The deltaic estuarine system of the Matang Mangrove Forest Reserve of Malaysia is a site where several human settlements and brackish water aquaculture have been established. Here, we evaluated the level of fecal indicator bacteria (FIB) and the presence of potentially pathogenic bacteria in the surface water and sediments. Higher levels of FIB were detected at downstream sampling sites from the fishing village, indicating it as a possible source of anthropogenic pollution to the estuary. Enterococci levels in the estuarine sediments were higher than in the surface water, while total coliforms and E. coli in the estuarine sediments were not detected in all samples. Also, various types of potentially pathogenic bacteria, including Klebsiella pneumoniae, Serratia marcescens and Enterobacter cloacae were isolated. The results indicate that the Matang estuarine system is contaminated with various types of potential human bacterial pathogens which might pose a health risk to the public.

The purpose of the present work was to study the concentration variations in O3, NO, NO2, NOX over a 4–year period (2006–2009), using the Kolmogorov–Zurbenko filter. Data were decomposed into seasonal and trend components. Seasonal component of the time–series analysis (2006–2009) of NO and NOx in Canoas and Esteio showed values above average during the cold seasons, while O3 showed an opposite pattern. The trend component was marked by the decrease of NO2 at Canoas and the increase of NO at Esteio, thus revealing their variation (NO and NOX) due to local emissions. Furthermore, evaluations of the mean daily concentrations of NO, NOX, NO2, O3, PM10 and CO, and correlations of these pollutants with meteorological parameters (ambient temperature, wind velocity, solar radiation and relative humidity) allowed the confirmation of the influence of mobile sources in the study area.

Despite being a highly valuable key-stone ecosystem, seagrass meadows are threatened and declining worldwide, creating urgent need for indicators of their health status. We compared two indicators for seagrass health: standing leaf area index versus relative recovery from local disturbance. Disturbance was created by removing aboveground biomass and recording the rate of regrowth for Zostera marina meadows exposed to contrasting wave regimes and nutrient stress levels.Within the experimental period, relative regrowth in gaps was around 50% in most plots, except for the ambient nutrient treatment at the sheltered site, where it exceeded 100%. The two indicators showed an opposite response to disturbance: the higher the standing leaf area index, the lower the relative recovery from disturbance. This conflicting response raises the question on the proper interpretation of such indicators to estimate seagrass health and resilience, and how to ideally monitor seagrass ecosystems in order to predict collapse.

A fast paced industrial and port development has occurred at Suape Estuary, Northeast Brazil, but no information about hydrocarbon concentrations in water is available to this area. Considering that, the contamination level of Suape was determined by UV-Fluorescence in terms of dissolved and/or dispersed petroleum hydrocarbons (DDPHs), during wet and dry seasons. DDPHs ranged between 0.05 and 4.59μgL−1 Carmópolis oil equivalents and 0.01–1.39μgL−1 chrysene equivalents, indicating DDPHs close to a baseline contamination level. Some relatively high concentrations (>1μgL−1) were probably associated with shipyard operations (hull paintings and ship docking), pollutants remobilization by dredging operations, occasional industrial discharges and oil derivatives released by vessels. DDPHs concentrations were lower in the wet season suggesting that the increased dilution rates caused by rainfall dominated upon the wet deposition of atmospheric combustion-derived PAHs process. Results in this study may be used as baseline to further studies in this area.

The response of metal accumulation in coral Tubastraea coccinea to various degrees of metal enrichment was investigated from the Yin-Yang Sea (YYS) receiving abandoned mining effluents, the Kueishan Islet (KI) hydrothermal vent field, and the nearshore area of remoted Green Island (GI). The concentrations of most dissolved metals were highest in seawater at YYS, followed by KI, and then GI, showing the effects of anthropogenic and venting inputs on metal levels. Five metals (Co, Fe, Mn, Ni, and Zn) yielded significant differences (p<0.05) among the skeleton samples. We identified similar patterns in the metal–Ca ratios, indicating that the elevated metals in skeletons was a consequence of external inputs. The coral tissues were relatively sensitive in monitoring metal accumulation, showing significant differences among three locations for Cd, Co, Cu, Fe, Pb, Ni, and Zn. Specific bioconcentration factors provided strong support for the differential metal accumulation in skeletons and tissues.

Natural abundance carbon isotope analyses are sensitive tracers for fates and use of oil in aquatic environments. Use of oil carbon in estuarine food webs should lead to isotope values approaching those of oil itself, −27‰ for stable carbon isotopes reflecting oil origins and −1000‰ for carbon-14 reflecting oil age. To test for transfer of oil from the 2010 Deepwater Horizon spill into estuarine food webs, filter-feeding barnacles (Balanus sp.) and marsh mussels (Geukensia demissa) were collected from Louisiana estuaries near the site of the oil spill. Carbon-14 analyses of these animals from open waters and oiled marshes showed that oil use was <1% and near detection limits estimated at 0.3% oil incorporation. Respiration studies showed no evidence for enhanced microbial activity in bay waters. Results are consistent with low dietary impacts of oil for filter feeders and little overall impact on respiration in the productive Louisiana estuarine systems.

Urban fugitive dust samples were collected to determine the chemical profiles of fugitive dust over Xi'an. Seventy eight samples were collected and divided into categories of paved road dust, construction dust, cement dust, and soil dust. Eighteen elements, including Na, Mg, Al, Si, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Ba, and Pb, and eight water–soluble inorganic ions, including Na+, Mg2−, Ca2−, NH4−, F−, Cl−, NO3− and SO42−, were measured. The most abundant elements in these urban dust samples were Al, Si, Ca, and Fe. Al, Si, K, and Ti and showed strong positive correlations with each other, indicating they are typical dust trace elements. In contrast, elements of Ca, Zn, As, and Pb had negative correlations to crustal elements. Si/Al, K/Al, Ti/Al, Mn/Al, and Fe/Al ratios varied insignificantly among these four samples types; these ratios are similar to the properties of loess, desert, and Gobi soil dust reported in previous studies. A significantly higher Ca/Al ratio was dominant in the chemical profile of the cement samples. In addition, high Pb/Al and Zn/Al ratios were detected in comparison with those in the Gobi soil, desert soil, and loess soil samples, which indicated that Pb/Al and Zn/Al ratios can be considered as markers of urban dust. To t a l water–soluble ions occupied only a small fraction (<5%) in the urban fugitive soil samples indicating that most of the materials in the fugitive dust were insoluble. Ca2+ and SO42− were the most abundant ions in all samples. Most of the Ca and K in the fugitive soil samples were in insoluble phases, which differ significantly in comparison with combustion sources. A strong correlation was observed between Ca2+ and estimated CO32− levels indicating that most of Ca2+ was in the form of CaCO3 rather than other calcium minerals in Xi’an fugitive dust.

This study investigated NH3 concentrations in and around a large–scale commercial pig farm with the so–called “gan qing fen” manure collection system near Beijing from April 2009 to August 2011. NH3 emissions from the fattening pig houses were calculated based on the heat balance method. Monthly concentrations of time–averaged NH3 in and near the pig house averaged 3 392 and 182μg m−3 and ranged from 1 044 to 7 514μg m−3 and 35.4 to 478μg m−3, respectively. Daily NH3 concentrations varied from 767 to 2 389μg m−3 in the pig house and 184 to 574μg m−3 outside. Time–averaged NH3 concentrations varied from 21.6 to 558μg m−3 within the farm while concentrations outside the farm ranged from 38.4μg m−3 at a distance of 10m to 14.0μg m−3 at a distance of 650m. Calculated average NH3 emission rates per pig were highest in summer and lowest in winter, 8.0±5.5 (average±standard deviation) and 2.0±0.4g day−1 pig−1, respectively. Average NH3 emission rates (normalized to 500kg live weight, expressed as AU) were highest during spring and summer (average 65.4±25.0 and 53.7±35.6 g day−1 AU−1) and lowest in autumn and winter (average 25.4±9.3 and 13.7±2.7g day−1 AU−1). Average NH3 emission per area (m2) from house was almost three times higher in summer (average 3.5±2.4g day−1 m−2) than in winter (average 1.1±0.3g day−1 m−2).

The anthropogenic PM2.5 in ambient air is implicated in the increased health risks and morbidities of urban subjects. However in the literature, there is a limited information on mass concentrations and size segregated chemical profile of ultrafine and superfine PM1 fractions of traffic linked urban ambient air. The size, and the adsorbed chemicals, and response to seasonal change in this submicron range of particles have seldom been studied so far. We have looked into these aspects in urban ambient air of Lucknow Uttar Pradesh India. A 10–stage MOUDI cascade impactor sampled the superfine (PM0.56, PM0.32, PM0.18) and ultrafine particles (PM0.1, PM0.056) distributed in traffic linked ambient air. We studied their morphology, mass concentrations, the adsorbed metal contents and organic chemical moieties using TEM, gravimetric analyses, AAS, and FTIR spectroscopy. A change in their contents and profile with season was also examined. Results revealed spherical and fractal shapes of PM0.1, 50nm–2μm size range of PM0.56 fractions, and 10–100nm size range of constituent spherules. Gravimetric analyses disclosed mass concentrations and multifold increases in their levels in winter. Cr, Cd, Ni, Pb and transition element Cu, Fe were found to be present in the studied particles. The presence of aliphatic and aromatic hydrocarbons with hydroxyl, carbonyl, and ketone groups were also found and displayed changes in their levels with season. Presence of organonitrate compounds indicated the role of submicron and nanosize particulates in secondary aerosol formation also. Results are important for epidemiological studies and public policy on superfine and ultrafine particulate matter in urban ambient air for identification of toxicity risk or health hazard, air quality monitoring and regulation.