollutants (POPs) in deep sea fish from the Rockall fishing area was investigated. Predator and prey species were analysed for stable isotopes, fatty acids, polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs). δ15N indicated that black scabbard was at the highest trophic level and the prey the lowest. The fatty acid signatures indicated that black scabbard and black dogfish fed at a higher trophic level compared to the roundnose grenadier. PCBs and PBDEs were detected in the liver of all three predator species. PCB concentrations were significantly higher in the roundnose grenadier, possibly due to their longer life span. PCB concentrations were compared to OSPAR assessment criteria, concentrations were above background but below Environmental Assessment Criteria for all but one congener. PCB concentrations were below food safety levels in the flesh, but exceeded the limit for liver in the roundnose grenadier and black dogfish.

In this study, we report the acidification impact mimicking the pre-industrial, the present, and near-future oceans on calcification of two coral species (Porites australiensis, Isopora palifera) by using precise pCO2 control system which can produce acidified seawater under stable pCO2 values with low variations. In the analyses, we performed Bayesian modeling approaches incorporating the variations of pCO2 and compared the results between our modeling approach and classical statistical one. The results showed highest calcification rates in pre-industrial pCO2 level and gradual decreases of calcification in the near-future ocean acidification level, which suggests that ongoing and near-future ocean acidification would negatively impact coral calcification. In addition, it was expected that the variations of parameters of carbon chemistry may affect the inference of the best model on calcification responses to these parameters between Bayesian modeling approach and classical statistical one even under stable pCO2 values with low variations.

Cystoseira amentacea is a Mediterranean endemic alga thriving on very shallow rocky substrates. It has been considered as a threatened species, having experienced a steady decline and is therefore protected by international conventions. The historical distribution of the species has been assessed along the French Mediterranean coast, on the basis of 467 articles and herbarium vouchers. We have produced an accurate map of its current distribution and abundance along 1832km of coastline, through in situ surveys. C. amentacea was observed along 1125km of shoreline, including 33% of almost continuous or continuous belt. In most of its range, there is no evidence of loss, except in 4 areas of Provence, French Riviera and Corsica. A significant relation was found between the absence or low abundance of C. amentacea and the vicinity of ports and large sewage outfalls. The status of conservation of the species should therefore be reassessed.